

FOLLOWUS
a.College of Materials Science and Engineering, China University of Petroleum-Beijing, Beijing 102249, China
b.Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology, Beijing 100190, China
c.Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Science, Beijing 100049, China
d.School of Chemistry and Pharmaceutical Engineering, Shandong First Medical University & Shandong Academy of Medical Sciences, Taian 271016, China
guold@nanoctr.cn (L.D.G.)
occb@163.com (C.B.C.)
sunxn@nanoctr.cn (X.N.S.)
Received:30 April 2026,
Accepted:19 July 2026,
Online First:10 October 2026,
Published:2026-09
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Zhang, C.; Guo, L. D.; Cong, C. B.; Zhou, Q.; Sun, X. N. Recent progress in spin transport dynamics in organic semiconductors. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3820-5
Cheng Zhang, Li-Dan Guo, Chuan-Bo Cong, et al. Recent Progress in Spin Transport Dynamics in Organic Semiconductors[J/OL]. Chinese Journal of Polymer Science, 2026, 441-19.
Zhang, C.; Guo, L. D.; Cong, C. B.; Zhou, Q.; Sun, X. N. Recent progress in spin transport dynamics in organic semiconductors. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3820-5 DOI:
Cheng Zhang, Li-Dan Guo, Chuan-Bo Cong, et al. Recent Progress in Spin Transport Dynamics in Organic Semiconductors[J/OL]. Chinese Journal of Polymer Science, 2026, 441-19. DOI: 10.1007/s10118-026-3820-5.
Organic semiconductors (OSCs) have emerged as a compelling materials platform for spintronic research due to their light-element composition generally gives rise to weak spin–orbit coupling and hyperfine interactions
thereby enabling long spin relaxation time and spin diffusion length even at room temperature. These features have stimulated extensive interest in spin transport dynamics in OSCs
and rapid progress in both experimental characterization and theoretical modeling has substantially deepened on the understanding of spin transport
spin relaxation
and spin-dependent interactions in OSCs. In this Review
we provide a comprehensive overview of recent advances in spin transport dynamics in OSCs
with emphasis on spin transport characteristics
spin relaxation strengths and mechanisms in organic films
and spin transport processes in representative device architectures. Finally
we outline the key challenges that remain and highlight emerging opportunities for advancing the fundamental understanding and practical applications of organic spintronics.
Xiong, Z. H.; Wu, D.; Vardeny, Z. V.; Shi, J. Giant magnetoresistance in organic spin-valves. Nature 2004 , 427 , 821−824..
Xie, Z.; Liu, D.; Gao, C.; Zhang, X.; Dong, H.; Hu, W. High mobility emissive organi c semiconductors for optoelectronic devices. J. Am. Chem. Soc. 2025 , 147 , 2239−2256..
Meng, K.; Li, M.; Guo, L.; Zhang, R.; Guo, A.; Liu, M.; Gu, X.; Qin, Y.; Yang, T.; Yang, X.; Hu, S.; Zhang, C.; Zheng, R.; Wu, M.; Sun, X. Room-temperature organic spintronic devices with wide range magnetocurrent tuning and multifunctionality via electro-optical compensation strategy. Adv. Mater. 2025 , 37 , 2417995..
Fu, D.; Liu, J.; Hou, F.; Chang, X.; Qu, T.; Félisaz, J.; Krishnaswamy, G. K.; Grebenchuk, S.; Jie, Y.; Watanabe, K.; Taniguchi, T.; Pereira, V. M.; Novoselov, K. S.; Koperski, M.; Yakovlev, N. L.; Soumyanarayanan, A.; Avsar, A.; Yazyev, O. V.; Lin, J.; Özyilmaz, B. Electric field-tunable ferromagnetism in a van der Waals semiconductor up to room temperature. Nat. Commun. 2025 , 16 , 10197..
Cornia, A.; Seneor, P. Spintronics: the molecular way. Nat. Mater. 2017 , 16 , 505−506..
Vardeny, V. Organics strike back. Nat. Mater. 2009 , 8 , 91−93..
Dediu, V. A.; Hueso, L. E.; Be rgenti, I.; Taliani, C. Spin routes in organic semiconductors. Nat. Mater. 2009 , 8 , 707−716..
Galbiati, M.; Barraud, C.; Tatay, S.; Bouzehouane, K.; Deranlot, C.; Jacquet, E.; Fert, A.; Seneor, P.; Mattana, R.; Petroff, F. Unveiling self-assembled monolayers' potential for molecular spintronics: spin transport at high voltage. Adv. Mater. 2012 , 24 , 6429−6432..
Hu, S.; Liu, W.; Guo, L.; Zhang, R.; Gu, X.; Meng, K.; Qin, Y.; Guo, A.; Yang, T.; Zhang, C.; Yang, X.; Lu, S.; Wu, M.; Lu, K.; Tan, T.; Zhou, E.; Wei, Z.; Sun, X. Continuous room-temperature spin-injection modulation achieved by spin-filtering competition in molecular spin valves. Adv. Mater. 2023 , 35 , 2300055..
Rybicki, J.; Lin, R.; Wang, F.; Wohlgenannt, M.; He, C.; Sanders, T.; Suzuki, Y. Tuning the performance of organic spintronic devices using X-ray generated traps. Phys. Rev. Lett. 2012 , 109 , 076603..
Qin, Y.; Wu, M.; Xiang, J.; Yang, T.; Guo, L.; Gu, X.; Zhang, R.; Zhang, X.; Meng, K.; Hu, S.; Zheng, R.; Li, M.; Wang, Y.; Zou, Y.; Zhang, J.; Gao, X.; Sun, X. Enhancing room-temperature spin lifetimes in molecular semiconductors by designing intramolecular dipole orientations. Adv. Mater. 2025 , 37 , 2500521..
