a.School of Chemical Engineering, Qingdao University of Science & Technology, Qingdao 266042, China
b.College of Engineering, Yanching institute of Technology, Langfang 065210, China
c.Key Laboratory of Rubber-plastics, Qingdao University of Science & Technology, Qingdao 266042, China
d.State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
zhwp@qust.edu.cn (W.P.Z.)
skyan@mail.buct.edu.cn (S.K.Y.)
Scan for full text
Xu, J.; Zhu, L.; Feng, X. Q.; Sui, C.; Zhao, W. P.; Yan, S. K. Effect of phase separation size on the properties of self-healing elastomer. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-024-3097-5
Jun Xu, Lei Zhu, Xian-Qi Feng, et al. Effect of Phase Separation Size on the Properties of Self-healing Elastomer. [J/OL]. Chinese Journal of Polymer Science 421-7(2024)
Xu, J.; Zhu, L.; Feng, X. Q.; Sui, C.; Zhao, W. P.; Yan, S. K. Effect of phase separation size on the properties of self-healing elastomer. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-024-3097-5 DOI:
Jun Xu, Lei Zhu, Xian-Qi Feng, et al. Effect of Phase Separation Size on the Properties of Self-healing Elastomer. [J/OL]. Chinese Journal of Polymer Science 421-7(2024) DOI: 10.1007/s10118-024-3097-5.
Regulation of phase structure has been recognized as one of the most effective ways to fabricate self-healing polymers with high mechanical strength. The mechanical properties of the resultant polymers are certainly affected by the size of separated phase domain. However
the study on this aspect is absence
because it can hardly exclude the influence of variation in monomer proportion required for tuning the separated phase size. Here
we report the first study on tuning the phase size through reversible addition-fragmentation chain transfer (RAFT) polymerization without changing the proportion of monomers. As expected
the size of separated phase has been successfully mediated from 15 nm to 9 nm by tuning the molecular weight of the chain transfer agent. It is found that the mechanical strength and the self-healing efficiency of the resultant polymers increase simultaneously with the decrease of phase size. The study on the formation kinetics of hydrogen bonds reveals that the decrease of phase size can facilitate the re-bonding rate of hydrogen bonds
even if the migration of polymer chains is restricted.
Self-healing polymersPhase separationReversible addition-fragmentation chain transfer
Sumerlin,B.S.Next-generationself-healingmaterials.Science2018, 362,150−151..
Zhang,M.Self-healingpolymericmaterials:onawindingroadtosuccess.Chinese J. Polym. Sci.2022, 40,1315−1316..
Xu,J.;Zhu,L.;Nie,Y.;Li,Y.;Wei,S.;Chen,X.;Zhao,W.;Yan,S.Advancesandchallengesofself-healingelastomers:aminireview.Materials2022, 15,5993..
Zheng,Y.;Zhu,H.;Tan,Y.;Liu,F.;Wu,Y.Rapidself-healingandstrongadhesiveelastomer viasupramolecularaggregatesfromcore-shellmicellesofsiliconhydroxyl-functionalized cis-polybutadiene.Chinese J. Polym. Sci.2023, 41,84−94..
Guo,Z.;Lu,X.;Wang,X.;Li,X.;Li,J.;Sun,J.Engineeringofchainrigidityandhydrogenbondcross-linkingtowardultra-strong,healable,recyclableandwater-resistantelastomers.Adv. Mater.2023, 35,2300286..
Li,C.;Liu,J.;Qiu,X.;Yang,X.;Huang,X.;Zhang,X.Photoswitchableandreversiblefluorescenteutectogelsforconformalinformationencryption.Angew. Chem. Int. Ed.2023, 62,13971..
Wang,Y.;Shu,R.;Zhang,X.Strong,supertoughandself-healingbiomimeticlayerednanocompositesenabledbyreversibleinterfacialpolymerchainsliding.Angew. Chem. Int. Ed.2023, 62,03446..
Yang,T.;Lu,X.;Wang,X.;Li,Y.;Wei,X.;Wang,W.;Sun,J.Healable,recyclable,andscratch-resistantpolyurethaneelastomerscross-linkedwithmultiplehydrogenbonds.ACS Appl. Polym. Mater.2023, 5,2830−2839..
Zhao,C.;Guo,M.;Mao,J.;Li,Y.;Wu,Y.;Guo,H.;Xiang,D.;Li,H.Self-healing,stretchable,temperature-sensitiveandstrain-sensitivehydrogel-basedflexiblesensors.Chinese J. Polym. Sci.2023, 41,334−344..
Zhang,L.;You,Z.Dynamicoxime-urethanebonds,aversatileunitofhighperformanceself-healingpolymersfordiverseapplications.Chinese J. Polym. Sci.2021, 39,1281−1291..
