POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS

Yan-guo Li; Jing-yu Liu; Yue-sheng Li

Your Location：

Home >

Browse articles >

POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS

Papers | Updated：2021-06-21

- POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS
- Vol. 28, Issue 1, Pages: 101-106(2010)
- Affiliations：
- Author bio：
- Funds：
- DOI：
  CLC：
- Published：20 January 2010
- Accepted：
Scan QR Code
Yan-guo Li, Jing-yu Liu, Yue-sheng Li. POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS[J]. 2010, 28(1): 101-106.
DOI：

Yan-guo Li, Jing-yu Liu, Yue-sheng Li. POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS[J]. 2010, 28(1): 101-106. DOI：

摘要

A simple and effective way to prepare poly(acrylate)s

such as poly(methacrylate)

poly(butyl acrylate) and poly(butyl methacrylate)

has been achieved by using the single component aluminum-based compounds

such as modified methylaluminoxane (MMAO)

triisobutylaluminium (TIBA) and triethylaluminium (TEA) as initiators. Effective initiations and high molecular weight polymers with unimodal molecular weight distributions could be easily obtained by varying the reaction parameters of systems under mild conditions. Although these aluminum compounds were inefficient initiators for methyl methacrylate (MMA) polymerization

they exhibited remarkable catalytic activity for butyl methacrylate (BMA) polymerization

affording high molecular weight poly(BMA)s.

Abstract

A simple and effective way to prepare poly(acrylate)s

such as poly(methacrylate)

poly(butyl acrylate) and poly(butyl methacrylate)

has been achieved by using the single component aluminum-based compounds

such as modified methylaluminoxane (MMAO)

they exhibited remarkable catalytic activity for butyl methacrylate (BMA) polymerization

affording high molecular weight poly(BMA)s.

关键词

Keywords

references

Views

110

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

A Paradigm for BF3 Co-initiated Cationic Polymerization with Low Dispersity: Introducing Acetonitrile and Lowering the Reaction Temperature

End-group and Side-chain Dual-engineering of Selenium-fused Acceptors for 20.08% Efficiency Polymer Solar Cells with Low Energy Loss

Energy Storage Performance of Supercapacitors with Polyelectrolyte Surface Coatings: Effects of Dielectric Contrast

2026-9 Contents

Squaramide-directed Cooperative One-dimensional Assembly in Telechelic Polydimethylsiloxane for Hierarchical Network Formation

Related Author

No data

Related Institution

No data

⁰