

FOLLOWUS
a.Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Materials Chemistry and Service Failure, National Anti-counterfeit Engineering Research Center, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
b.School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430205, China
wukong.s@163.com (Y.Q.)
ygliao@mail.hust.edu.cn (Y.G.L.)
Received:17 November 2025,
Revised:2025-12-31,
Accepted:27 January 2026,
Online First:25 March 2026,
Published:2026-02
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Li, W. T.; Wang, W.; Chen, J.; Liao, G. J.; Qiu, Y.; Wang, H.; Yin, G. C.; Liao, Y. G.; Xie, X. L. Composition-dependent emission in bifuran-based polyester films doped with aggregation-induced emission luminogen for information storage and encryption. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3595-8
Wen-Ting Li, Wei Wang, Jie Chen, et al. Composition-dependent Emission in Bifuran-based Polyester Films Doped with Aggregation-induced Emission Luminogen for Information Storage and Encryption[J/OL]. Chinese Journal of Polymer Science, 2026, 441-10.
Li, W. T.; Wang, W.; Chen, J.; Liao, G. J.; Qiu, Y.; Wang, H.; Yin, G. C.; Liao, Y. G.; Xie, X. L. Composition-dependent emission in bifuran-based polyester films doped with aggregation-induced emission luminogen for information storage and encryption. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3595-8 DOI:
Wen-Ting Li, Wei Wang, Jie Chen, et al. Composition-dependent Emission in Bifuran-based Polyester Films Doped with Aggregation-induced Emission Luminogen for Information Storage and Encryption[J/OL]. Chinese Journal of Polymer Science, 2026, 441-10. DOI: 10.1007/s10118-026-3595-8.
Multicolor luminescent materials have attracted considerable attention for their applications in information storage
encryption
and flexible displays. However
these materials often suffer from cumbersome synthesis and poor film-form ability. Herein
we report a facile strategy to fabricate multicolor luminescent films by doping an intramolecular charge transfer (ICT)-active aggregation-induced emission luminogen (AIEgen) into highly polar bifuran-based polyester. In combination with the ICT effect of the AIEgen
the distinct energy transfer efficiency between the polyester and the AIEgen achieves the wide-range emission color change from blue to red in the doped films. Furthermore
the AIEgen exhibits reversible pH-responsiveness and irreversible photocyclization under 365 nm UV light. Accordingly
a nine-grid and “dragon/QR code” patterns are designed using these doped films
demonstrating their potential in advanced information encryption and storage. This work not only provides a new perspective on the fabrication of multicolor luminescent materials
but also paves the way in information storage
data encryption
and other advanced technologies.
Wang, Y.; Wu, H.; Hu, W.; Stoddart, J. F. Color-tunable supramolecular luminescent materials. Adv. Mater. 2021 , 34 , 2105405..
Liu, P.; Xiang, Y.; Li, Y.; Peng, S. S.; Zhu, Z.; Shi, X.; Wu, J.; Chen, P. Color-tunable light-emitting fibers for pattern displaying textiles. J. Mater. Chem. C 2024 , 12 , 941−947..
Gao, R. H.; Ge, Q.; Tao, Z.; Cong, H. Achieving color-tunable and stable luminescent hydrophilic phosphorescent films in the presence of cucurbit[8 ] uril for advanced anti-counterfeiting. Macromolecules 2025 , 58 , 1401−1408..
Mu, G.; Rao, T.; Qi, Y.; Ma, S.; Hao, Q.; Chen, M.; Tang, X. Color-tunable organic light-emitting displays for interactive multi-signal visualization. Adv. Funct. Mater. 2023 , 33 , 2301280..
Chen, Z.; Xie, H.; Li, G.; Wang, Y.; Guo, D.; Yang, Z.; Mao, Z.; Zhao, J.; Yang, Z.; Ge, X.; Xu, J.; Chi, Z. Multiple-flexibility emitter exhibiting color-tunable singlet and triplet emissions via guest regulation. Sci. China. Chem. 2025 , 68 , 3778−3785..
