Scalable All-biomass Nanofibers: Energy-save Exfoliation and Application as Eco-friendly Functional Coatings
RESEARCH ARTICLE|Updated:2026-11-13
|
Scalable All-biomass Nanofibers: Energy-save Exfoliation and Application as Eco-friendly Functional Coatings
Chinese Journal of Polymer ScienceVol. 44, Pages: 1-11(2026)
Affiliations:
a.Center for Environmental Metrology, National Institute of Metrology, Beijing 100029, China
b.CAS Key Laboratory of Engineering Plastics and CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Zhou, Y.; Xia, Z. H.; Yang, J. Z.; Yin, C. C.; Wen, J. H.; Zhang, J. M.; Wang, H.; Zhang, J. Scalable all-biomass nanofibers: energy-save exfoliation and application as eco-friendly functional coatings. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3886-0
Yan Zhou, Zheng-Hao Xia, Jian-Zheng Yang, et al. Scalable All-biomass Nanofibers: Energy-save Exfoliation and Application as Eco-friendly Functional Coatings[J/OL]. Chinese Journal of Polymer Science, 2026, 441-11.
Zhou, Y.; Xia, Z. H.; Yang, J. Z.; Yin, C. C.; Wen, J. H.; Zhang, J. M.; Wang, H.; Zhang, J. Scalable all-biomass nanofibers: energy-save exfoliation and application as eco-friendly functional coatings. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3886-0DOI:
Yan Zhou, Zheng-Hao Xia, Jian-Zheng Yang, et al. Scalable All-biomass Nanofibers: Energy-save Exfoliation and Application as Eco-friendly Functional Coatings[J/OL]. Chinese Journal of Polymer Science, 2026, 441-11.DOI: 10.1007/s10118-026-3886-0.
Scalable All-biomass Nanofibers: Energy-save Exfoliation and Application as Eco-friendly Functional Coatings
The preparation and application of biomass nanomaterials represent a crucial pathway for the high-value utilization of natural biomass resources. Developing simple and energy-saving strategies for converting biomass into all-biomass nanomaterials is fascinating and of practical value. Herein
we propose a simple and energy-saving method to fabricate all-biomass nanofibers (ANFs) using natural biomass
such as bamboo powder and straw. By removing part of the hemicellulose and lignin
the interactions between the nanofibers in natural biomass are disrupted
resulting in all-biomass micronanofibers. Subsequently
ANFs were obtained by ultrasonic oscillation. The entire process is simple and operates under mild conditions
eliminating the need for energy-intensive high-pressure homogenization or specialized equipment
thereby facilitating scalable production. This method preserves cellulose
along with most hemicellulose and lignin
thus achieving a high biomass utilization rate. Moreover
the retention of hemicellulose and lignin endows the obtained ANFs with desirable properties including ultraviolet resistance and high haze. ANFs can spontaneously form high-strength film and binder-free straws. Based on the nanoscale effect and excellent complete biodegradability
ANFs can be used as eco-friendly functional coatings for fruit and vegetable preservation
as well as high-throughput oil-water separation. Thus
this work not only provides an efficient and energy-saving method for preparing ANFs but also achieves the high-value utilization of low-grade biomass resources.
关键词
Keywords
references
Bhattarai, M.; Al-Terke, H.; Liu, K.; Wan, Z. M.; Kilpelaeinen, P.; King, A. W. T.; Khakalo, A.; Xu, J. Y.; Xu, C. L.; Ras, R. H. A.; Mattos, B. D.; Rojas, O. J. Wood biomolecules as agricultural adjuvants for effective suppression of droplet rebound from plant foliage. Adv. Sci. 2025 , 12 , 2416686 ..
Snyder, P. J.; Allard, V.; Bhagia, S.; Farahi, R. H.; Lereu, A. L.; Backlund, M. P.; Passian, A. Hemicellulose modulates nanoscale lignin architecture in synthetic plant cell walls. ACS Nano 2025 , 19 , 40364−40382..
Zheng, S. S.; Sun, S. L.; Manker, L. P.; Luterbacher, J. S. Aldehyde-stabilization strategies for building biobased consumer products around intact lignocellulosic structures. Acc. Chem. Res. 2025 , 58 , 877−892..
Zhang, W. M.; Niu, W. T.; Tan, F. F.; Li, Y. Selective transformation of biomass and the derivatives for aryl compounds and hydrogen via visible-light-induced radicals. Acc. Chem. Res. 2025 , 58 , 1407−1423..
Xu, J. H.; Zou, Y. J.; Chen, H. J. Y.; Wan, Z. M.; Takagi, A.; Wang, Z. G.; Yu, J.; Liu, L.; Lu, Y.; Fan, Y. M.; Rojas, O. J. Magnetoresponsive cellulose nanofiber hydrogels: dynamic structuring, selective light transmission, and information encoding. ACS Nano 2025 , 19 , 14063−14072..