Yang, T.; Qin, Y.; Wu, M.; Guo, L.; Gu, X.; Meng, K.; Hu, S.; Zhang, C.; Zheng, R.; Zhang, R.; Sun, X. Structural isomeric effect on spin transport in molecular semiconductors. Adv. Mater. 2024 , 36 , 2402001..
Hu, S.; Qin, Y.; Lu, S.; Guo, L.; Gu, X.; Yang, T.; Zhang, R.; Meng, K.; Zhang, C.; Wu, M.; Sun, X. Interface engineering for enhancing air-stable spin-charge interaction in molecular spin-photovoltaic devices. Adv. Funct. Mater. 2024 , 34 , 2315239..
Yang, W.; Shi, Q.; Miao, T.; Li, Q.; Cai, P.; Liu, H.; Lin, H.; Bai, Y.; Zhu, Y.; Yu, Y.; Deng, L.; Wang, W.; Yin, L.; Sun, D.; Zhang, X.-G.; Shen, J. Achieving large and nonvolatile tunable magnetoresistance in organic spin valves using electronic phase separated manganites. Nat. Commun. 2019 , 10 , 3877..
Xu, J.; Jarocha, L. E.; Zollitsch, T.; Konowalczyk, M.; Henbest, K. B.; Richert, S.; Golesworthy, M. J.; Schmidt, J.; Déjean, V.; Sowood, D. J. C.; Bassetto, M.; Luo, J.; Walton, J. R.; Fleming, J.; Wei, Y.; Pitcher, T. L.; Moise, G.; Herrmann, M.; Yin, H.; Wu, H.; Bartölke, R.; Käsehagen, S. J.; Horst, S.; Dautaj, G.; Murton, P. D. F.; Gehrckens, A. S.; Chelliah, Y.; Takahashi, J. S.; Koch, K.-W.; Weber, S.; Solov’yov, I. A.; Xie, C .; MacKenzie, S. R.; Timmel, C. R.; Mouritsen, H.; Hore, P. J. Magnetic sensitivity of cryptochrome 4 from a migratory songbird. Nature 2021 , 594 , 535−540..
Geng, R.; Mena, A.; Pappas, W. J.; McCamey, D. R. Sub-micron spin-based magnetic field imaging with an organic light emitting diode. Nat. Commun. 2023 , 14 , 1441..
Devkota, J.; Geng, R.; Subedi, R. C.; Nguyen, T. D. Organic spin valves: a review. Adv. Funct. Mater. 2016 , 26 , 3881−3898..
Sun, X.; Vélez, S.; Atxabal, A.; Bedoya-Pinto, A.; Parui, S.; Zhu, X.; Llopis, R.; Casanova, F.; Hueso, L. E. A molecular spin-photovoltaic device. Science 2017 , 357 , 677−680..
Sun, X.; Gobbi, M.; Bedoya-Pinto, A.; Txoperena, O.; Golmar, F.; Llopis, R.; Chuvilin, A.; Casanova, F.; Hueso, L. E. Room-temperature air-stable spin transport in bathocuproine-based spin valves. Nat. Commun. 2013 , 4 , 2794..
Groesbeck, M.; Liu, H.; Kavand, M.; Lafalce, E.; Wang, J.; Pan, X.; Tennahewa, T. H.; Popli, H.; Malissa, H.; Boehme, C.; Vardeny, Z. V. Separation of spin and charge transport in pristine π-conjugated polymers. Phys. Rev. Lett. 2020 , 124 , 067702..
Shah, B.; Anderson, S. W.; Scalera, J.; Jara, H.; Soto, J. A. Quantitative MR imaging: physical principles and sequence design in abdominal imaging. Radiographics 2011 , 31 , 867−880..
Awojoyogbe, O. B.; Dada, O. M.; Faromika, O. P.; Dada, O. E. Mathematical concept of the Bloch flow equations for general magnetic resonance imaging: a review. Concepts Magn. Reson. Part A 2011 , 38A , 85−101..
Bhalekar, S.; Daftardar-Gejji, V.; Baleanu, D.; Magin, R. Fractional Bloch equation with delay. Comput. Math. Appl. 2011 , 61 , 1355−1365..
Jiang, S. W.; Wang, P.; Chen, B. B.; Zhou, Y.; Ding, H. F.; Wu, D. Tuning carrier mobility without spin transport degrading in copper-phthalocyanine. Appl. Phys. Lett. 2015 , 107 , 042407..
Guo, L.; Gu, X.; Hu, S.; Sun, W.; Zhang, R.; Qin, Y.; Meng, K.; Lu, X.; Liu, Y.; Wang, J.; Ma, P.; Zhang, C.; Guo, A.; Yang, T.; Yang, X.; Wang, G.; Liu , Y.; Wang, K.; Mi, W.; Zhang, C.; Jiang, L.; Liu, L.; Zheng, K.; Qin, W.; Yan, W.; Sun, X. Strain-restricted transfer of ferromagnetic electrodes for constructing reproducibly superior-quality spintronic devices. Nat. Commun. 2024 , 15 , 865..
Julliere, M. Tunneling between ferromagnetic films. Phys. Lett. A 1975 , 54 , 225−226..
Sarkar, S.; Oh, S.; Newton, P. J.; Li, Y.; Zhu, Y.; Ghani, M. A.; Yan, H.; Jeong, H. Y.; Wang, Y.; Chhowalla, M. Spin injection in graphene using ferromagnetic van der Waals contacts of indium and cobalt. Nat. Electron. 2025 , 8 , 215−221..
