SIMULTANEOUS CALIBRATION OF MOLECULAR WEIGHT SEPARATION AND COLUMN DISPERSION OF SEC WITH CHARACTERIZED POLYMER STANDARDS
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SIMULTANEOUS CALIBRATION OF MOLECULAR WEIGHT SEPARATION AND COLUMN DISPERSION OF SEC WITH CHARACTERIZED POLYMER STANDARDS
Vol. 1, Issue 2, Pages: 125-131(1983)
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Published:20 November 1983
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CHENG Rongshi, BO Shuqin. SIMULTANEOUS CALIBRATION OF MOLECULAR WEIGHT SEPARATION AND COLUMN DISPERSION OF SEC WITH CHARACTERIZED POLYMER STANDARDS[J]. 1983, 1(2): 125-131.
DOI:
CHENG Rongshi, BO Shuqin. SIMULTANEOUS CALIBRATION OF MOLECULAR WEIGHT SEPARATION AND COLUMN DISPERSION OF SEC WITH CHARACTERIZED POLYMER STANDARDS[J]. 1983, 1(2): 125-131.DOI:
SIMULTANEOUS CALIBRATION OF MOLECULAR WEIGHT SEPARATION AND COLUMN DISPERSION OF SEC WITH CHARACTERIZED POLYMER STANDARDS
With the aid of the theoretical relationship between the calibration relation of a SEC column for the monodisperse polymer species under ideal working condition and the effective relations between the molecular weight and the elution volume for characterized polymer samples
a computational procedure for simultaneous calibration of molecular weight separation and column dispersion is proposed. From the experimental chromatograms of narrow MWD polystyrene standards and broad MWD 1
2-polybutadiene fractions the spreading factor with the elution volume is independent upon the polymer sample used.
Abstract
With the aid of the theoretical relationship between the calibration relation of a SEC column for the monodisperse polymer species under ideal working condition and the effective relations between the molecular weight and the elution volume for characterized polymer samples
a computational procedure for simultaneous calibration of molecular weight separation and column dispersion is proposed. From the experimental chromatograms of narrow MWD polystyrene standards and broad MWD 1
2-polybutadiene fractions the spreading factor with the elution volume is independent upon the polymer sample used.
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