Li, K.; Clarkson, C. M.; Wang, L.; Liu, Y.; Lamm, M.; Pang, Z. Q.; Zhou, Y. B.; Qian, J.; Tajvidi, M.; Gardner, D. J.; Tekinalp, H.; Hu, L. B.; Li, T.; Ragauskas, A. J.; Youngblood, J. P.; Ozcan, S. Alignment of cellulose nanofibers: harnessing nanoscale properties to macroscale benefits. ACS Nano 2021 , 15 , 3646−3673..
Habibi, Y. Key Advances in the chemical modification of nanocelluloses. Chem. Soc. Rev. 2014 , 43 , 1519−1542..
Li, Z. H.; Chen, C. J.; Xie, H.; Yao, Y.; Zhang, X.; Brozena, A.; Li, J. G.; Ding, Y.; Zhao, X. P.; Hong, M.; Qiao, H . Y.; Smith, L. M.; Pan, X. J.; Briber, R.; Shi, S. Q.; Hu, L. B. Sustainable high-strength macrofibres extracted from natural bamboo. Nat. Sustain. 2022 , 5 , 235−244..
Li, D. H.; Han, Z. M.; Shao, M.; Jiao, Z. J.; Gao, C.; Sun, W. B.; Liu, Z. X.; Yang, K. P.; Guan, Q. F.; Yu, S. H. A robust, biodegradable, and fire-retardant cellulose nanofibers-based structural material fabricated from natural sargassum. Adv. Mater. 2025 , 37 , 2417617..
Ke, Q. F.; Qin, Z. Y.; Zhang, Y. F.; Yang, Y. X.; Zhang, Y. C.; Kou, X. R. Tunable mechanical properties of aroma microcapsules achieved via cellulose nanocrystals interfacial self-assembly strategies. Carbohyd. Polym. 2025 , 368 , 124252..
Parthasarathy, V.; Kumar, P. S.; Albert, A. A.; Krishnasamy, S.; Chandrasekar, M. Recent progress in nanocellulose-based biocomposites for bone tissue engineering and wound healing applications. Carbohyd. Polym. 2025 , 357 , 123455..
Yang, H. B.; Yue, X.; Liu, Z. X.; Guan, Q. F.; Yu, S. H. Emerging sustainable structural materials by assembling cellulose nanofibers. Adv. Mater. 2025 , 37 , 2413564..
Mao, Y. S.; Sheng, Y. H.; Fan, Z. Y.; Yang, J.; Liu, J.; Tang, C. X.; Fu, S. H. Atmospheric pressure dried discontinuous pore gradient structured CNF-based aerogel for ultra-low reflection, broadband, and super-high EMI shielding. Adv. Funct. Mater. 2025 , 35 , 2421492..
[Chen, L. X.; Wang, X.; Zhuo, H. L.; Yin, C. C.; Luo, Q.; Zhang, J.; Zhang, J. M. Functional pharmaceutical excipient from cellulose to enhance the effectiveness of antibiotics and inhibit drug resistance. CCS Chem . 2026 , doi: 10.31635/ccschem.026.202608343..
Qiu, Y. J.; Zhang, D. C.; Long, M.; Zhou, Z. X.; Gao, C. D.; Ma, S.; Qin, J. F.; Chen, K. J.; Chen, C. J.; Zhao, Z.; Deng, H. B. Coassembly of hybrid microscale biomatter for robust, water-processable, and sustainable bioplastics. Sci. Adv. 2025 , 11 , 1596..
Wang, Y. R.; Ma, J. X.; Shao, C.; Yin, C. C.; Wang, Y. L.; Wang, J. F.; Zhang, J. M.; Wang, J. Z.; Zhang, J. Significant Increase of Carrier Mobilities for Efficient and Stable Solar Cells by Repairing Interfaces of Perovskite. CCS Chem. 2026 , 8 , 2387−2402..
Liu, S. L. ; Zhang, Q.; Gou, S. H.; Zhang, L. L.; Wang, Z. G. Esterification of cellulose using carboxylic acid-based deep eutectic solvents to produce high-yield cellulose nanofibers. Carbohyd. Polym. 2021 , 251 , 117018..
Zhou, M.; Chen, D. Z.; Chen, Q. Q.; Chen, P.; Song, G. J.; Chang, C. Y. Reversible surface engineering of cellulose elementary fibrils: from ultralong nanocelluloses to advanced cellulosic materials. Adv. Mater. 2024 , 36 , 2312220..
