An Efficient Catalytic System for Room-temperature Stille Polymerization

Yi-Ming Shao; Xiao-Hei Wu; Lin-Yong Xu; Xin-Rong Yang; Rui Sun; Jie Min

doi:10.1007/s10118-026-3826-z

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An Efficient Catalytic System for Room-temperature Stille Polymerization

RESEARCH ARTICLE | Updated：2026-09-30

- An Efficient Catalytic System for Room-temperature Stille Polymerization
- Chinese Journal of Polymer Science Vol. 44, Pages: 1-10(2026)
- Affiliations：
  
  a.Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, College of Chemistry and Chemical Engineering, Hubei Normal University, Huangshi 435002, China
  b.The Institute for Advanced Studies, Wuhan University, Wuhan 430072, China
- Author bio：
  
  sym@hbnu.edu.cn (Y.M.S.)
  sun.rui@whu.edu.cn (R.S.)
  min.jie@whu.edu.cn (J.M.)
- Funds：
- DOI：10.1007/s10118-026-3826-z
  CLC：
- Received：02 June 2026，
  
  Accepted：24 July 2026，
  
  Online First：30 September 2026，
  
  Published：2026-09
- Accepted：
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Shao, Y. M.; Wu, X. H.; Xu, L. Y.; Yang, X. R.; Sun, R.; Min, J. An efficient catalytic system for room-temperature stille polymerization. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3826-z

Yi-Ming Shao, Xiao-Hei Wu, Lin-Yong Xu, et al. An Efficient Catalytic System for Room-temperature Stille Polymerization[J/OL]. Chinese Journal of Polymer Science, 2026, 441-10.
Shao, Y. M.; Wu, X. H.; Xu, L. Y.; Yang, X. R.; Sun, R.; Min, J. An efficient catalytic system for room-temperature stille polymerization. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3826-z DOI：

Yi-Ming Shao, Xiao-Hei Wu, Lin-Yong Xu, et al. An Efficient Catalytic System for Room-temperature Stille Polymerization[J/OL]. Chinese Journal of Polymer Science, 2026, 441-10. DOI： 10.1007/s10118-026-3826-z.

摘要

Abstract

Donor-acceptor conjugated polymers are vital materials for organic electronics

but traditional thermally driven Stille polymerization suffers from unavoidable homocoupling defects and batch vari

ations. In this study

we developed an efficient room-temperature Stille catalytic system using P(

-Bu)

Pd(crotyl)Cl as the precatalyst and CsF as the base. This method displays broad substrate universality

affording various conjugated polymers with fewer homocoupling fragments than the traditional methods. This work provides a mild

general route toward high-performance

regio-regular conjugated polymers.

关键词

Keywords

references

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