SYNTHESIS OF SILICON MONOMERS AND OLIGOMERS CONTAINING CYCLOHEXYLENE RING*

LU Fengcai; WANG Baoren; GAO Yuanming; CHEN Suming; LI Congyu

Your Location：

Home >

Browse articles >

SYNTHESIS OF SILICON MONOMERS AND OLIGOMERS CONTAINING CYCLOHEXYLENE RING*

Papers | Updated：2021-06-21

- SYNTHESIS OF SILICON MONOMERS AND OLIGOMERS CONTAINING CYCLOHEXYLENE RING*
- Vol. 3, Issue 2, Pages: 110-115(1985)
- Affiliations：
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 June 1985
- Accepted：
Scan QR Code
LU Fengcai, WANG Baoren, GAO Yuanming, et al. SYNTHESIS OF SILICON MONOMERS AND OLIGOMERS CONTAINING CYCLOHEXYLENE RING*[J]. 1985, 3(2): 110-115.
DOI：

LU Fengcai, WANG Baoren, GAO Yuanming, et al. SYNTHESIS OF SILICON MONOMERS AND OLIGOMERS CONTAINING CYCLOHEXYLENE RING*[J]. 1985, 3(2): 110-115. DOI：

摘要

3-Bis(trichlorosilyl) cyclohexane was obtained by addition of HSiCl3

to cyclohexadiene-1

3in the presence of H2PtCl6.6H2O in isopropyl alcohol. The new compound was ethanolysed andmethylated to form di-methyl tetra-ethoxy disilyl

tri-methyl tri-ethoxy disilyl and terta-methyldi-ethoxy disilyl cyclohexanes. These di-to tetra-functional monomers were hydrolyzed by hydrochloric acid in ether. The di-functional monomer yielded cyclic dimer similar to octamethylcyclotetrasiloxane and the tri-functional monomer

a cyclic tetramer

while in the case of tetra-functional monomer a cyclic octamer was obtained.These compounds have not been reported in literature.

Abstract

3-Bis(trichlorosilyl) cyclohexane was obtained by addition of HSiCl3

to cyclohexadiene-1

3in the presence of H2PtCl6.6H2O in isopropyl alcohol. The new compound was ethanolysed andmethylated to form di-methyl tetra-ethoxy disilyl

a cyclic tetramer

while in the case of tetra-functional monomer a cyclic octamer was obtained.These compounds have not been reported in literature.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Preparation and Chiral Recognition Ability of Crystalline Cellulose Phenylcarbamate

Multiple-Responsive Chiral Hydrogels from Helical Dendronized Poly(phenylacetylene)s

End-group and Side-chain Dual-engineering of Selenium-fused Acceptors for 20.08% Efficiency Polymer Solar Cells with Low Energy Loss

Advances in Polymer-based Circularly Polarized Luminescent Materials

Sliding Dynamics of Ring Chain on a Rod-Coil Block Copolymer in Rotaxane

Related Author

No data

Related Institution

No data

⁰