Su, L.; Jiang, Z.; Tian, Z.; Wang, H.; Wang, H.; Zi, Y. Self-powered, ultrasensitive, and high-resolution visualized flexible pressure sensor based on color-tunable triboelectrification-induced electroluminescence. Nano Energy 2021 , 79 , 105431..
Liang, B.; An, W.; Liu, J.; Dong, Y.; F eng, S.; Huang, W. Ultralong organic phosphorescence of triazatruxene derivatives for dynamic data encryption and anti-counterfeiting. Chin. J. Chem. 2023 , 41 , 2261−2268..
Yang, L.; Zhang, Q.; Ma, Y.; Li, H.; Sun, S.; Xu, Y. Stimulus-responsive room-temperature phosphorescence with tunable color for time-resolved advanced dynamic anti-counterfeiting. Chem. Eng. J. 2024 , 490 , 151679..
Zuo, Z. H.; Peng, Y. Y.; Li, J.; Wang, X.; Liu, Z. Q.; Chen, Y. Thermal-responsive dynamic color-tunable persistent luminescence from green to deep red for advanced anti-counterfeiting. Chem. Eng. J. 2022 , 446 , 136976..
Zuo, M.; Zeng, C.; Liu, J.; Wu, H.; Feng, S.; Dong, Y.; Huang, W. Pyridine-based rigidochromic fluorescent security ink. Chin. J. Chem. 2025 , 43 , 1405−1416..
Yang, Z.; Du, Y.; Li, Q.; Zhang, J.; Li, Q.; Yan, H. Oligomeric polysiloxanes with tunable emission colors from blue to yellow. Macromolecules 2025 , 58 , 2450−2458..
[Zhang, X.; Yu, X.; Wu, J.; Huang, W. Stimuli-responsive molecules: Emerging materials for advanced data-encryption and anti-counterfeiting, Chin. J. Struct. Chem . 2022 , 41 , 2212001−2212003..
Sun, S.; Yang, W.; Zhang, C.; Jing, J.; Gao, Y.; Yu, X.; Song, Q.; Xiao, S. Real-time tunable colors from microfluidic reconfigurable all-dielectric metasurfaces. ACS Nano 2018 , 12 , 2151−2159..
Hu, Y.; Huang, Z.; Willner, I.; Ma, X. Multicolor circularly polarized luminescence of a single-component system revealing multiple information encryption. CCS Chem. 2024 , 6 , 518−527..
Jia, D.; Tian, Y.; Zhu, D.; Wang, X. Rewritable flexible cnc-based composite film with highly homogeneous structural color and time-dependent fluorescence for optical information storage and encryption. Chem. Eng. J. 2025 , 518 , 164898..
Zhang, J.; Qin, S.; Zhang, S.; Sun, C.; Ren, Y.; Zhang, L.; Liu, J.; Xiao, J.; Hu, W.; Yang, H.; Yang, D. Programmable dynamic information storage composite film with highly sensitive thermochromism and gradually adjustable fluorescence. Adv. Mater. 2023 , 36 , 2305872..
Dong, Y.; Wu, H.; Liu, J.; Zheng, S.; Liang, B.; Zhang, C.; Ling, Y.; Wu, X.; Chen, J.; Yu, X.; Feng, S.; Huang, W. Multicolor photochemical printing inside polymer matrices for advanced photonic anticounterfeiting. Adv. Mater. 2024 , 36 , 2401294..
Xu, M.; Hua, L.; Gong, L.; Lu, J.; Wang, J.; Zhao, C. Lighted up by hydrogen-bonding: Luminescence behavior and applications of aiegen-doped interpenetrating network hydrogel. Sci. China. Chem. 2021 , 64 , 1770−1777..
Zheng, S.; Wu, H.;Li, C.; Liu, J.; Yu, X.; Dong, Y.; Zhang, C.; Zhu, L.; Feng, S.; Huang, W. Versatile ratiometric fluorescent thermometer based on antirigidochromic fluorophores in a polymer matrix with exceptional anti-interference capability. ACS Appl. Polym. Mater. 2024 , 6 , 3523−3533..
Wang, W.; Wang, J.; Li, W.; Liao, G.; Qiu, Y.; Yin, G.; Liao, Y.; Xie, X. Composition-dependent emission colors for biomass-based main-chain luminescent liquid crystalline copolyesters with excellent tensile properties. Polym. Chem. 2024 , 15 , 4721−4731..
