STUDIES ON THE ORGANIC PEROXIDE-DITERTIARY AMINE INITIATION SYSTEMS*

QIU Kunyuan; ZHANG Jingyi; HU Yuanjie; FENG Xinde

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STUDIES ON THE ORGANIC PEROXIDE-DITERTIARY AMINE INITIATION SYSTEMS*

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- STUDIES ON THE ORGANIC PEROXIDE-DITERTIARY AMINE INITIATION SYSTEMS*
- Vol. 3, Issue 1, Pages: 76-81(1985)
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- Published：20 March 1985
- Accepted：
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QIU Kunyuan, ZHANG Jingyi, HU Yuanjie, et al. STUDIES ON THE ORGANIC PEROXIDE-DITERTIARY AMINE INITIATION SYSTEMS*[J]. 1985, 3(1): 76-81.
DOI：

QIU Kunyuan, ZHANG Jingyi, HU Yuanjie, et al. STUDIES ON THE ORGANIC PEROXIDE-DITERTIARY AMINE INITIATION SYSTEMS*[J]. 1985, 3(1): 76-81. DOI：

摘要

Radical polperization of methyl methacrylate (MMA) initiated with organic peroxide-ditertiary amine binary systems was studied. Benzoyl peroxide (BPO)

lauroyl peroxide (LPO)

t-butyl hydro-peroxide (TBH)

and t-butyl peroxybenzoate (TBPB) were used as organic peroxide components

aromatic ditertiay amine 4

4′-tetramethyldiaminodiphenylmethane (TMDAPM) an d aliphatic di-tertiary amine tetramethylethylenediamine (TMEDA) were used as amine components. The polymeri-zation rate RP

the overall activation energy of polymerization Ea

the rate equation of MMA polymerization

and the end group of polymer formed were determined.

Abstract

Radical polperization of methyl methacrylate (MMA) initiated with organic peroxide-ditertiary amine binary systems was studied. Benzoyl peroxide (BPO)

lauroyl peroxide (LPO)

t-butyl hydro-peroxide (TBH)

and t-butyl peroxybenzoate (TBPB) were used as organic peroxide components

aromatic ditertiay amine 4

4′-tetramethyldiaminodiphenylmethane (TMDAPM) an d aliphatic di-tertiary amine tetramethylethylenediamine (TMEDA) were used as amine components. The polymeri-zation rate RP

the overall activation energy of polymerization Ea

the rate equation of MMA polymerization

and the end group of polymer formed were determined.

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