SYNTHESIS OF POLY(VINYLIDENE FLUORIDE) WITH LOW CONTENTS OF HEAD-TO-HEAD CHAIN

DUAN Youlu; YU Xiuying; XUE Ying; ZENG Miaoying; JI Shanrong

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SYNTHESIS OF POLY(VINYLIDENE FLUORIDE) WITH LOW CONTENTS OF HEAD-TO-HEAD CHAIN

Papers | Updated：2021-06-21

- SYNTHESIS OF POLY(VINYLIDENE FLUORIDE) WITH LOW CONTENTS OF HEAD-TO-HEAD CHAIN
- Vol. 1, Issue 2, Pages: 161-167(1983)
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- Published：20 November 1983
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DUAN Youlu, YU Xiuying, XUE Ying, et al. SYNTHESIS OF POLY(VINYLIDENE FLUORIDE) WITH LOW CONTENTS OF HEAD-TO-HEAD CHAIN[J]. 1983, 1(2): 161-167.
DOI：

DUAN Youlu, YU Xiuying, XUE Ying, et al. SYNTHESIS OF POLY(VINYLIDENE FLUORIDE) WITH LOW CONTENTS OF HEAD-TO-HEAD CHAIN[J]. 1983, 1(2): 161-167. DOI：

摘要

The relations between polymerization conditions of vinylidene fluoride and contents of head-tohead chain in the polymer have been studied. It shows that the contents of head-to-head chain of the polymer are related to its polymerization temperature

but are not related with the kinds of initiators used. Therefore

poly(vinylidene fluoride) with low contents of head-to-head chain (ca. 3%) can be prepared under lower polymerization temperature. Plot of the contents of A chains against melting points of the polymer is linear

which can be expressed by an equation:A=24.8+0.362 Tm(%).

Abstract

but are not related with the kinds of initiators used. Therefore

which can be expressed by an equation:A=24.8+0.362 Tm(%).

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