Liu, H.; Zhang, C.; Malissa, H.; Groesbeck, M.; Kavand, M.; McLaughlin, R.; Jamali, S.; Hao, J.; Sun, D.; Davidson, R. A.; Wojcik, L.; Miller, J. S.; Boehme, C.; Vardeny, Z. V. Organic-based magnon spintronics. Nat. Mater. 2018 , 17 , 308−312..
Atodiresei, N.; Brede, J.; Lazić, P.; Caciuc, V.; Hoffmann, G.; Wiesendanger, R.; Blügel, S. Design of the local spin polarization at the organic-ferromagnetic interface. Phys. Rev. Lett. 2010 , 105 , 066601..
Geng, R.; Subedi, R. C.; Luong, H. M.; Pham, M. T.; Huang, W.; Li, X.; Hong, K.; Shao, M.; Xiao, K.; Hornak, L. A.; Nguyen, T. D. Effect of charge localization on the effective hyperfine interaction in organic semiconducting polymers. Phys. Rev. Lett. 2018 , 120 , 086602..
Sun, D.; Fang, M.; Xu, X.; Jiang, L.; Guo, H.; Wang, Y.; Yang, W.; Yin, L.; Snijders, P. C.; Ward, T. Z.; Gai, Z.; Zhang, X.-G.; Lee, H. N.; Shen, J. Active control of magnetoresistance of organic spin valves using ferroelectricity. Nat. Commun. 2014 , 5 , 4396..
Drew, A. J.; Hoppler, J.; Schulz, L.; Pratt, F. L.; Desai, P.; Shakya, P.; Kreouzis, T.; Gillin, W. P.;Suter, A.; Morley, N. A.; Malik, V. K.; Dubroka, A.; Kim, K. W.; Bouyanfif, H.; Bourqui, F.; Bernhard, C.; Scheuermann, R.; Nieuwenhuys, G. J.; Prokscha, T.; Morenzoni, E. Direct measurement of the electronic spin diffusion length in a fully functional organic spin valve by low-energy muon spin rotation. Nat. Mater. 2009 , 8 , 109−114..
Ding, S.; Tian, Y.; Wang, H.; Zhou, Z.; Mi, W.; Ni, Z.; Zou, Y.; Dong, H.; Gao, H.; Zhu, D.; Hu, W. Reliable spin valves of conjugated polymer based on mechanically transferrable top electrodes. ACS Nano 2018 , 12 , 12657−12664..
Jedema, F. J.; Filip, A. T.; van Wees, B.J. Electrical spin injection and accumulation at room temperature in an all-metal mesoscopic spin valve. Nature 2001 , 410 , 345−348..
Yu, Z. G.; Baker, J.; Krishnamurthy, S. Transfer lengths and spin injection from a three-dimensional ferromagnet into graphene. Phys. Rev. B 2010 , 82 , 035425..
Yang, T.; Kimura, T.; Otani, Y. Giant spin-accumulation signal and pure spin-current-induced reversible magnetization switching. Nat. Phys. 2008 , 4 , 851−854..
Rashba, E. I. Theory of electrical spin injection: tunnel contacts as a solution of the conductivity mismatch problem. Phys. Rev. B 2000 , 62 , R16267−R16270..
Schmidt, G.; Ferrand, D.; Molenkamp, L.; Filip, A.; van Wees, B. Fundamental obstacle for electrical spin injection from a ferromagnetic metal into a diffusive semiconductor. Phys. Rev. B Condens. Matter Mater. Phys. 2000 , 62 , R4790−R4793..
Ando, K.; Watanabe, S.; Mo oser, S.; Saitoh, E.; Sirringhaus, H. Solution-processed organic spin–charge converter. Nat. Mater. 2013 , 12 , 622−627..
Kajiwara, Y.; Harii, K.; Takahashi, S.; Ohe, J.; Uchida, K.; Mizuguchi, M.; Umezawa, H.; Kawai, H.; Ando, K.; Takanashi, K.; Maekawa, S.; Saitoh, E. Transmission of electrical signals by spin-wave interconversion in a magnetic insulator. Nature 2010 , 464 , 262−266..
Ando, K.; Takahashi, S.; Ieda, J.; Kurebayashi, H.; Trypiniotis, T.; Barnes, C. H. W.; Maekawa, S.; Saitoh, E. Electrically tunable spin injector free from the impedance mismatch problem. Nat. Mater. 2011 , 10 , 655−659..
Tran, T. L. A.; Le, T. Q.; Sanderink, J. G. M.; van der Wiel, W. G.; de Jong, M. P. The multistep tunneling analogue of conductivity mismatch in organic spin valves. Adv. Funct. Mater. 2012 , 22 , 1180−1189..
Kimura, T.; Otani, Y.; Sato, T.; Takahashi, S.; Maekawa, S. Room-temperature reversible spin Hall effect. Phys. Rev. Lett. 2007 , 98 , 156601..
Saitoh, E.; Ueda, M.; Miyaji ma, H.; Tatara, G. Conversion of spin current into charge current at room temperature: inverse spin-Hall effect. Appl. Phys. Lett. 2006 , 88 , 182509..
Wittmann, A.; Schweicher, G.; Broch, K.; Novak, J.; Lami, V.; Cornil, D.; McNellis, E. R.; Zadvorna, O.; Venkateshvaran, D.; Takimiya, K.; Geerts, Y. H.; Cornil, J.; Vaynzof, Y.; Sinova, J.; Watanabe, S.; Sirringhaus, H. Tuning spin current injection at ferromagnet-nonmagnet interfaces by molecular design. Phys. Rev. Lett. 2020 , 124 , 027204..