Neal,J.A.;Mozhdehi,D.;Guan,Z.Enhancingmechanicalperformanceofacovalentself-healingmaterialbysacrificialnon-covalentbonds.J. Am. Chem. Soc.2015, 137,4846−4850..
Chen,Y.;Guan,Z.Multivalenthydrogenbondingblockcopolymersself-assembleintostrongandtoughself-healingmaterials.Chem. Commun.2014, 50,10868−10870..
Li,M.;Rong,M.;Zhang,M.Reversiblemechanochemistryenabledautonomoussustainingofrobustnessofpolymers—anexampleofnextgenerationself-healingstrategy.Chinese J. Polym. Sci.2021, 39,545−553..
Eom,Y.;Kim,S.-M.;Lee,M.;Jeon,H.;Park,J.;Lee,E.S.;Hwang,S.Y.;Park,J.;Oh,D.X.Mechano-responsivehydrogen-bondingarrayofthermoplasticpolyurethaneelastomercapturesbothstrengthandself-healing.Nat. Commun.2021, 12,621..
Wang,Y.;Huang,X.;Zhang,X.Mechano-responsivehydrogen-bondingarrayofthermoplasticpolyurethaneelastomercapturesbothstrengthandself-healing.Nat. Commun.2021, 12,1291..
Sun,F.;Liu,L.;Liu,T.;Wang,X.;Qi,Q.;Hang,Z.;Chen,K.;Xu,J.;Fu,J.Vascularsmoothmuscle-inspiredarchitectureenablessoftyettoughself-healingmaterialsfordurablecapacitivestrain-sensor.Nat. Commun.2023, 14,130..
Tie,J.;Mao,Z.;Zhang,L.;Zhong,Y.;Xu,H.Strongandultratoughionogelenabledbyingeniouscombinedionicliquidsinducedmicrophaseseparation.Adv. Funct. Mater. 2023 ,2307367..
Li,H.;Li,X.;Liu,N.;Liu,D.;Wang,Z.;Chen,F.Atoughandstrain-stiffeningionogelenabledbymoderatemicrophaseseparationforepidermalmulti-sensor.Polymer2023, 282,126166..
Wu,J.;Zhang,Z.;Wu,Z.;Liu,D.;Yang,X.;Wang,Y.;Jia,X.;Xu,X.;Jiang,P.;Wang,X.Atoughandstrain-stiffeningionogelenabledbymoderatemicrophaseseparationforepidermalmulti-sensor.Adv. Funct. Mater.2022, 33,2210395..
Liu,Y.;Chen,L.;Yang,Y.;Chen,H.;Zhang,X.;Liu,S.HighMechanicalStrengthandMultifunctionalMicrophase-SeparatedSupramolecularHydrogelsFabricatedbyLiquid-CrystallineBlockcopolymer.Macromol. Rapid Commun.2022, 44,2200829..
Lai,Y.;Kuang,X.;Zhu,P.;Huang,M.;Dong,X.;Wang,D.Colorless,transparent,robust,andfastscratch-self-healingelastomers viaaphase-lockeddynamicbondsdesign.Adv. Mater.2018, 30,1802556..
Wang,B.;Zhai,W.;Fan,J.B.;Xu,J.;Zhao,W.;Feng,X.Aninterfaciallypolymerizedself-healingorgano/hydrocopolymerwithshapememory.Nanoscale2019, 11,6846−6851..
An,N.;Wang,X.;Li,Y.;Zhang,L.;Lu,Z.;Sun,J.Healableandmechanicallysuper-strongpolymericcompositesderivedfromhydrogen-bondedpolymericcomplexes.Adv. Mater.2019, 31,1904882..
Xun,X.;Zhao,X.;Li,Q.;Zhao,B.;Ouyang,T.;Zhang,Z.;Kang,Z.;Liao,Q.;Zhang,Y.Toughanddegradableself-healingelastomerfromsynergisticsoft-hardsegmentsdesignforbiomechano-robustartificialskin.ACS Nano2021, 15,20656−20665..
Xie,Z.;Hu,B.;Li,R.;Zhang,Q.Hydrogenbondinginself-healingelastomers.ACS Omega2021, 6,9319−9333..
Zhao,W.;Liu,Y.;Zhao,C.;Shi,X.;Feng,X.;Xu,J.;Wang,S.;Wu,Y.;Yan,S.Afastself-healableandstretchableconductorbasedonhierarchicalwrinkledstructureforflexibleelectronics.Compos. Sci. Technol.2021, 211,108834..
Zhao,W.;Zhang,Z.;Hu,J.;Feng,X.;Xu,J.;Wu,Y.;Yan,S.Robustandultra-fastself-healingelastomerswithhierarchicallyanisotropicstructuresandusedforwearablesensors.Chem. Eng. J.2022, 446,137305..
Zhao,W.;Li,Y.;Hu,J.;Feng,X.;Zhang,H.;Xu,J.;Yan,S.Mechanicallyrobust,instantself-healingpolymerstowardselasticentropydrivenartificialmuscles.Chem. Eng. J.2023, 454,140100..
