Synthesis and Properties of Poly(ethylene succinate)-<italic style="font-style: italic">b</italic>-poly(butylene carbonate) Multiblock Copolymers

Xu-Cheng Du; Zhen-Chao Li; Ai-Min Mao; Pei-Xian Wang; Jun Ma; Zi-Qing Wang

doi:10.1007/s10118-025-3532-2

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Synthesis and Properties of Poly(ethylene succinate)-b-poly(butylene carbonate) Multiblock Copolymers

RESEARCH ARTICLE | Updated：2026-02-13

- Synthesis and Properties of Poly(ethylene succinate)-b-poly(butylene carbonate) Multiblock Copolymers
- Chinese Journal of Polymer Science Vol. 44, Issue 3, Pages: 743-755(2026)
- Affiliations：
  
  a.School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi 832003, China
  b.Xinjiang Blue Ridge Tunhe Polyester Co., Ltd., Changji 831100, China
- Author bio：
  
  wzq20070420@163.com or wzq_yh@shzu.edu.cn
- Funds：
- DOI：10.1007/s10118-025-3532-2
  CLC：
- Received：20 September 2025，
  
  Accepted：11 December 2025，
  
  Online First：06 February 2026，
  
  Published：15 March 2026
- Accepted：
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Du, X. C.; Li, Z. C.; Mao, A. M.; Wang, P. X.; Ma, J.; Wang, Z. Q. Synthesis and properties of poly(ethylene succinate)-b-poly(butylene carbonate) multiblock copolymers. Chinese J. Polym. Sci. 2026, 44, 743–755

Xu-Cheng Du, Zhen-Chao Li, Ai-Min Mao, et al. Synthesis and Properties of Poly(ethylene succinate)-b-poly(butylene carbonate) Multiblock Copolymers[J]. Chinese Journal of Polymer Science, 2026, 44(3): 743-755. DOI: 10.1007/s10118-025-3532-2.
Du, X. C.; Li, Z. C.; Mao, A. M.; Wang, P. X.; Ma, J.; Wang, Z. Q. Synthesis and properties of poly(ethylene succinate)-b-poly(butylene carbonate) multiblock copolymers. Chinese J. Polym. Sci. 2026, 44, 743–755 DOI： 10.1007/s10118-025-3532-2.

Xu-Cheng Du, Zhen-Chao Li, Ai-Min Mao, et al. Synthesis and Properties of Poly(ethylene succinate)-b-poly(butylene carbonate) Multiblock Copolymers[J]. Chinese Journal of Polymer Science, 2026, 44(3): 743-755. DOI: 10.1007/s10118-025-3532-2. DOI：

摘要

Poly(ethylene succinate)-

-poly(butylene carbonate) (PES-

-PBC) multiblock copolymers were synthesized

via

chain extension. When prepolymer molecular weight is below 2000 g/mol

PES and PBC become fully miscible

enhancing compatibility. Incorporating PBC tunes crystallinity

mechanical properties

and degradation

yielding tough

biodegradable materials with promising applications.

Abstract

In this study

a series of poly(ethylene succinate)-

-poly(butylene carbonate) (PES-

-PBC) multiblock copolymers were prepared through the chain-extension reaction of hydroxyl-terminated PES (PES-OH) and hydroxyl-terminated PBC (PBC-OH) prepolymers with 1

6-hexmethylene diisocyanate (HDI) as a chain extender. The effects of the prepolymer molecular weight and content on the structure and application properties of the PES-

-PBC copolymers were systematically investigated using various techniques. It was found th

at the compatibility of PES and PBC blocks in PES-

-PBC copolymers can be greatly enhanced by lowering the length of the prepolymers

and the amorphous phase of the PES and PBC chain segments in the PES-

-PBC copolymer would transform from immiscibility and partial miscibility to miscibility when the number-average molecular weight (

) of the PES-OH and PBC-OH prepolymers is less than 2000 g/mol. Only the crystal structure of bare PES can be observed in the wide-angle X-ray diffraction (WAXD) spectrum of the PES-

-PBC copolymers

but their crystallinity degrees were found to decrease with increasing PBC fraction. The thermal behavior

crystallization performance

rheological properties

mechanical properties

and degradation properties of the PES-

-PBC multiblock copolymers can be easily modulated by altering the block length and composition of the prepolymers

offering potential applications in biodegradable materials.

关键词

Keywords

references

Bergmann, M.; Collard, F.; Fabres, J.; Gabrielsen G.; Provencher J., Rochman, C.; Sebille, E.; Tekman, M. Plastic pollution in the arctic. Nat. Rev. Earth Environ. 2022 , 3 , 323−337..

Helm, L.; Venier-Cambron, C.; Verburg, P. The potential land-use impacts of bio-based plastics and plastic alternatives. Nat. Sustain. 2025 , 8 , 190−201..

Mohanty, A.; Vivekanandhan, S.; Pin, J; Misra, M. Composites from renewable and sustainable resources: challenges and innovations. Science 2018 , 362 , 536−542..

Zhu, Y.; Romain, C.; Williams, C. Sustainable polymers from renewable resources. Nature 2016 , 540 , 354−362..

Takaya, D.; Kabe, T.; Gan, H.; Iwata, T. Biodegradation rate control with blends of poly(butylene succinate) and poly(butylene succinate-co-adipate). Polym. Degrad. Stabil. 2025 , 240 , 111431..