Tserkovnyak, Y.; Brataas, A.; Bauer, G. E. W. Spin pumping and magnetization dynamics in metallic multilayers. Phys. Rev. B 2002 , 66 , 224403..
Ando, K.; Takahashi, S.; Ieda, J.; Kajiwara, Y.; Nakayama, H.; Yoshino, T.; Harii, K.; Fujikawa, Y.; Matsuo, M.; Maekawa, S.; Saitoh, E. Inverse spin-Hall effect induced by spin pumping in metallic system. J. Appl. Phys. 2011 , 109 , 103913..
Jiao, H.; Bauer, G. E. W. Spin backflow and AC voltage generation by spin pumping and the inverse spin Hall effect. Phys. Rev. Lett. 2013 , 110 , 217602..
Sun, D.; van Schooten, K. J.; Kavand, M.; Malissa, H.; Zhang, C.; Groesbeck, M.; Boehme, C.; Vardeny, Z. V. Inverse spin Hall effect from pulsed spin current in organic semiconductors with tunable spin-orbit coupling. Nat. Mater. 2016 , 15 , 863−869..
Li, T.; Xu, L.; Xiao, X.; Chen, F.; Cao, L.; Wu, W.; Tong, W.; Zhang, F. Enhanced spin transport of conjugated polymer in the semiconductor/insulating polymer blend. ACS Appl. Mater. Interfaces 2020 , 12 , 2708−2716..
Wang, S.-J.; Venkateshvaran, D.; Mahani, M. R.; Chopra, U.; McNellis, E. R.; Di Pietro, R.; Schott, S.; Wittmann, A.; Schweicher, G.; Cubukcu, M.; Kang, K.; Carey, R.; Wagner, T. J.; Siebrecht, J. N. M.; Wong, D. P. G. H.; Jacobs, I. E.; Aboljadayel, R. O.; Ionescu, A.; Egorov, S. A.; Mueller, S.; Zadvorna, O.; Skalski, P.; Jellett, C.; Little, M.; Marks, A.; McCulloch, I.; Wunderlich, J.; Sinova, J.; Sirringhaus, H. Long spin diffusion lengths in doped conjugated polymers due to enhanced exchange coupling. Nat. Electron. 2019 , 2 , 98−107..
Uchida, K. I.; Adachi, H.; Kikkawa, T.; Kirihara, A.; Ishida, M.; Yorozu, S.; Maekawa, S.; Saitoh, E. Thermoelectric generation based on spin seebeck effects. Proc. IEEE 2016 , 104 , 1946−1973..
Slachter, A.; Bakker, F. L.; Adam, J. P.; van Wees, B. J. Thermally driven spin injection from a ferromagnet into a non-magnetic metal. Nat. Phys. 2010 , 6 , 879−882..
Wang, P.; Zhou, L. F.; Jiang, S. W.; Luan, Z. Z.; Shu, D. J.; Ding, H. F.; Wu, D. Unidirectional spin-wave-propagation-induced seebeck voltage in a PEDOT:PSS/YIG bilayer. Phys. Rev. Lett. 2018 , 120 , 047201..
Mosendz, O.; Pearson, J. E.; Fradin, F. Y.; Bauer, G. E. W.; Bader, S. D.; Hoffmann, A. Quantifying spin hall angles from spin pumping: experiments and theory. Phys. Rev. Lett. 2010 , 104 , 046601..
Wang, P.; Jiang, S. W.; Luan, Z. Z.; Zhou, L. F.; Ding, H. F.; Zhou, Y.; Tao, X. D.; Wu, D. Spin rectification induced by spin Hall magnetoresistance at room temperature. Appl. Phys. Lett. 2016 , 109 , 112406..
Miao, B. F.; Huang, S. Y.; Qu, D.; Chien, C. L. Inverse spin Hall effect in a ferromagnetic metal. Phys. Rev. Lett. 2013 , 111 , 066602..
Jiang, S. W.; Liu, S.; Wang, P.; Luan, Z. Z.; Tao, X. D.; Ding, H. F.; Wu, D. Exchange-dominated pure spin current transport in Alq3 molecules. Phys. Rev. Lett. 2015 , 115 , 086601..
Zhang, C.; Guo, L.; Cong, C.; Zhou, Q.; Sun, X. Organic spintronic materials: recent progress and emerging multifunctionalities. CCS Chem. 2026 , 8 , 716−735..
Shikoh, E.; Ando, K.; Kubo, K.; Saitoh, E.; Shinjo, T.; Shiraishi, M. Spin-pump-induced spin transport in p-type Si at room temperature. Phys. Rev. Lett. 2013 , 110 , 127201..
Pramanik, S.; Stefanita, C.-G.; Patibandla, S.; Bandyopadhyay, S.; Garre, K.; Harth, N.; Cahay, M. Observation of extremely long spin relaxation times in an organic nanowire spin valve. Nat. Nanotechnol. 2007 , 2 , 216−219..
Tsurumi, J.; Matsui, H.; Kubo, T.; Häusermann, R.; Mitsui, C.; Okamoto, T.; Watanabe, S.; Takeya, J. Coexistence of ultra-long spin relaxation time and coherent charge transport in organic single-crystal semiconductors. Nat. Phys. 2017 , 13 , 994−998..
