PREPARATION AND PROPERTY OF POLYMERIC PENDANT Ru(bpy)32+ COMPLEXES*

HOU Xiaohuai; Masao Kaneko; Akira Yamada

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PREPARATION AND PROPERTY OF POLYMERIC PENDANT Ru(bpy)32+ COMPLEXES*

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- PREPARATION AND PROPERTY OF POLYMERIC PENDANT Ru(bpy)32+ COMPLEXES*
- Vol. 2, Issue 2, Pages: 151-158(1984)
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- Published：20 December 1984
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HOU Xiaohuai, Masao Kaneko, Akira Yamada. PREPARATION AND PROPERTY OF POLYMERIC PENDANT Ru(bpy)32+ COMPLEXES*[J]. 1984, 2(2): 151-158.
DOI：

HOU Xiaohuai, Masao Kaneko, Akira Yamada. PREPARATION AND PROPERTY OF POLYMERIC PENDANT Ru(bpy)32+ COMPLEXES*[J]. 1984, 2(2): 151-158. DOI：

摘要

Polymeric pendant Ru(bpy)32+ complexes were prepared from homopolymer and copolymers of 4-methyl-4'-vinyl-2

2'-bipyridine (Vbpy). Vbpy was prepared from 4-methylpyridine. The comonomers were styrene (St)

acrylic acid (AA)

N-vinylpyrrolidone (Pyr)

4-vinylpyridine (Vpy)

methyl methacrylate (MMA)

2-hydroxyethyl methacrylate (HEMA)

acrylonitrile (AN) and N-ethyl-4-vinylpyridium bromide (EQ-Vpy). The fraction of the pendant Ru(bpy)32+ repeating unit in the polymeric complex was 0.022 to 0.052. Absorption maximum

molar extinction coefficient

emission maximum and relative emission intensity of the polymeric complexes were studied.

Abstract

Polymeric pendant Ru(bpy)32+ complexes were prepared from homopolymer and copolymers of 4-methyl-4'-vinyl-2

2'-bipyridine (Vbpy). Vbpy was prepared from 4-methylpyridine. The comonomers were styrene (St)

acrylic acid (AA)

N-vinylpyrrolidone (Pyr)

4-vinylpyridine (Vpy)

methyl methacrylate (MMA)

2-hydroxyethyl methacrylate (HEMA)

acrylonitrile (AN) and N-ethyl-4-vinylpyridium bromide (EQ-Vpy). The fraction of the pendant Ru(bpy)32+ repeating unit in the polymeric complex was 0.022 to 0.052. Absorption maximum

molar extinction coefficient

emission maximum and relative emission intensity of the polymeric complexes were studied.

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