STUDIES ON CHARGE TRANSFER POLYMERIZATION——POLYMERIZATION OF ACRYLONITRILE INITIATED WITH PHENYL HYDRAZINE AND ITS DERIVATIVES

CAO Weixiao; HAN Ping; FENG Xinde

Your Location：

Home >

Browse articles >

STUDIES ON CHARGE TRANSFER POLYMERIZATION——POLYMERIZATION OF ACRYLONITRILE INITIATED WITH PHENYL HYDRAZINE AND ITS DERIVATIVES

Papers | Updated：2021-06-21

- STUDIES ON CHARGE TRANSFER POLYMERIZATION——POLYMERIZATION OF ACRYLONITRILE INITIATED WITH PHENYL HYDRAZINE AND ITS DERIVATIVES
- Vol. 1, Issue 2, Pages: 189-195(1983)
- Affiliations：
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 November 1983
- Accepted：
Scan QR Code
CAO Weixiao, HAN Ping, FENG Xinde. STUDIES ON CHARGE TRANSFER POLYMERIZATION——POLYMERIZATION OF ACRYLONITRILE INITIATED WITH PHENYL HYDRAZINE AND ITS DERIVATIVES[J]. 1983, 1(2): 189-195.
DOI：

CAO Weixiao, HAN Ping, FENG Xinde. STUDIES ON CHARGE TRANSFER POLYMERIZATION——POLYMERIZATION OF ACRYLONITRILE INITIATED WITH PHENYL HYDRAZINE AND ITS DERIVATIVES[J]. 1983, 1(2): 189-195. DOI：

摘要

The photopolymerization of acrylonitrile (AN) initiated with phenyl hydrazine (PHZ) and its derivatives has been studied. The initiator exponent and monomer exponent were determined from the kinetic investigation to be 0.66th and 2.1th respectively and the overall activation energy was 33.4KJ/mol for the PHZ-AN system. Spectral analysis and other data indicate that a charge transfer complex between PHZ as a donor and AN as an aceeptor is formed. The initiation mechanism was proposed.

Abstract

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Two-way Shape Memory Effect of Polycaprolactone-based Polyurethane via Synergistic Role of Hydrogen Bonding and Crystallization Tuned by Malic Acid

Silk Sericin-inspired Poly-β-homoserine for Protein Protection

From Molecular Defect to Macroscopic Performance: Manipulating Dichroism and Mechanics in Iodine-doped Poly(vinyl alcohol) via Ethylene Incorporation

Highly Regio- and trans-Selective Ring-opening Metathesis Polymerization of Chiral Aza-norbornene with a Simple Phenylimido-Tungsten Catalyst

Improvements of Hydrophobicity and Toughness of Epoxy Coatings Modified with Hydroxyl-terminated Fluororubber

Related Author

No data

Related Institution

No data

⁰