Schott, S.; Chopra, U.; Lemaur, V.; Melnyk, A.; Olivier, Y.; Di Pietro, R.; Romanov, I.; Carey, R. L.; Jiao, X.; Jellett, C.; Little, M.; Marks, A.; McNeill, C. R.; McCulloch, I.; McNellis, E. R.; Andrienko, D.; Beljonne, D.; Sinova, J.; Sirringhaus, H. Polaron spin dynamics in high-mobility polymeric semiconductors. Nat. Phys. 2019 , 15 , 814−822..
Watanabe, S.; Ando, K.; Kang, K.; Mooser, S.; Vaynzof, Y.; Kurebayashi, H.; Saitoh, E.; Sirringhaus, H. Polaron spin current transport in organic semiconductors. Nat. Phys. 2014 , 10 , 308−313..
Mooser, S.; Cooper, J. F. K.; Banger, K. K.; Wunderlich, J.; Sirringhaus, H. Spin injection and transport in a solution-processed organic semiconductor at room temperature. Phys. Rev. B 2012 , 85 , 235202..
Giannini, S.; Carof, A.; Blumberger, J. Crossover from hopping to band-like charge transport in an organic semiconductor model: atomistic nonadiabatic molecular dynamics simulation. J. Phys. Chem. Lett. 2018 , 9 , 3116−3123..
Nguyen, T. D.; Basel, T. P.; Pu, Y. J.; Li, X. G.; Ehrenfreund, E.; Vardeny, Z. V. Isotope effect in the spin response of aluminum tris(8-hydroxyquinoline) based devices. Phys. Rev. B 2012 , 85 , 245437..
Wang, G.; Liu, B. L.; Balocchi, A.; Renucci, P.; Zhu, C. R.; Amand, T.; Fontaine, C.; Marie, X. Gate control of the electron spin-diffusion length in semiconductor quantum wells. Nat. Commun. 2013 , 4 , 2372..
Meng, K.; Guo, L.; Sun, X. Strategies and applications of generating spin polarization in organic semiconductors. Nanoscale Horiz. 2023 , 8 , 1132−1154..
Li, L.; Lu, N.; Liu, M.; Bässler, H. General Einstein relation model in disordered organic semiconductors under quasiequilibrium. Phys. Rev. B 2014 , 90 , 214107..
Wetzelaer, G. A. H.; Koster, L. J. A.; Blom, P. W. M. Validity of the Einstein relation in disordered organic semiconductors. Phys. Rev. Lett. 2011 , 107 , 066605..
[Hanle, W. Über magnetische beeinflussung der polarisation der resonanzfluoreszenz. Z. Für Phys . 1924 , 30 , 93−105..
Parsons, R. R. Band-to-band optical pumping in solids and polarized photoluminescence. Phys. Rev. Lett. 1969 , 23 , 1152−1154..
Johnson, M.; Silsbee, R. Interfacial charge-spin coupling: injection and detection of spin magnetization in metals. Phys. Rev. Lett. 1985 , 55 , 1790−1793..
Johnson, M.; Silsbee, R. H. Spin-injection experiment. Phys. Rev. B 1988 , 37 , 5326−5335..
Johnson, M.; Silsbee, R. Coupling of electronic charge and spin at a ferromagnetic-paramagnetic metal interface. Phys. Rev. B 1988 , 37 , 5312−5325..
Lou, X.; Adelmann, C.; Furis, M.; Crooker, S. A.; Palmstrøm, C. J.; Crowell, P. A. Electrical detection of spin accumulation at a ferromagnet-semiconductor interface. Phys. Rev. Lett. 2006 , 96 , 176603..
Lou, X.; Adelmann, C.; Crooker, S. A.; Garlid, E. S.; Zhang, J.; Madhukar Reddy, K. S.; Flexner, S. D.; Palmstrøm, C. J.; Crowell, P. A. Electrical detection of spin transpo rt in lateral ferromagnet–semiconductor devices. Nat. Phys. 2007 , 3 , 197−202..
Jedema, F. J.; Heersche, H. B.; Filip, A. T.; Baselmans, J. J. A.; van Wees, B. J. Electrical detection of spin precession in a metallic mesoscopic spin valve. Nature 2002 , 416 , 713−716..
Tombros, N.; Jozsa, C.; Popinciuc, M.; Jonkman, H. T.; van Wees, B. J. Electronic spin transport and spin precession in single graphene layers at room temperature. Nature 2007 , 448 , 571−574..
Dash, S. P.; Sharma, S.; Patel, R. S.; de Jong, M. P.; Jansen, R. Electrical creation of spin polarization in silicon at room temperature. Nature 2009 , 462 , 491−494..
Han, W.; Jiang, X.; Kajdos, A.; Yang, S.-H.; Stemmer, S.; Parkin, S. S. P. Spin injection and detection in lanthanum- and niobium-doped SrTiO 3 using the Hanle technique. Nat. Commun. 2013 , 4 , 2134..
Appelbaum, I. Introduction to spin-polarized ballistic hot electron injection and detection in silicon. Phil. Trans. R. Soc. A. 2011 , 369 , 3554−3574..
Huang, B.; Monsma, D. J.; Appelbaum, I. Coherent spin transport through a 350 micron thick silicon wafer. Phys. Rev. Lett. 2007 , 99 , 177209..
Appelbaum, I.; Huang, B.; Monsma, D. J. Electronic measurement and control of spin transport in silicon. Nature 2007 , 447 , 295−298..
Grünewald, M.; Göckeritz, R.; Homonnay, N.; Würthner, F.; Molenkamp, L. W.; Schmidt, G. Vertical organic spin valves in perpendicular magnetic fields. Phys. Rev. B 2013 , 88 , 085319..
