

FOLLOWUS
a.State Key Laboratory of Advanced Fiber Materials, College of Chemistry and Chemical Engineering & Center for Advanced Low-dimension Materials, Donghua University, Shanghai 201620, China
b.Jülich Centre for Neutron Science (JCNS) at Heinz Maier-Leibnitz Zentrum (MLZ) Forschungszentrum Jülich, Garching 85748, Germany
shengtongsun@dhu.edu.cn (S.T.S.)
wupeiyi@dhu.edu.cn (P.Y.W.)
Received:11 February 2026,
Accepted:03 March 2026,
Online First:12 May 2026,
Published:05 June 2026
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Lou, C. C.; Wu, B. H.; Sun, S. T.; Wu, P. Y. A transparent acoustic damping hydrogel with dual-scale bicontinuous microphase separation. Chinese J. Polym. Sci. 2026, 44, 1727–1737
Chen-Chen Lou, Bao-Hu Wu, Sheng-Tong Sun, et al. A Transparent Acoustic Damping Hydrogel with Dual-scale Bicontinuous Microphase Separation[J]. Chinese Journal of Polymer Science, 2026, 44(6): 1727-1737.
Lou, C. C.; Wu, B. H.; Sun, S. T.; Wu, P. Y. A transparent acoustic damping hydrogel with dual-scale bicontinuous microphase separation. Chinese J. Polym. Sci. 2026, 44, 1727–1737 DOI: 10.1007/s10118-026-3642-5.
Chen-Chen Lou, Bao-Hu Wu, Sheng-Tong Sun, et al. A Transparent Acoustic Damping Hydrogel with Dual-scale Bicontinuous Microphase Separation[J]. Chinese Journal of Polymer Science, 2026, 44(6): 1727-1737. DOI: 10.1007/s10118-026-3642-5.
This work presents a hierarchical hydrogel that combines optical transparency and acoustic damping capacity. The hydrogel features a dual-scale bicontinuous nanostructure comprising three intertwined phases: hydrophilic
hydrophobic
and aqueous. This architecture enables acoustic impedance matching with water
strong vibrational damping
and ultrahigh absorption of sound.
Underwater camouflage materials can be hidden either from sight by being transparent or from sound by absorbing acoustic waves
but achieving both in one material remains challenging due to their distinct chemical designs. Here we decouple these conflicting properties using a hierarchically structured hydrogel featuring unique dual-scale bicontinuous microphase separation. By precisely integrating hydrophilic and hydrophobic units
we engineer three intertwined polymer-rich and aqueous phases spanning nano-to-micro length scales. This unique nanoconfinement preserves optical clarity by minimizing light scattering while facilitating ultrahigh broadband energy dissipation. Furthermore
the hydrogel’s acoustic impedance matches that of water
maximizing sound wave incidence into the material
where the propagating waves are scattered and attenuated through viscoelastic damping within the highly tortuous hydrophilic phases. A hydrogel film only 4 mm thick can absorb nearly 78% of incident sound energy. These findings highlight molecular-engineered hierarchical phase separation as a powerful strategy for developing advanced opto-acoustic soft materials.
Li, Z.; Chitre, M.; Stojanovic, M. Underwater acoustic communications. Nat. Rev. Electr. Eng. 2025 , 2 , 83−95..
Li, G.; Wong, T. W.; Shih, B.; Guo, C.; Wang, L.; Liu, J.; Wang, T.; Liu, X.; Yan, J.; Wu, B.; Yu, F.; Chen, Y.; Liang, Y.; Xue, Y.; Wang, C.; He, S.; Wen, L.; Tolley, M. T.; Zhang, A. M.; Laschi, C.; Li, T. Bioinspired soft robots for deep-sea exploration. Nat. Commun. 2023 , 14 , 7097..
