A STUDY OF POLYBUTADIENE SYNTHESIS WITH MoCln(OR)4-n-(i-Bu)2AlOPh AS A CATALYST

XU Ling; ZHAO Senkun; TANG Xueming

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A STUDY OF POLYBUTADIENE SYNTHESIS WITH MoCln(OR)4-n-(i-Bu)2AlOPh AS A CATALYST

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- A STUDY OF POLYBUTADIENE SYNTHESIS WITH MoCln(OR)4-n-(i-Bu)2AlOPh AS A CATALYST
- Vol. 4, Issue 2, Pages: 194-199(1986)
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- Published：20 June 1986
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XU Ling, ZHAO Senkun, TANG Xueming. A STUDY OF POLYBUTADIENE SYNTHESIS WITH MoCln(OR)4-n-(i-Bu)2AlOPh AS A CATALYST[J]. 1986, 4(2): 194-199.
DOI：

XU Ling, ZHAO Senkun, TANG Xueming. A STUDY OF POLYBUTADIENE SYNTHESIS WITH MoCln(OR)4-n-(i-Bu)2AlOPh AS A CATALYST[J]. 1986, 4(2): 194-199. DOI：

摘要

The catalytic effect of Mo Cln (OR)4-n-(i-Bu)2AlOPh on the polymerization of butadiene inhydrogenated gasoline is studied (R is alkyl

cycloheptyl

phenyl of C4-16). In this system

the solu-bility and the catalytic activity of the catalyst do not depend on whether the number of carbon atomsin R group is odd or even. The R group with the primary and secondary carbon atom has a fairlygreat influence on the catalytic activity. When R is an alkyl

the catalytic activity increases and therange of Al/Mo values that keeps higher conversion of butadiene is broadened as the size of the R group increases.The content of 1

2-units in the polymer hardly varies with the size of the R group.

Abstract

The catalytic effect of Mo Cln (OR)4-n-(i-Bu)2AlOPh on the polymerization of butadiene inhydrogenated gasoline is studied (R is alkyl

cycloheptyl

phenyl of C4-16). In this system

the catalytic activity increases and therange of Al/Mo values that keeps higher conversion of butadiene is broadened as the size of the R group increases.The content of 1

2-units in the polymer hardly varies with the size of the R group.

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