Huang, B.; Jang, H. J.; Appelbaum, I. Geometric dephasing-limited Hanle effect in long-distance lateral silicon spin transport devices. Appl. Phys. Lett. 2008 , 93 , 162508..
Riminucci, A.; Yu, Z. G.; Prezioso, M.; Cecchini, R.; Bergenti, I.; Graziosi, P.; Dediu, V. A. Controlling magnetoresistance by oxygen impurities in Mq3-based molecular spin valves. ACS Appl. Mater. Interfaces 2019 , 11 , 8319−8326..
Yu, Z. G. Suppression of the hanle effect in organic spintronic devices. Phys. Rev. Lett. 2013 , 111 , 016601..
Carey, R. L.; Giannini, S.; Schott, S.; Lemaur, V.; Xiao, M.; Prodhan, S.; Wang, L.; Bovoloni, M.; Quarti, C.; Beljonne, D.; Sirringhaus, H. Spin relaxation of electron and hole polarons in ambipolar conjugated polymers. Nat. Commun. 2024 , 15 , 288..
Li, D.; Yu, G. Innovation of materials, devices, and functionalized interfaces in organic spintronics. Adv. Funct. Mater. 2021 , 31 , 2100550..
Yang, T.; Qin, Y.; Wu, M.; Gu, X.; Meng, K.; Hu, S.; Zhang, C.; Guo, A.; Zheng, R.; Zhang, R.; Guo, L.; Sun, X. Spin-lifetime probe for detecting intramolecular noncovalent interaction in organic semiconductors. Adv. Mater. 2024 , 36 , 2410695..
Marumoto, K.; Kuroda, S.-I.; Takenobu, T.; Iwasa, Y. Spatial extent of wave functions of gate-induced hole carriers in pentacene field-effect devices as investigated by electron spin resonance. Phys. Rev. Lett. 2006 , 97 , 256603..
Matsui, H.; Hasegawa, T.; Tokura, Y.; Hiraoka, M.; Yamada, T. Polaron motional narrowing of electron spin resonance in organic field-effect transistors. Phys. Rev. Lett. 2008 , 100 , 126601..
Schott, S.; McNellis, E. R.; Nielsen, C. B.; Chen, H.Y.; Watanabe, S.; Tanaka, H.; McCulloch, I.; Takimiya, K.; Sinova, J.; Sirringhaus, H. Tuning the effective spin-orbit coupling in molecular semiconductors. Nat. Commun. 2017 , 8 , 15200..
Harmon, N. J.; Flatté, M. E. Distinguishing spin relaxation mechanisms in organic semiconductors. Phys. Rev. Lett. 2013 , 110 , 176602..
Bandyopadhyay, S. Dominant spin relaxation mechanism in compound organic semiconductors. Phys. Rev. B 2010 , 81 , 153202..
Harmon, N. J.; Flatté, M. E. Spin relaxation in materials lacking coherent charge transport. Phys. Rev. B 2014 , 90 , 115203..
Sheng, Y.; Nguyen, T. D.; Veeraraghavan, G.; Mermer, Wohlgenannt, M.; Qiu, S.; Scherf, U. Hyperfine interaction and magnetoresistance in organic semiconductors. Phys. Rev. B 2006 , 74 , 045213..
Nuccio, L.; Willis, M.; Schulz, L.; Fratini, S.; Messina, F.; D’Amico, M.; Pratt, F. L.; Lord, J. S.; McKenzie, I.; Loth, M.; Purushothaman, B.; Anthony, J.; Heeney, M.; Wilson, R. M.; Hernández, I.; Cannas, M.; Sedlak, K.; Kreouzis, T.; Gillin, W. P.; Bernhard, C.; Drew, A. J. Importance of spin-orbit interaction for the electron spin relaxation in organic semiconductors. Phys. Rev. Lett. 2013 , 110 , 216602.
Chen, B. B.; Wang, S.; Jiang, S. W.; Yu, Z. G.; Wan, X. G.; Ding, H. F.; Wu, D. The role of heavy metal ions on spin transport in organic semiconductors. New J. Phys. 2015 , 17 , 013004..
Zhang, Y.; Bai, H.; Han, L.; Chen, C.; Zhou, Y.; Back, C. H.; Pan, F.; Wang, Y.; Song, C. Simultaneous high charge-spin conversion efficiency and large spin diffusion length in altermagnetic RuO 2 . Adv. Funct. Mater. 2024 , 34 , 2313332..
Wang, H. L.; Du, C. H.; Pu, Y.; Adur, R.; Hammel, P. C.; Yang, F. Y. Scaling of spin hall angle in 3d, 4d, and 5d metals from Y 3 Fe 5 O 12 /metal spin pumping. Phys. Rev. Lett. 2014 , 112 , 197201..
Sun, R.; Park, K. S.; Comstock, A. H.; McConnell, A.; Chen, Y.-C.; Zhang, P.; Beratan, D.; You, W.; Hoffmann, A.; Yu, Z.-G.; Diao, Y.; Sun, D. Inverse chirality-induced spin selectivity effect in chiral assemblies of π-conjugated polymers. Nat. Mater. 2024 , 23 , 782−789..
Lee, J. W.; Oh, Y. W.; Park, S. Y.; Figueroa, A. I.; van der Laan, G.; Go, G.; Lee, K. J.; Park, B. G. Enhanced spin-orbit torque by engineering Pt resistivity in Pt/Co/AlO x structures. Phys. Rev. B 2017 , 96 , 064405..
Paul, B.; Ghosh, T. K. Understanding spin Hall effect in two-dimensional Fermionic systems with generic spin–orbit interaction in III-V heterostructures. Phys. Lett. A 2015 , 379 , 728−731..