Gao, Y.; Song, J.; Li, S.; Elowsky, C.; Zhou, Y.; Ducharme, S.; Chen, Y. M.; Zhou, Q.; Tan, L. Hydrogel microphones for stealthy underwater listening. Nat. Commun. 2016 , 7 , 12316..
Yu, Z.; Wu, P. Underwater communication and optical camouflage ionogels. Adv. Mater. 2021 , 33 , 2008479..
Yuk, H.; Lin, S.; Ma, C.; Takaffoli, M.; Fang, N. X.; Zhao, X. Hydraulic hydrogel actuators and robots optically and sonically camouflaged in water. Nat. Commun. 2017 , 8 , 14230..
Zhang, Z.; Zhao, Y.; Gao, N. Recent study progress of underwater sound absorption coating. Eng. Rep. 2023 , 5 , e12627..
Fu, Y.; Kabir, I. I.; Yeoh,G. H.; Peng, Z. A review on polymer-based materials for underwater sound absorption. Polym. Test. 2021 , 96 , 107115..
Dong, E.; Cao, P.; Zhang , J.; Zhang, S.; Fang, N. X.; Zhang, Y. Underwater acoustic metamaterials. Natl. Sci. Rev. 2022 , 10 , nwac246..
Gu, J.; Yan, S.; Zhang, L.; Su, C.; Yin, B.; Qu, S. Superior underwater sound-absorbing metasurface based on wave mode conversion and cavity-plate coupling resonance. Compos. Struct. 2023 , 323 , 117459..
Li, K.; Zhou, Z.; Huang, Z.; Lin, Y.; Chen, M.; Yang, P.; Li, Y. Underwater sound absorption characteristic of the rubber core sandwich structure with funnel-shaped cavities reinforced by carbon fiber columns. Appl. Acoust. 2023 , 208 , 109375..
Ma, F.; Wang, C.; Du, Y.; Zhu, Z.; Wu, J. H. Enhancing of broadband sound absorption through soft matter. Mater. Horiz. 2022 , 9 , 653−662..
Qu, S.; Gao, N.; Tinel, A.; Morvan, B.; Romero-García, V.; Groby, J.-P.; Sheng, P. Underwater metamaterial absorber with impedance-matched composite. Sci. Adv. 2022 , 8 , eabm4206..
Wang, B.; Qiao, C.; Wang, Y. l.; Dong, X.; Zhang, W.; Lu, Y.; Yuan, J.; Zeng, H.; Wang, H. Multifunctional u nderwater adhesive film enabled by a single-component poly(ionic liquid). ACS Nano 2023 , 17 , 5871−5879..
Zheng, J.; Luo, H.; Du,J.; Sun, S.; Cheng, Q.; Zhang, L.; Wang, D.; Wang, Y.; Zhou, H. Smart skin of underwater vehicle with dual functions of sound detection and absorption. Nano Energy 2024 , 129 , 110053..
[Rossing, T. D., in Springer handbook of acoustics , Springer Science & Business Media, New York, 2007 , p. 1..
[Sperling, L. H., in Sound and vibration damping with polymers , American Chemical Society, Washington, 1990 , p. 5..
Huang, J.; Zhou, H.; Zhang, L.; Zhang, L.; Shi, W.; Yang, Y.; Zhou, J.; Zhao, T.; Liu, M. Full-scale polymer relaxation induced by single-chain confinement enhances mechanical stability of nanocomposites. Nat. Commun. 2024 , 15 , 6747..
Zhang, J.; Zhou, N.; Dong, E.; Zhang, C.; Song, Z.; Liu, S.; Yang, C.; Su, X.; Wang, S.; Zhang, Y. Soft bio-metamaterials with high acoustic transpa rency and gradient refractive index for tunable acoustic beamformer. Matter 2024 , 7 , 3857−3875..
Zhang, K.; Ma, C.; He, Q.; Lin, S.; Chen, Y.; Zhang, Y.; Fang, N. X.; Zhao, X. Metagel with broadband tunable acoustic properties over air–water–solid ranges. Adv. Funct. Mater. 2019 , 29 , 1903699..
