Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms

Ao-Qi Wang; Xiao-Bin Gao; Biao Zhao; Jian-Ping Deng

doi:10.1007/s10118-026-3712-8

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Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms

Special Topic: Chirality in Polymers | Updated：2026-08-31

- Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms
- Chinese Journal of Polymer Science Vol. 44, Issue 9, Pages: 2810-2823(2026)
- Affiliations：
  
  Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  zhaobiao@buct.edu.cn (B.Z.)
  dengjp@mail.buct.edu.cn (J.P.D.)
- Funds：
- DOI：10.1007/s10118-026-3712-8
  CLC：
- Received：12 March 2026，
  
  Accepted：13 April 2026，
  
  Online First：26 June 2026，
  
  Published：05 September 2026
- Accepted：
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Wang, A. Q.; Gao, X. B.; Zhao, B.; Deng, J. P. Circularly polarized luminescence based on helical polymers: structure-property relationships and regulation mechanisms. Chinese J. Polym. Sci. 2026, 44, 2810–2823

Ao-Qi Wang, Xiao-Bin Gao, Biao Zhao, et al. Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms[J]. Chinese Journal of Polymer Science, 2026, 44(9): 2810-2823.
Wang, A. Q.; Gao, X. B.; Zhao, B.; Deng, J. P. Circularly polarized luminescence based on helical polymers: structure-property relationships and regulation mechanisms. Chinese J. Polym. Sci. 2026, 44, 2810–2823 DOI： 10.1007/s10118-026-3712-8.

Ao-Qi Wang, Xiao-Bin Gao, Biao Zhao, et al. Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms[J]. Chinese Journal of Polymer Science, 2026, 44(9): 2810-2823. DOI： 10.1007/s10118-026-3712-8.

摘要

This schematic categorizes helical-polymer-based CPL materials into monocomponent

multicomponent

and hybrid systems

while elucidating the pivotal mechanisms that dictate chiroptical amplification

including chirality transfer

responsive inversion

and photonic modulation. These insights provide a systemic blueprint for rational integration of high-performance chiroptical systems with tailored properties.

Abstract

Circularly polarized luminescence (CPL) materials have attracted considerable attention because of their unique chiroptical properties and promising applications. However

the simultaneous achievement of a high luminescence dissymmetry factor (

lum

)

high photoluminescence quantum yield

excellent processability

and environmental stability remains challenging. Chiral helical polymers

featuring single-handed helical conformations

have emerged as versatile and powerful platforms for constructing high-performance CPL systems by utilizing their inherent chiral amplification effects

tunable conformational dynamics

and ability to form hierarchically ordered structures. This review systematically summarizes recent advances in CPL materials based on chiral helical polymers

focusing on the regulation of chiroptical properties through polymer conformation

mesoscopic ordered structures

and photophysical pathways. CPL systems are categorized into th

ree main classes: monocomponent chiral helical polymers

multi-component organic composites

and organic-inorganic hybrids. For each category

representative molecular design strategies

fabrication methodologies

and CPL performance were elaborated

emphasizing the underlying structure-property relationships. The key mechanisms governing CPL generation and amplification are discussed in depth

including chirality transfer

solvent- and state-dependent chiral inversion

selective absorption/filtering

and cholesteric liquid-crystal-mediated photonic amplification. Furthermore

representative breakthroughs

such as near-infrared CPL

room-temperature phosphorescence

and long-persistent CPL

are highlighted. Finally

the current challenges and future directions are outlined

providing a guideline for the rational design and practical application of next-generation helical polymer-based CPL materials.

关键词

Keywords

references

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One-handed Helical Poly(m-terphenyl acetylene)s with Broad Optical Activity Range from Ultraviolet-Visible to Near-infrared Regions

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Related Author

Li-Yuan Shi

Fu Tian

Cheng-Yin Cao

Kun Hu

Xiao-Die Zhu

Xiao-Hong Li

Sheng Wang

Jia-Qi Yu

Related Institution

Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University

Beijing National Laboratory for Molecular Science, Key Laboratory of Polymer Chemistry and Physics of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University

School of Materials Science and Engineering, Shanghai University

School of Material Science and Engineering, Henan University of Technology

College of Chemistry, Zhengzhou University

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