Neese, F. Prediction of electron paramagnetic resonance g values using coupled perturbed Hartree–Fock and Kohn–Sham theory. J. Chem. Phys. 2001 , 115 , 11080−11096..
Yang, X.; Guo, A.; Yang, J.; Chen, J.; Meng, K.; Hu, S.; Duan, R.; Zhu, M.; Shi, W.; Qin, Y.; Zhang, R.; Yang, H.; Li, J.; Guo, L.; Sun, X.; Liu, Y.; Guo, Y. Halogenated-edge polymeric semiconductor for efficient spin transport. Nat. Commun. 2024 , 15 , 8368..
Yu, Z. G. Spin-orbit coupling and its effects in organic solids. Phys. Rev. B 2012 , 85 , 115201..
Yu, Z. G. Spin-orbit coupling, spin relaxation, and spin diffusion in organic solids. Phys. Rev. Lett. 2011 , 106 , 106602..
Dediu, V.; Murgia, M.; Matacotta, F. C.; Taliani, C.; Barbanera, S. Room temperature spin polarized injection in organic semiconductor. Solid State Commun. 2002 , 122 , 181−184..
Liang, S.; Geng, R.; Yang, B.; Zhao, W.; Subedi, R. C.; Li, X.; Han, X.; Nguyen, T. D. Curvature-enhanced spin-orbit coupling and spinterface effect in fullerene-based spin valves. Sci. Rep. 2016 , 6 , 19461..
Nguyen, T. D.; Wang, F.; Li, X.-G.; Ehrenfreund, E.; Vardeny, Z. V. Spin diffusion in fullerene-based devices: morphology effect. Phys. Rev. B 2013 , 87 , 075205..
Wilson, J. S.; Dhoot, A. S.; Seeley, A. J. A. B.; Khan, M. S.; Köhler, A.; Friend, R. H. Spin-dependent exciton formation in π-conjugated compounds. Nature 2001 , 413 , 828−831..
Sheng, C. X.; Singh, S.; Gambetta, A.; Drori, T.; Tong, M.; Tretiak, S.; Vardeny, Z. V. Ultrafast intersystem-crossing in platinum containing π-conjugated polymers with tunable spin-orbit coupling. Sci. Rep. 2013 , 3 , 2653..
Yu, Z. G.; Ding, F.; Wang, H. Hyperfine interaction and its effects on spin dynamics in organic solids. Phys. Rev. B 2013 , 87 , 205446..
Dyakonov, V.; Rösler, G.; Schwoerer, M.; Frankevich, E. L. Evidence for triplet interchain polaron pairs and their transformations in polyphenylenevinylene. Phys. Rev. B 1997 , 56 , 3852−3862..
Ding, S.; Tian, Y.; Li, Y.; Zhang, H.; Zhou, K.; Liu, J.; Qin, L.; Zhang, X.; Qiu, X.; Dong, H.; Zhu, D.; Hu, W. Organic single-crystal spintronics: magnetoresistance devices with high magnetic-field sensitivity. ACS Nano 2019 , 13 , 9491−9497..
Nguyen, T. D.; Hukic-Markosian, G.; Wang, F.; Wojcik, L.; Li, X.-G.; Ehrenfreund, E.; Vardeny, Z. V. Isotope effect in spin response of π-conjugated polymer films and devices. Nat. Mater. 2010 , 9 , 345−352..
McCamey, D. R.; van Schooten, K. J.; Baker, W. J.; Lee, S.-Y.; Paik, S.-Y.; Lupton, J. M.; Boehme, C. Hyperfine-field-mediated spin beating in electrostatically bound charge carrier pairs. Phys. Rev. Lett. 2010 , 104 , 017601..
Lunghi, A.; Sanvito, S. How do phonons relax molecular spins. Sci. Adv. 2019 , 5 , eaax7163..
Teferi, M. Y.; Ogle, J.; Joshi, G.; Malissa, H.; Jamali, S.; Baird, D. L.; Lupton, J. M.; Brooks, L. W.; Boehme, C. Tuning effective hyperfine fields in PEDOT: PSS thin films by doping. Phys. Rev. B 2018 , 98 , 241201..
Carey, R. L.; Ren, X.; Jacobs, I. E.; Elsner, J.; Schott, S.; Goldberg, E.; Wang, Z.; Blumberger, J.; Sirringhaus, H. Long spin lifetimes of charge carriers in rubrene crystals due to fast transient-localization motion. Nat. Commun. 2025 , 16 , 7605..
Elliott, R. J. Theory of the effect of spin-orbit coupling on magnetic resonance in some semiconductors. Phys. Rev. 1954 , 96 , 266−279..
Yafet, Y. Calculation of the g factor of metallic sodium. Phys. Rev. 1952 , 85 , 478..
Zheng, Y.; Wudl, F. Organic spin transporting materials: present and future. J. Mater. Chem. A 2014 , 2 , 48−57..
Wang, Y.; Yao, J.; Ding, S.; Guo, S.; Cui, D.; Wang, X.; Yang, S.; Zhang, L.; Tian, X.; Wu, D.; Jin, C.; Li, R.; Hu, W. Spin injection and transport in single-crystalline organic spin valves based on TIPS-pentacene. Sci. China Mater. 2021 , 64 , 2795−2804..
Tong, J.; Ruan, L.; Yao, X.; Qin, G.; Zhang, X. Defect states dependence of spin transport in iron phthalocyanine spin valves. Phys. Rev. B 2019 , 99 , 054406..
