

FOLLOWUS
a.Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
b.Huazhong University of Science and Technology, Wuhan 430074, China
bien.tan@mail.hust.edu.cn
Received:10 March 2026,
Accepted:03 April 2026,
Online First:05 August 2026,
Published:05 September 2026
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Xie, J. W.; Tan, B. E. Porous organic polymers for photocatalytic hydrogen peroxide production: recent advances and future perspectives. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3697-3
Jia-Wei Xie, Bi-En Tan. Porous Organic Polymers for Photocatalytic Hydrogen Peroxide Production: Recent Advances and Future Perspectives[J/OL]. Chinese Journal of Polymer Science, 2026, 441-25.
Xie, J. W.; Tan, B. E. Porous organic polymers for photocatalytic hydrogen peroxide production: recent advances and future perspectives. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3697-3 DOI:
Jia-Wei Xie, Bi-En Tan. Porous Organic Polymers for Photocatalytic Hydrogen Peroxide Production: Recent Advances and Future Perspectives[J/OL]. Chinese Journal of Polymer Science, 2026, 441-25. DOI: 10.1007/s10118-026-3697-3.
Hydrogen peroxide (H
2
O
2
) is a green chemical with extensive applications in chemical synthesis and environmental remediation. While the industrial anthraquinone process remains the dominant production method
solar-driven photocatalytic H
2
O
2
production has emerged as a promising strategy to complement or optimize current production models
particularly for on-site applications. Among various porous organic polymers (POPs)
covalent organic frameworks (COFs)
and covalent triazine frameworks (CTFs) have attracted significant attention as a premier platform due to their modular construction and precise molecular-level tunability. Here
we systematically summarize recent progress in POPs-based photocatalysts
with a primary focus on the structural and functional modification of COFs and CTFs. We first elucidate the fundamental principles and existing challenges of photocatalytic H
2
O
2
production. Subsequently
the research landscape of various POPs materials in photocatalysis is discussed. Taking COFs and CTFs as representative examples
we then highlight advanced modification strategies
including the design of donor-acceptor (D-A) structures
functional group engineering
and the construction of heterostructures. These strategies effectively facilitate efficient charge separation
extend carrier lifetimes
and improve mass transport
thereby enhancing solar-to-chemical conversion efficiency. Finally
we summarize the current state of the field and offer perspectives on future research directions for POPs-based photocatalytic H
2
O
2
production.
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