Yang, X. P.; Abe, K.; Yano, H.; Wang, L. Multifunctional cellulosic materials prepared by a reactive DES based zero-waste system. Nano Lett. 2022 , 22 , 6128−6134..
Sirviö, J. A. Cationization of lignocellulosic fibers with betaine in deep eutectic solvent: facile route to charge stabilized cellulose and wood nanofibers. Carbohyd. Polym. 2018 , 198 , 34−40..
Yang, X.; Reid, M. S.; Olsén, P.; Berglund, L. A. Eco-friendly cellulose nanofibrils designed by nature: effects from preserving native state. ACS Nano 2020 , 14 , 724−735..
Yu, Y. Y.; Cheng, W. K.; Li, Y. L.; Wang, T.; Xia, Q. Q.; Liu, Y. Z.; Yu, H. P. Tailored one-pot lignocellulose fractionation to maximize biorefinery toward versatile xylochemicals and nanomaterials. Green Chem. 2022 , 24 , 3257−3268..
Shi, X. C.; Wang, Z. B.; Liu, S. Y.; Xia, Q. Q.; Liu, Y. Z.; Chen, W. S.; Yu, H. P.; Zhang, K. Scalable production of carboxylated cellulose nanofibres using a green and recyclable solvent. Nat. Sustain. 2024 , 7 , 315−325..
Haque, A. M. A.; Vanniappan, G.; Bayattork, M.; Zhang, Y.; Naebe, M. Green nanofibrillation of hemp cellulose via deep eutectic solvent and simple shear mixing: a response surface approach to process refinement. ACS Sustainable Chem. Eng. 2026 , 14 , 812−826..
Norizan, M. N.; Shazleen, S. S.; Alias, A. H.; Sabaruddin, F. A.; Asyraf, M. R. M.; Zainudin, E. S.; Abdullah, N.; Samsudin, M. S.; Kamarudin, S. H.; Norrrahim, M. N. F. Nanocellulose-based nanocomposites for sustainable applications: a review. Nanomaterials 2022 , 12 , 3483..
Wang, B.; Dai, H. Y.; Zhang, C. H.; Dong, Z. C.; Li, K.; Jiang, L. Nasal cavity inspired micro-nanostructured cone array tube for oil recovery in wastewater. Adv. Mater. Interfaces 2022 , 9 , 2102311..
Satam, C.C.; Irvin, C. W.; Coffey, C. J.; Geran, R. K.; Ibarra-Rivera, R.; Shofner, M. L.; Meredith, J. C. Controlling barrier and mechanical properties of cellulose nanocrystals by blending with chitin nanofibers. Biomacromolecules 2020 , 21 , 545−555..
Ru, J.; Tong, C. C.; Chen, N.; Shan, P. J.; Zhao, X. K.; Liu, X. Y.; Chen, J. Z.; Li, Q.; Liu, X. H.; Zhao, Y. Morphological and property characteristics of surface-quaternized nanofibrillated cellulose derived from bamboo pulp. Cellulose 2019 , 26 , 1683−1701..
Luo, J. Q.; Su, Y. Q.; Liu, J. G.; Li, Q. Oxygen and water vapor barrier properties of nanocellulose materials: a review. Trans. China Pulp Pap . 2019 , 34 , 61−70..
The trial reading is over, you can activate your VIP account to continue reading.
Surface Functionalization Modification of Metal Organic Frameworks with Polymer via Metal-free Atom Transfer Radical Polymerization for Oil-water Separation
Polymer Decorated Zn-MOF (ZIF-8-NH2) for the Fabrication of Superhydrophobic Material via Metal-free Atom Transfer Radical Polymerization
Bioinspired Double-stranded Yarn with Alternating Hydrophobic/Hydrophilic Patterns for High-efficiency Fog Collection
Tunable Circularly Polarized Luminescence of Helical Poly(phenylacetylene)s via Side-chain-to-Backbone Förster Resonance Energy Transfer
Durable Anti-fogging and Abrasion-resistant Coatings Based on Polyoxometalates-Hydrophilic Resin Composites with Enhanced Cohesion and Adhesion
Related Author
Guang Li
Li-Ping Wang
Zi-An Wang
Hong-Ye Li
Bo Ge
Mei-Mei Yang
Yong Zhao
Lan-Lan Hou
Related Institution
School of Materials Science and Engineering, Liaocheng University
Beijing Key Laboratory for Bioengineering and Sensing, Technology, Daxing Research Institute, School of Chemistry and Biological Engineering, University of Science and Technology Beijing
Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences
Key Laboratory of Bioinspired Smart Interfacial Science and Technology of Ministry of Education, Beijing Key Laboratory of Bioinspired Energy Materials and Devices, School of Chemistry, Beijing Advanced Innovation Center for Biomedical Engineering, Beihang University