FOLLOWUS
Key Laboratory of Advanced Materials of Ministry of Education of China, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
tanglm@tsinghua.edu.cn
Published:2024-3,
Published Online:15 April 2024,
Received:12 January 2024,
Revised:20 February 2024,
Accepted:6 March 2024
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Zhou, J. H.; Tang, L. M. Investigation on UV-curing reprocessable thermosets bearing hindered urea bonds and their composites with modified zinc oxide nanoparticles. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-024-3121-9
Jun-Hao Zhou, Li-Ming Tang. Investigation on UV-curing Reprocessable Thermosets Bearing Hindered Urea Bonds and Their Composites with Modified Zinc Oxide Nanoparticles. [J/OL]. Chinese Journal of Polymer Science 421-15(2024)
Zhou, J. H.; Tang, L. M. Investigation on UV-curing reprocessable thermosets bearing hindered urea bonds and their composites with modified zinc oxide nanoparticles. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-024-3121-9 DOI:
Jun-Hao Zhou, Li-Ming Tang. Investigation on UV-curing Reprocessable Thermosets Bearing Hindered Urea Bonds and Their Composites with Modified Zinc Oxide Nanoparticles. [J/OL]. Chinese Journal of Polymer Science 421-15(2024) DOI: 10.1007/s10118-024-3121-9.
In this study
a series of hindered urea bond (HUB) containing polyurethane-urea methacrylate prepolymers and a none HUB containing polyurethane methacrylate prepolymer were prepared using isobornyl methacrylate as the reactive diluent
via
one-pot procedure. The prepolymers were characterized fully by various techniques. Then
their thermosets were fabricated
via
UV curing in presence of a photo initiator
and their mechanical property and thermal behavior were investigated and compared. Different from the none HUB containing thermoset
the HUB containing thermosets (defined as PUT) could be recycled and reprocessed by hot press under relatively mild conditions with high recovery ratio of mechanical property. Furthermore
zinc oxide (ZnO) nanoparticles were modified with 3-(trimethoxysilyl) propyl methacrylate and the modified ZnO (defined as ZnO-TPM) was dispersed and polymerized into PUT matrix to prepare their nanocomposites. The influence of ZnO-TPM on the mechanical performance of the composites was evaluated
which indicated that the Young’s modulus and tensile strength increased gradually to the maximum values at ZnO-TPM content of 1 wt% and then decreased. The composites also displayed good reprocessability with improved recovery ratio compared to the pure PUT sample. In addition
the composite materials exhibited strong UV absorption capacity
implying their potential application in the circumstance where UV-shielding was required.
Polyurethane-urea methacrylateHindered urea bondZnO nanoparticlesReprocessingUV curing
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