PREPARATION OF POLYSTYRENE/SiO2 COMPOSITE NANOPARTICLES BEARING SULFONIC GROUPS ON THE SURFACE VIA EMULSION COPOLYMERIZATION USING A POLYMERIZABLE EMULSIFIER
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PREPARATION OF POLYSTYRENE/SiO2 COMPOSITE NANOPARTICLES BEARING SULFONIC GROUPS ON THE SURFACE VIA EMULSION COPOLYMERIZATION USING A POLYMERIZABLE EMULSIFIER
Vol. 27, Issue 5, Pages: 629-637(2009)
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Published:20 September 2009
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Yi-zhang Chen a, Zhao-xia Guo a, Jian Yu a, et al. PREPARATION OF POLYSTYRENE/SiO2 COMPOSITE NANOPARTICLES BEARING SULFONIC GROUPS ON THE SURFACE VIA EMULSION COPOLYMERIZATION USING A POLYMERIZABLE EMULSIFIER[J]. 2009, 27(5): 629-637.
DOI:
Yi-zhang Chen a, Zhao-xia Guo a, Jian Yu a, et al. PREPARATION OF POLYSTYRENE/SiO2 COMPOSITE NANOPARTICLES BEARING SULFONIC GROUPS ON THE SURFACE VIA EMULSION COPOLYMERIZATION USING A POLYMERIZABLE EMULSIFIER[J]. 2009, 27(5): 629-637.DOI:
PREPARATION OF POLYSTYRENE/SiO2 COMPOSITE NANOPARTICLES BEARING SULFONIC GROUPS ON THE SURFACE VIA EMULSION COPOLYMERIZATION USING A POLYMERIZABLE EMULSIFIER
Functionalized PS/SiO2 composite nanoparticles bearing sulfonic groups on the surface were successfully synthesized via emulsion copolymerization using a polymerizable emulsifier α olefin solfonate (AOS). As demonstrated by transmission electron microscopy and atomic force microscopy
well-defined core-shell PS/SiO2 composite nanoparticles with a diameter of 50 nm were obtained. Sulfonic groups introduced onto the surface of the composite nanoparticles were quantified by FTIR
and can be controlled to some extent via a two-stage procedure.
Abstract
Functionalized PS/SiO2 composite nanoparticles bearing sulfonic groups on the surface were successfully synthesized via emulsion copolymerization using a polymerizable emulsifier α olefin solfonate (AOS). As demonstrated by transmission electron microscopy and atomic force microscopy
well-defined core-shell PS/SiO2 composite nanoparticles with a diameter of 50 nm were obtained. Sulfonic groups introduced onto the surface of the composite nanoparticles were quantified by FTIR
and can be controlled to some extent via a two-stage procedure.
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