SYNTHESIS AND POLYMERIZATION OF ALIPHATIC TERTIARY AMINO-GROUP N-SUBSTITUTED ACRYLAMIDES*

LI Fumian; WANG Lin; DING Yewei; FENG Xinde

Your Location：

Home >

Browse articles >

SYNTHESIS AND POLYMERIZATION OF ALIPHATIC TERTIARY AMINO-GROUP N-SUBSTITUTED ACRYLAMIDES*

Papers | Updated：2021-06-21

- SYNTHESIS AND POLYMERIZATION OF ALIPHATIC TERTIARY AMINO-GROUP N-SUBSTITUTED ACRYLAMIDES*
- Vol. 3, Issue 2, Pages: 140-149(1985)
- Affiliations：
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 June 1985
- Accepted：
Scan QR Code
LI Fumian, WANG Lin, DING Yewei, et al. SYNTHESIS AND POLYMERIZATION OF ALIPHATIC TERTIARY AMINO-GROUP N-SUBSTITUTED ACRYLAMIDES*[J]. 1985, 3(2): 140-149.
DOI：

LI Fumian, WANG Lin, DING Yewei, et al. SYNTHESIS AND POLYMERIZATION OF ALIPHATIC TERTIARY AMINO-GROUP N-SUBSTITUTED ACRYLAMIDES*[J]. 1985, 3(2): 140-149. DOI：

摘要

Aliphatic tertiary amino-group N-substituted acrylamides

N-acryl-N′-methylpiperazine (AMP)and N-methacryl-N′-methylpiperazine (MAMP) were synthesized directly from N-methylpiperazinewith corresponding acryloyl chlorides and characterized by elementary analysis of their picrates

1H-NMR

IR and MS. AMP did not polymerize with benzoyl peroxide (BPO)

but could poly-merize with lauroyl peroxide (LPO). The rate equation of the polymerization was given as RP=KP [AMP]1.5[LPO]0.5 and the overall activation energy of this polymerization system was 10.8Kcal/mol.The redox nature of LPO with the monomer itself was suggested.Even though AMP and MAMP hardly proceed the polymerization initiated with BPO

but under lower concentration would form redox system with BPO to initiate the polymerization of MMA readily.The rate equation of the polymerization of MMA initiated with MAMP-BPO system was given as Rp=Kp[MMA][MAMP]0.5[BPO]0.5 and the overall activation energy was 10.2 Kcal/mol.The analysis of the obtained polymers confirmed that MAMP not only initiated the polymerization of MMA by combining with BPO

but also took part in the polymer chains imparting them with better biocompatibility.

Abstract

Aliphatic tertiary amino-group N-substituted acrylamides

1H-NMR

IR and MS. AMP did not polymerize with benzoyl peroxide (BPO)

but also took part in the polymer chains imparting them with better biocompatibility.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Bioinspired Zinc-doped Nano Hydroxyapatite Reinforced Poly(lactic acid) Composites for Bone Repair

Optically Active Helical Poly(phenyl isocyanide)s Bearing Achiral Benzanilide Pendants: from Controlled Synthesis to Enantioseparation Application

Porous Organic Polymers for Photocatalytic Hydrogen Peroxide Production: Recent Advances and Future Perspectives

Molecularly Engineered Polyimide Films with Switchable Cavitation for Bidirectional Passive Thermal Regulation

End-to-End Neuron-inspired Signal Transduction Using Organic Electrochemical Transistors

Related Author

No data

Related Institution

No data

⁰