Dong, E.; Song, Z.; Zhang, Y.; Ghaffari Mosanenzadeh, S.; He, Q.; Zhao, X.; Fang, N. X. Bioinspired metagel with broadband tunable impedance matching. Sci. Adv. 2020 , 6 , eabb3641..
Zhao, X.; Zhou, Y.; Li, A.; Xu, J.; Karjagi, S.; Hahm, E.; Rulloda, L.; Li, J.; Hollister, J.; Kavehpour, P.; Chen, J. A self-filtering liquid acoustic sensor for voice recognition. Nat. Electron. 2024 , 7 , 924−932..
Tang, H.; Yang, Y.; Liu, Z.; Li, W.; Zhang, Y.; Huang, Y.; Kang, T.; Yu, Y.; Li, N.; Tian, Y.; Liu, X.; Cheng, Y.; Yin, Z.; Jiang, X.; Chen, X.; Zang, J. Injectable ultrasonic sensor for wireless monitoring of intracranial signals. Nature 2024 , 630 , 84−90..
Zhang, J.; Zhang, T.; Dong, E.; Z hang, C.; Lin, Z.; Song, Z.; Li, H.; Fang, N. X.; Zhang, Y. Bioinspired hydrogel jellyfish with mechanical flexibility and acoustic transparency. Cell Rep. Phys. Sci. 2022 , 3 , 101081..
Xu, Y.; Tan, J.; Dong, W.; Chen, Y.; Wuliu, Y.; Xu, W.; Wang, R.; Yin, G.; Zhang, Z.; Zhu, C.; Xu, J.; Tian, L. Super strong and tough hydrogels constructed via network uniformization of macromolecular chains. Adv. Funct. Mater. 2025 , 35 , 2419161..
Jiang, L.; Li, F.; Li, Y.; Pi, M.; Xie, J.; Zhang, J.; Guo, H.; Ran, R.; Cui, W. Solvent-free fabrication of robust physical hdrogels via bulk copolymerization for underwater acoustics. Adv. Mater. 2025 , 37 , 2508162..
Göransson, P. Acoustic and vibrational damping in porous solids. Phil. Trans. R. Soc. A 2006 , 364 , 89−108..
Dong, J.; Tian, P. Review of underwater sound absorption materials. IOP Conf. Ser.: Earth Environ. Sci 2020 , 508 , 012182..
Kim, J.; Zhang, G.; Shi, M.; Suo, Z. Fracture, fatigue, and friction o f polymers in which entanglements greatly outnumber cross-links. Science 2021 , 374 , 212−216..
Zhang, C.; Bao, Q.; Zhu, H.; Zhang, Q. Highly transparent and long-term stable dielectric elastomer composites enabled by poly(ionic liquid) inclusion. Adv. Funct. Mater. 2024 , 34 , 2401901..
[Groh, W.; Zimmermann, A. What is the lowest refractive index of an organic polymer. Macromolecules 1991, 24 , 6660−6663..
Humzah, M. D. Tyndall, Rayleigh, Mei, and Raman scattering: Understanding their role in aesthetics. J. Cosmet. Dermatol. 2024 , 23 , 3493−3496..
Chen, G.; Wu, J.; Wang, Z.; Zhu, H.; Zhu, S.; Zhang, Q. Armored polymer-fluid gels with integrated damping and impact protection across broad temperatures. Sci. Adv. 2025 , 11 , eadv5292..
Xiang, H.; Li, X.; Wu, B.; Sun, S.; Wu, P. Highly damping and self-healable ionic elastomer from dynamic phase separation of sticky fluorinated polymers. Adv. Mater. 2023 , 35 , 2209581..
Xu, Z.; Lu, J.; Lu, D.; Li, Y.; Lei, H.; Chen, B.; Li, W.; Xue, B.; Cao, Y.; Wang, W. Rapidly damping hydrogels engineered through molecular friction. Nat. Commun. 2024 , 15 , 4895..