Yang, X.; Guo, A.; Guo, L.; Liu, Y .; Sun, X.; Guo, Y. Organic semiconductors for room-temperature spin valves. ACS Mater. Lett. 2022 , 4 , 805−814..
Gu, R. Y.; Xing, D. Y.; Dong, J. Spin-polarized tunneling between ferromagnetic films. J. Appl. Phys. 1996 , 80 , 7163−7165..
Grünewald, M.; Wahler, M.; Schumann, F.; Michelfeit, M.; Gould, C.; Schmidt, R.; Würthner, F.; Schmidt, G.; Molenkamp, L. W. Tunneling anisotropic magnetoresistance in organic spin valves. Phys. Rev. B 2011 , 84 , 125208..
Gobbi, M.; Golmar, F.; Llopis, R.; Casanova, F.; Hueso, L. E. Room-temperature spin transport in C 60 -based spin valves. Adv. Mater. 2011 , 23 , 1609−1613..
Butler, W. H.; Zhang, X. G.; Schulthess, T. C.; MacLaren, J. M. Spin-dependent tunneling conductance of Fe|MgO|Fe sandwiches. Phys. Rev. B 2001 , 63 , 054416..
Xu, W.; Szulczewski, G. J.; LeClair, P.; Navarrete, I.; Schad, R.; Miao, G.; Guo, H.; Gupta, A. Tunneling magnetoresistance observed in La 0.67 Sr 0.33 MnO3/organic molecule/ Co junctions. Appl. Phys. Lett. 2007 , 90 , 072506..
Lu, Q.; Xie, S.; Qu, F.Hopping-dominated spin transport in unintentionally doped organic semiconductors. J. Phys. Chem. Lett. 2021 , 12 , 3540−3544..
Yoo, J. W.; Jang, H. W.; Prigodin, V. N.; Kao, C.; Eom, C. B.; Epstein, A. J. Giant magnetoresistance in ferromagnet/organic semiconductor/ferromagnet heterojunctions. Phys. Rev. B 2009 , 80 , 205207..
Coropceanu, V.; Cornil, J.; da Silva Filho, D. A.; Olivier, Y.; Silbey, R.; Brédas, J.-L. Charge transport in organic semiconductors. Chem. Rev. 2007 , 107 , 926−952..
Lin, R.; Wang, F.; Rybicki, J.; Wohlgenannt, M.; Hutchinson, K. A. Distinguishing between tunneling and injection regimes of ferromagnet/organic semiconductor/ferromagnet junctions. Phys. Rev. B 2010 , 81 , 195214..
Sun, X.; Bedoya-Pinto, A.; Mao, Z.; Gobbi, M.; Yan, W.; Guo, Y.; Atxabal, A.; Llopis, R.; Yu, G.; Liu, Y.; Chuvilin, A.; Casanova, F.; Hueso, L. E. Active morphology control for concomitant long distance spin transport and photoresponse in a single organic device. Adv. Mater. 2016 , 28 , 2609−2615..
Massé, A.; Friederich, P.; Symalla, F.; Liu, F.; Meded, V.; Coehoorn, R.; Wenzel, W.; Bobbert, P. A. Effects of energy correlations and superexchange on charge transport and exciton formation in amorphous molecular semiconductors: an ab initio study. Phys. Rev. B 2017 , 95 , 115204..
Abdalla, H.; Zuo, G.; Kemerink, M. Range and energetics of charge hopping in organic semiconductors. Phys. Rev. B 2017 , 96 , 241202..
Hu, B.; Wu, Y. Tuning magnetoresistance between positive and negative values in organic semiconductors. Nat. Mater. 2007 , 6 , 985−991..
Nguyen, T. D.; Ehrenfreund, E.; Vardeny, Z. V. Spin-polarized light-emitting diode based on an organic bipolar spin valve. Science 2012 , 337 , 204−209..
Prieto-Ruiz, J. P.; Miralles, S. G.; Prima-García, H.; López-Muñoz, A.; Riminucci, A.; Graziosi, P.; Aeschlimann, M.; Cinchetti, M.; Dediu, V. A.; Cor onado, E. Enhancing light emission in interface engineered spin-OLEDs through spin-polarized injection at high voltages. Adv. Mater. 2019 , 31 , 1806817..
Bairagi, K.; Romero, D. G.; Calavalle, F.; Catalano, S.; Zuccatti, E.; Llopis, R.; Casanova, F.; Hueso, L. E. Room-temperature operation of a p-type molecular spin photovoltaic device on a transparent substrate. Adv. Mater. 2020 , 32 , 1906908..
Yu, Z. G. Impurity-band transport in organic spin valves. Nat. Commun. 2014 , 5 , 4842..
Droghetti, A.; Sanvito, S. Impurity band magnetism in organic semiconductors. Phys. Rev. B 2019 , 99 , 094413..
Arnold, T.; Atxabal, A.; Parui, S.; Hueso, L. E.; Ortmann, F. Hot electrons and hot spins at metal–organic interfaces. Adv. Funct. Mater. 2018 , 28 , 1706105..
Meng, K.; Zheng, R.; Gu, X.; Zhang, R.; Guo, L.; Qin, Y.; Yang, T.; Li, M.; Hu, S.; Zhang, C.; Wu, M.; Guo, A.; Yang, X.; Zhang, J.; Sun, X. In-device ballistic-electron-emission spectroscopy for accurately in situ mapping energy level alignment at metal–organic semiconductors interface. Adv. Mater. 2025 , 37 , 2412758..
Yang, T.; Qin, Y.; Gu, X.; Sun, X. Molecular design for enhanced spin transport in molecular semiconductors. Nano Res. 2023 , 16 , 13457−13473..
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