Zhao,W.;Liu,Y.;Zhang,Z.;Feng,X.;Xu,H.;Xu,J.;Hu,J.;Wang,S.;Wu,Y.;Yan,S.High-strength,fastself-healing,aging-insensitiveelastomerswithshapememoryeffect.ACS Appl. Mater. Interfaces2020, 12,35445−35452..
Li,Y.;Feng,X.;Sui,C.;Xu,J.;Zhao,W.;Yan,S.Highlyentangledelastomerwithultra-fastself-healingcapabilityandhighmechanicalstrength.Chem. Eng. J.2024, 479,147689..
Lai,J.;Filla,D.;Shea,R.Functionalpolymersfromnovelcarboxyl-terminatedtrithiocarbonatesashighlyefficientRAFTagents.Macromolecules2002, 35,6754−6756..
Pan,J.;Zeng,H.;Gao,L.;Zhang,Q.;Luo,H.;Shi,X.;Zhang,H.Hierarchicalmultiscalehydrogelswithidenticalcompositionsyetdisparateproperties viatunablephaseseparation.Adv. Funct. Mater.2022, 32,2110277..
Chen,Y.;Kushner,A.;Williams,G.;Guan,Z.Multiphasedesignofautonomicself-healingthermoplasticelastomers.Nat. Chem.2012, 4,467−472..
Wang,X.;Zhan,S.;Lu,Z.;Li,J.;Yang,X.;Qiao,Y.;Men,Y.;Sun,J.Healable,recyclable,andmechanicallytoughpolyurethaneelastomerswithexceptionaldamagetolerance.Adv. Mater.2020, 32,2005759..
Xiang,H.;Li,X.;Wu,B.;Sun,S.;Wu,P.Highlydampingandself-healableionicelastomerfromdynamicphaseseparationofstickyfluorinatedpolymers.Adv. Mater.2023, 35,2209581..
Yao,Y.;Liu,B.;Xu,Z.;Yang,J.;Liu,W.AnunparalleledH-bondingandion-bondingcrosslinkedwaterbornepolyurethanewithsupertoughnessandunprecedentedfractureenergy.Mater. Horiz.2021, 8,2742..
Zhang,Q.;Niu,S.;Wang,L.;Lopez,J.;Chen,S.;Cai,Y.;Du,R.;Liu,Y.;Lai,J.;Liu,L.;Li,C.;Yan,X.;Liu,C.;Tok,J.;Jia,X.;Bao,Z.Anelasticautonomousself-healingcapacitivesensorbasedonadynamicdualcrosslinkedchemicalsystem.Adv. Mater.2018, 30,1801435..
Peng,Y.;Zhao,L.;Yang,C.;Yang,Y.;Song,C.;Wu,Q.;Huang,G.;Wu,J.Supertoughandstrongself-healingelastomersbasedonpolyampholytes.J. Mater. Chem. A2018, 6,19066..
Zhao,P.;Yin,C.;Zhang,Y.;Chen,X.;Yang,B.;Xia,J.;Bian,L.Musselcuticle-mimeticultra-tough,self-healingelastomerswithdouble-lockednanodomainsexhibitfaststimuli-responsiveshapetransformation.J. Mater. Chem. A2020, 8,12463..
Su,G.;Yin,S.;Guo,Y.;Zhao,F.;Guo,Q.;Zhang,X.;Zhou,T.;Yu,G.Balancingthemechanical,electronic,andself-healingpropertiesinconductiveself-healinghydrogelforwearablesensorapplications.Mater. Horiz.2021, 8,1795..
Yang,Y.;Wang,H.;Huang,L.;Nishiura,M.;Higaki,Y.;Hou,Z.Terpolymerizationofethyleneandtwodifferentmethoxyaryl-substitutedpropylenesbyscandiumcatalystmakestoughandfastself-healingelastomers.Angew. Chem. Int. Ed.2021, 60,26192−26198..
Tang,M.;Li,Z.;Wang,K.;Jiang,Y.;Tian,M.;Qin,Y.;Gong,Y.;Li,Z.;Wu,L.Ultrafastself-healingandself-adhesivepolysiloxanetowardsreconfigurableon-skinelectronics.J. Mater. Chem. A2022, 10,1750−1759..
Xu,J.;Chen,J.;Zhang,Y.;Liu,T.;Fu,J.Afastroom-temperatureself-healingglassypolyurethane.Angew. Chem. Int. Ed.2021, 60,7947−7955..
Tee,B.C.K.;Wang,C.;Allen,R.;Bao,Z.Afastroom-temperatureself-healingglassypolyurethane.Nat. Nanotechnol.2012, 7,825−832..
0
Views
0
Downloads
0
CSCD
Publicity Resources
Related Articles
Related Author
Related Institution