Nara, M.; Orita, R.;Ishige, R.; Ando, S. White-light emission and tunable luminescence colors of p olyimide copolymers based on fret and room-temperature phosphorescence. ACS Omega 2020 , 5 , 14831−14841..
Qin, S.; Zou, H.; Hai, Y.; You, L. Aggregation-induced emission luminogens and tunable multicolor polymer networks modulated by dynamic covalent chemistry. Chin. Chem. Lett. 2022 , 33 , 3267−3271..
Ma, X.; Li, J. S.; Shen, R. F.; Ye, T J.; Gu, P.; Yang, H. J.; Xu, L. J.; Zhang, Q. Dynamic color-tunable ultra-long room temperature phosphorescence polymers with photo-chromism and water-stimuli response for multilevel anti-counterfeiting. Aggregate 2024 , 5 , e579..
Tao, L.; Li, M. L.; Yang, K. P.; Guan, Y.; Wang, P.; Shen, Z.; Xie, H. L. Color-tunable and stimulus-responsive luminescent liquid crystalline polymers fabricated by hydrogen bonding. ACS Appl. Mater. Interfaces 2019 , 11 , 15051−15059..
[Luo, J.; Xie, Z.; Lam, J. W. Y.; Cheng, L.; Chen, H.; Qiu, C.; Kwok, H. S.; Zhan, X.; Liu, Y.; Zhu, D.; Tang, B. Z. Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole. Chem. Commun . 2001 , 1740−1741..
Dai, W.; Bianconi, T.; Ferraguzzi, E.; Wu, X.; Lei, Y.; Shi, J.; Tong, B.; Carlotti, B.; Cai, Z.; Dong, Y. Excited-state modulation of aggregation-induced emission molecules for high-efficiency triplet exciton generation. ACS Mater. Lett. 2021 , 3 , 1767−1777..
Huang, S.; Ding, J.; Bi, A.; Yu, K.; Zeng, W. Insights into optical probes based on aggregation-induced emission: From restriction of intramolecular motions to dark state. Adv. Opt. Mater. 2021 , 9 , 2100832..
[Wang, B. W.; Jiang, K.; Li, J. X.; Luo, S. H.; Wang, Z. Y.; Jiang, H. 1,1-Diphenylvinylsulfide as a functional aiegen derived from the aggregation-caused-quenching molecule 1,1-diphenylethene through simple thioetherification. Angew. Chem. Int. Ed . 2019 , 59, 2338−2343..
Leung, N. L. C.; Miao, Q.; Lam, J. W. Y.; Xie, N.; Yuan, W.; Liu, Y.; Wu, Q.; Tang, B. Z. Restriction of intramolecular motions: The general mechanism behind aggregation-induced emission. Chem. Eur. J. 2014 , 20 , 15349−15353..
Zhang, Q.; Zhang, Z.; Liu, J.; Song, A.; Li, C.; Yang, X.; Zhang, D.; Ye, Y. Advances in aggregation-induced emission fluorescent probes for reactive sulfur species detection. Coord. Chem. Rev. 2026 , 547 , 217122..
Chen, Y.; Lam, J. W. Y.; Kwok, R. T. K.; Liu, B.; Tang, B. Z. Aggregation-induced emission: Fundamental understanding and future developments. Mater. Horiz. 2019 , 6 , 428−433..
Huo, M.; Ye, Q.; Che, H.; Wang, X.; Wei, Y.; Yuan, J. Polymer assemblies with nanostructure-correlated aggregation-induced emission. Macromolecules 2017 , 50 , 1126−1133..
Zhang, W.; Kong, J.; Miao, R.; Song, H.;Ma, Y.; Zhou, M.; Fang, Y. Integrating aggregation induced emission and twisted intramolecular charge transfer via molecular engineering. Adv. Funct. Mater. 2023 , 34 , 2311404..
