THE POLYMERIZATION OF ACETYLENE BY COORDINATION CATALYSTS COMPOSED OF NEODYMIUM COMPOUND, ALUMINUM TRIALKYL AND A THIRD COMPONENT*

ZHANG Yifeng; CAI Yiping; YANG Mujie; SHEN Zhiquan

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THE POLYMERIZATION OF ACETYLENE BY COORDINATION CATALYSTS COMPOSED OF NEODYMIUM COMPOUND, ALUMINUM TRIALKYL AND A THIRD COMPONENT*

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- THE POLYMERIZATION OF ACETYLENE BY COORDINATION CATALYSTS COMPOSED OF NEODYMIUM COMPOUND, ALUMINUM TRIALKYL AND A THIRD COMPONENT*
- Vol. 3, Issue 4, Pages: 367-372(1985)
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- Published：20 December 1985
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ZHANG Yifeng, CAI Yiping, YANG Mujie, et al. THE POLYMERIZATION OF ACETYLENE BY COORDINATION CATALYSTS COMPOSED OF NEODYMIUM COMPOUND, ALUMINUM TRIALKYL AND A THIRD COMPONENT*[J]. 1985, 3(4): 367-372.
DOI：

ZHANG Yifeng, CAI Yiping, YANG Mujie, et al. THE POLYMERIZATION OF ACETYLENE BY COORDINATION CATALYSTS COMPOSED OF NEODYMIUM COMPOUND, ALUMINUM TRIALKYL AND A THIRD COMPONENT*[J]. 1985, 3(4): 367-372. DOI：

摘要

This paper describes the polymerization of acetylene by coordination catalysts composed ofvarious neodymium compounds

(Nd (P204)3; Nd (P507)3; Nd (NO3)3 3P350; Nd (BA)3.2H2O; and Nd (acac)3.2H2O)

aluminum trialkyl and an electron donor. The catalysts show fairly high catalyticactivity and high cis stereospecificity on acetylene polymerization at 30℃.

Abstract

This paper describes the polymerization of acetylene by coordination catalysts composed ofvarious neodymium compounds

(Nd (P204)3; Nd (P507)3; Nd (NO3)3 3P350; Nd (BA)3.2H2O; and Nd (acac)3.2H2O)

aluminum trialkyl and an electron donor. The catalysts show fairly high catalyticactivity and high cis stereospecificity on acetylene polymerization at 30℃.

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