Ion-conducting Membranes Based on Bacterial Cellulose Nanofibers Modified by Poly(sodium acrylate-<italic style="font-style: italic">co</italic>-2-acrylamido-2-methylpropanesulfonic acid)

Elizaveta V. Batishcheva; Nikolay N. Smirnov; Natalya V. Bobrova; Maria P. Sokolova; Michael A. Smirnov

doi:10.1007/s10118-023-3054-8

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Ion-conducting Membranes Based on Bacterial Cellulose Nanofibers Modified by Poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid)

RESEARCH ARTICLE | Updated：2024-02-20

- Ion-conducting Membranes Based on Bacterial Cellulose Nanofibers Modified by Poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid)
  Enhanced Publication
- Chinese Journal of Polymer Science Vol. 42, Issue 3, Pages: 333-343(2024)
- Affiliations：
  
  Institute of Macromolecular Compounds, Russian Academy of Sciences, Bolshoy pr. 31, Saint Petersburg 199004, Russia
- Author bio：
  
  batischevaelisaveta@gmail.com (E.V.B.)
  smirnov_michael@mail.ru (M.A.S.)
- Funds：
- DOI：10.1007/s10118-023-3054-8
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Batishcheva, E. V.; Smirnov, N. N.; Bobrova, N. V.; Sokolova, M. P.; Smirnov, M. A. Ion-conducting membranes based on bacterial cellulose nanofibers modified by poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid). Chinese J. Polym. Sci. 2024, 42, 333–343

Elizaveta V. Batishcheva, Nikolay N. Smirnov, Natalya V. Bobrova, et al. Ion-conducting Membranes Based on Bacterial Cellulose Nanofibers Modified by Poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid). [J]. Chinese Journal of Polymer Science 42(3):333-343(2024)
Batishcheva, E. V.; Smirnov, N. N.; Bobrova, N. V.; Sokolova, M. P.; Smirnov, M. A. Ion-conducting membranes based on bacterial cellulose nanofibers modified by poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid). Chinese J. Polym. Sci. 2024, 42, 333–343 DOI： 10.1007/s10118-023-3054-8.

Elizaveta V. Batishcheva, Nikolay N. Smirnov, Natalya V. Bobrova, et al. Ion-conducting Membranes Based on Bacterial Cellulose Nanofibers Modified by Poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid). [J]. Chinese Journal of Polymer Science 42(3):333-343(2024) DOI： 10.1007/s10118-023-3054-8.

摘要

Green ion-conducting membranes based on bacterial cellulose nanofibers with grafted acrylic copolymer was elaborated. High ion mobility and low activation energy of conductivity of prepared membrane allow supercapacitor cell to operate at an ultra-high current density.

Abstract

Green method for preparation of ion-conducting membranes (ICM) based on bacterial cellulose nanofibers (CNF) modified by a copolymer of sodium acrylate and 2-acrylamido-2-methylpropanesulfonic acid was elaborated. FTIR and NMR data confirmed grafting of polyacrylate onto cellulose surface. Formation of porous structure of the ICM was controlled by SEM and AFM. The maximal ionic conductivity of the membranes reaches 1.5 and 3.1 mS·cm,−1, (60 °C and 98% relative humidity) when they are saturated with water or H,2,SO,4, (1 mol·L,−1,) electrolyte, respectively. Prepared ICM was tested as a separator in a symmetrical supercapacitor with electrodes based on polyaniline hydrogel. The assembled cell demonstrate ability to operate at high current density up to 100 A·g,−1, maintaining specific capacitance 165 F·g,−1,. Maximal specific capacitance of 289 F·g,−1, was achieved at current density 1 A·g,−1,. Retaining of 90% of initial capacitance after 10000 of charge-discharge cycles proves high electrochemical stability of prepared ICM.

关键词

Keywords

Bacterial celluloseIon conductivityPorous membraneSupercapacitor

references

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Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University

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Ion-conducting Membranes Based on Bacterial Cellulose Nanofibers Modified by Poly(sodium acrylate-co-2-acrylamido-2-methylpropanesulfonic acid)

DOI：10.1007/s10118-023-3054-8

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