Hanaoka, K.; Iwaki, S.; Yagi, K.; Myochin, T.; Ikeno, T.; Ohno, H.; Sasaki, E.; Komatsu, T.; Ueno, T.; Uchigashima, M.; Mikuni, T.; Tainaka, K.; Tahara, S.; Takeuchi, S.; Tahara, T.; Uchiyama, M.; Nagano, T.; Urano, Y. General design strategy to precisely control the emission of fluorophores via a twisted intramolecular charge transfer (TICT) process. J. Am. Chem. Soc. 2022 , 144 , 19778−19790..
Hu, Y.; Barbier, L.; Li, Z.; Ji, X.; Le Blay, H.; Hourdet, D.; Sanson, N.; Lam, J. W. Y.; Marcellan, A.; Tang, B. Z. Hydrophilicity-hydrophobicity transformation, thermoresponsive morphomechanics, and crack multifurcation revealed by AIEgens in mechanically strong hydrogels. Adv. Mater. 2021 , 33 , 2101500..
Luo, W.; Wu, B.; Xu, X.; Han, X.; Hu, J.; Wang, G. A triple pH-responsive aiegen: synthesis, optical properties and applications. Chem. Eng. J. 2022 , 431 , 133717..
Yan, C.; Guo, Z.; Chi, W.; Fu, W.; Abedi, S. A. A.; Liu, X.; Tian, H.; Zhu, W. H. Fluorescence umpolung enables light-up sensing of N-acetyltransferases and nerve agents. Nat. Commun. 2021 , 12 , 3869..
Zhang, J.; Li, A.; Zou, H.; Peng, J.; Guo, J.; Wu, W.; Zhang, H.; Zhang, J.; Liu, S. H.; Gu, X.; Weiqing Xu; Xu, S.; Qin, A.; Lama, J. W. Y.; Tang, B. Z. A “simple” donor–acceptor aiegen with multi-stimuli responsive behavior. Mater. Horiz. 2020 , 7 , 135−142..
Kainulainen, T. P.; Sirviö, J. A.; Sethi, J.; Hukka, T. I.; Heiskanen, J. P. UV-blocking synthetic biopolymer from biomass-based bifuran diester and ethylene glycol. Macromolecules 2018 , 51 , 1822−1829..
Ahmed, A. M.; Kainulainen, T. P.; Heiskanen, J. P. Furfural-based modification of pet for UV-blocking copolymers with decreased oxygen permeability. Ind. Eng. Chem. Res. 2021 , 60 , 7495−7504..
Kainulainen, T. P.; Hukka, T. I.; D, H. s.; Ö zeren, J. A.; Sirviö, M. S.; Hedenqvist; Heiskanen, J. P. Utilizing furfural-based bifuran diester as monomer and comonomer for high-performance bioplastics: Properties of poly(butylene furanoate), poly(butylene bifuranoate), and their copolyesters. Biomacromolecules 2019 , 21 , 743−752..
Wang, T.; Wang, J.; Liao, G.; Wang, W.; Qiu, Y.; Yin, G.; Liao, Y.; Xie, X. Flexible films of main-chain luminescent liquid crystalline polymers containing renewable biobased bifuran moieties. Eur. Polym. J. 2023 , 199 , 112448..
Miyagawa, N.; Ogura, T.; Okano, K.; Matsumoto, T.; Nishino, T.; Mori, A. Preparation of furandimer-based biopolyester showing high melting points. Chem. Lett. 2017 , 46 , 1535−1538..
Sun, L.; Wang, J.; Mahmud, S.; Jianga, Y.; Zhua, J.; Liu, X. New insight into the mechanism for the excellent gas properties of poly(ethylene 2,5-furandicarboxylate) (PEF): role of furan ring’s polarity. Eur. Polym. J. 2019 , 118 , 642−650..
Huang, R.; Liu, H.; Liu, K.; Wang, G.; Liu, Q.; Wang, Z.; Liu, T.; Miao, R.; Peng, H.; Fang, Y. Marriage of aggregation-induced emission and intramolecular charge transfer toward high performance film-based sensing of phenolic compounds in the air. Anal. Chem. 2019 , 91 , 14451−14457..
Zhang, J.; He, B.; Hu, Y.; Alam, P.; Zhang, H.; Lam, J. W. Y.; Tang, B. Z. Stimuli-responsive AIEgens. Adv. Mater. 2021 , 33 , 2008071..