Zhang, Y.; Yuan, J.; Hu, J.; Tian, Z.; Feng, W.; Yan, H. Toward understanding the cross-linking from molecular chains to aggregates by engineering terminals of supramolecular hyperbranched polysiloxane. Aggregate 2024 , 5 , e404..
Shi, Y.; Wu, B.; Sun, S.; Wu, P. Peeling–stiffening self-Adhesive ionogel with superhigh interfacial toughness. Adv. Mater. 2024 , 36 , 2310576..
Wang, Y. C.; Ludwigson, M.; Lakes, R. S. Deformation of extreme viscoelastic metals and composites. Mat. Sci. Eng. A 2004 , 370 , 41−49..
Zhang, P.; To, A. Highly enhanced damping figure of merit in biomimetic hierarchical staggered composites. J. Appl. Mech. 2014 , 81 , 051015..
Park, B.; Shin, J. H.; Ok, J.; Park, S.; Jung, W.; Jeong, C.; Choy, S.; Jo, Y. J.; Kim, T.-i. Cuticular pad–inspired selective frequency damper for nearly dynamic noise–free bioelectronics. Science 2022 , 376 , 624−629..
[Lakes, R. Viscoelastic Materials . Cambridge University Press 2009 ..
Wu, Y.; Wang, Y.; Guan, X.; Zhang, H.; Guo, R.; Cui, C.; Wu, D.; Cheng, Y.; Ge, Z.; Zheng, Y.; Zhang, Y. Molecular clogging organogels with excellent solvent maintenance, adjustable modulus, and advanced mechanics for impact protection. Adv. Mater. 2023 , 35 , 2306882..
Grindy, S. C.; Learsch, R.; Mozhdehi, D.; Cheng, J.; Barrett, D. G.; Guan, Z.; Messersmith, P. B.; Holten-Andersen, N. Control of hierarchical polymer mechanics with bioinspired metal-coordination dynamics. Nat. Mater. 2015 , 14 , 1210−1216..
Qiao, H.; Wu, B.; Sun, S.; Wu, P. Entropy-driven design of highly impact-stiffening supramolecular polymer networks with salt-bridge hydrogen bonds. J. Am. Chem. Soc. 2024 , 146 , 7533−7542..
Li, X.; Wu, B.; Sun, S.; Wu, P. Making sticky-slippery switchable fluorogels through self-adaptivebicontinuous phase separation. Adv. Mater. 2024 , 36 , 2411273..
[Song, Y. Q.; Kausik, R. NMR application in unconventional shale reservoirs—a new porous media research frontier. Prog. Nucl. Magn. Reson. Spectrosc . 2019, 112−113 , 17−33..
Wang, S.; Zhang, L.; Wang, Z.; Song, Z.; Liu, H.; Tian, Z.; Xu, X. Humidity-adaptive, mechanically robust, and recyclable bioplastic films amplified by nanoconfined assembly. Aggregate 2024 , 5 , e643..
Huang, J.; Xu, Y.; Qi, S.; Zhou, J.; Shi, W.; Zhao, T.; Liu, M. Ultrahigh energy-dissipation elastomers by precisely tailoring the relaxation of confined polymer fluids. Nat. Commun. 2021 , 12 , 3610..
Hou, L.; Wu, P.; Sun, S. Physical interaction-driven design of modulus-adaptive polymers. Sci. China Mater. 2025 , 68 , 3526..
Li, L.; Wu, B.; Sun, S.; Wu, P. High-entropy thermal-stiffening hydrogels with fast switching dynamics. Natl. Sci. Rev. 2025 , 12 , nwaf072..
Zeqiri, B.; Scholl, W.; Robinson, S. P. Measurement and testing of the acoustic properties of materials: a review. Metrologia 2010 , 47 , S156..
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