Liu, X.; Qiao, Q.; Tian, W.; Liu, W.; Chen, J.; Lang, M. J.; Xu, Z. Aziridinyl fluorophores demonstrate bright fluorescence and superior photostability by effectively inhibiting twisted intramolecular charge transfer. J. Am. Chem. Soc. 2016 , 138 , 6960−6963..
Zhang, J.; Tu, Y.; Shen, H.; Lam, J. W. Y.; Sun, J.; Zhang, H.; Tang, B. Z. Regulating the proximity effect of heterocycle-containing aiegens. Nat Commun. 2023 , 14 , 3772..
Chen, M.; Jiang, Z.; Qiu, Z. Synthesis and properties of poly(hexamethylene 2,5-furandicarboxylate-co-adipate) copolyesters. Eur. Polym. J. 2021 , 161 , 110860..
Zhou, J.; Ma, Z.; Wang, H.; Wang, W.; Chen, K.; Gui, H.; Chi, Z.; Liu, S. Protonation regulates intermolecular interaction force to achieve reversible ACQ-AIE conversion. Dyes Pigment 2024 , 229 , 112296..
Dharmayanti, C.; Clulow, A. J.; Hussain, M. S.; Gillam, T. A.; Klingler-Hoffmann, M.; Albrecht, H.; Blencowe, A. Influence of pendant pyridyl regioisomers on the pH-responsive behaviour of polymer-homopeptide copolymers and micelles. Eur. Polym. J. 2025 , 234 , 113931..
Qi, J.; Hu, X.; Dong, X.; Lu, Y.; Lu, H.; Zhao, W.; Wu, W. Towards more accurate bioimaging of drug nanocarriers: Turning aggregation-caused quenching into a useful tool. Adv. Drug Deliv. Rev. 2019 , 143 , 206−225..
Wu, L.; Bull, S. D.; Huang, C.; Emery, B. P.; Sedgwick, A. C.; He, X. P.; Tian, H.; Yoon, J.; Sessler, J. L.; James, T. D. Förster resonance energy transfer (FRET)-based small-molecule sensors and imaging agents. Chem. Soc. Rev. 2020 , 49 , 5110−5139..
Luo, Y.; Li, X.; Zhang, X.; Ren, H.; Shi, H.; Yang, Y.; Liu, C.; Xu, B.; Tian, W.; Wang, G. Novel AIE-active polyarylethersulfone polymers incorporating tetraphenylethene for enhanced fluorescence. Macromol. Rapid Commun. 2025 , 46 , 2401056..
Zhou, Z.; Xie, S.; Chen, X.; Tu, Y.; Xiang, J.; Wang, J.; He, Z.; Zeng, Z.; Tang, B. Z. Spiro-functionalized diphenylethenes: Suppression of a reversible photocyclization contributes to the aggregation-induced emission effect. J. Am. Chem. Soc. 2019 , 141 , 9803−9807..
Wei, P.; Zhang, J. X.; Zhao, Z.; Chen, Y.; He, X.; Chen, M.; Gong, J.; Sung, H. H. Y.; Williams, I. D.; Lam, J. W. Y.; Tang, B. Z. Multiple yet controllable photoswitching in a single AIEgen system. J. Am. Chem. Soc. 2018 , 140 , 1966−1975..
Shi, X.; Yan, N.; Niu, G.; Sung, S. H. P.; Liu, Z.; Liu, J.; Kwok, R. T. K.; Lam, J. W. Y.; Wang, W. X.; Sung, H. H. Y.; Williams, I. D.; Tang, B. Z. In vivomonitoring of tissue regeneration using a ratiometric lysosomal AIE probe. Chem. Sci. 2020 , 11 , 3152−3163..
Hu, Y.; Han, T.; Yan, N.; Liu, J.; Liu, X.; Wang, W. X.; Lam, J. W. Y.; Tang, B. Z. Visualization of biogenic amines and in vivo ratiometric mapping of intestinal pH by AIE-active polyheterocycles synthesized by metal-free multicomponent polymerizations. Adv. Funct. Mater. 2019 , 29 , 1902240..
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