Guo, Y. T.; Sun, L.; Fang, C.; Zhou, N.; Peng, T. Y.; Dai, Z. F.; Zhang, T.; Chen, J.; Xiong, Y. B. Compatibilization of poly(lactic acid) and poly(butylene adipate-co -butylene terephthalate) blends by using epoxidized magnesium hydroxide nanoparticles. Int. J. Biol. Macromol. 2025 , 306 , 141838..

Mastropetros, S.; Pispas, K.; Zagklis, D.; Ali, S.; Kornaros, M. Biopolymers production from microalgae and cyanobacteria cultivated in wastewater: recent advances. Biotechnol. Adv. 2022 , 60 , 107999..

Qu, R.; Wei, W.; Gu, Y. N.; Li, G. H.; Luan, Y.; Suo, H. Y.; Liu, J.; Qin, Y. S. CO2-based polycarbonate block copolymers prepared by an organocatalytic one-step route: a novel platform for constructing antibacterial materials via alternative strategies. Chem. Eng. J. 2025 , 507 , 160467..

Cai, K.; Liu, X.; Ma, X. S.; Zhang, J.; Tu, S. H.; Feng, J. Preparation of biodegradable PLA/PBAT blends with balanced toughness and strength by dynamic vulcanization process. Polymer 2024 , 291 , 126587..

Garofalo, E. Maio, L.; Scarfato, P.; Vitiello, L.; Incarnato, L. Mechanical recycling of poly(butylene succinate)/poly(lactide) blends: assessment of film blowing processability and film performances after multiple extrusions. Chem. Eng. J. 2025 , 505 , 159823..

Jang, E.; Padhan, B.; Patel, M.; Pandey, J.; Xu, B.; Patel, R. Antibacterial and biodegradable food packaging film from bacterial cellulose. Food Control 2023 , 153 , 109902..

Sanchez, L.; Woroch, C.; Dumas, D.; Waymouth, R.; Kanan, M. Toughening poly(lactic acid) without compromise – statistical copolymerization with a bioderived bicyclic lactone. J. Am. Chem. Soc. 2025 , 147 , 5212−5219..

Zhang, S. H.; Zhang, H. H.; Liu, M. J.; Zhou, S. S.; Chen, Q.; Zhao, Y. F.; Xie, Z. X.; Qu, J. P. Development of an ultra-strength and high-barrier biodegradable polymer via one-Step rheological cold rolling. ACS Sustain. Chem. Eng. 2025 , 13 , 3685−3696..

Zhang, S. H.; Luo, Z. M.; Yang, G. M.; Liu, M. J.; Liu, S.; Qu, J. P. Nacre-inspired bacteriostatic polymer film with ultrastrong and high barrier properties by self-assembly in the cold solid-state. Chem. Eng. J. 2025 , 516 , 163863..

Kumagai, S.; Imada, M.; Hayashi, S.; Katsuragi, A.; Sato, K.; Abe, H.; Asakura, N.; Takenaka, Y. Synthesis and characterization of block copolymers consisting of poly(ethylene succinate) and poly(amino acid)s. Polym. Degrad. Stabil. 2025 , 235 , 111265..

Yin, M. Y.; Zhang, X. Q.; Wang, H.; Yuan, Z. C.; Deng, H. X.; Jiang, X. L.; Hu, H.; Zhu, J.; Wang, J. G. High-barrier-property copolyesters based on spiroglycol with controlled degradation. ACS Sustain. Chem.Eng. 2024 , 12 , 6343−6354..

Larrañaga, A.; Lizundia, E. A review on the thermomechanical properties and biodegradation behaviour of polyesters. Eur. Polym. J. 2019 , 121 , 109296..

Seretoudi, G.; Bikiaris, D.; Panayiotou, C. Synthesis, characterization and biodegradability of poly(ethylene succinate)/poly(ε-caprolactone) block copolymers. Polymer 2002 , 43 , 5405−5414..

Yang, Y.; Qiu, Z. B. Crystallization and melting behavior of biodegradable poly(ethylene succinate-co-6 mol % butylene succinate). J. Appl. Polym. Sci. 2011 , 122 , 105−111..

Zeng, J. B.; Zhu, Q. Y.; Lu, X. He, Y. S.; Wang, Y. Z. From miscible to partially miscible biodegradable double crystalline poly(ethylene succinate)-b-poly(butylene succinate) multiblock copolymers. Polym. Chem. 2012 , 3 , 399−408..

Qiu, S. T.; Su, Z. Q.; Qiu, Z. B. Crystallization kinetics, morphology, and mechanical properties of novel biodegradable poly(ethylene succinate-co-ethylene suberate) copolyesters. Ind. Eng. Chem. Res. 2016 , 55 , 10286−10293..

Wu, H. N.; Qiu, Z. B. A comparative study of crystallization, melting behavior, and morphology of biodegradable poly(ethylene adipate) and poly(ethylene adipate-co-5 mol % ethylene succinate). Ind.Eng. Chem. Res. 2012 , 51 , 13323−13328..

Tang, L.; Qiu, Z. B. Effect of poly(ethylene glycol)-polyhedral oligomeric silsesquioxanes on the crystallization kinetics and morphology of biodegradable poly(ethylene succinate). Polym. Degrad. and Stabil. 2016 , 134 , 97−104..

Li, X.; Qiu, Z. B. Crystallization kinetics, morphology, and mechanical properties of novel poly(ethylene succinate-co-octamethylene succinate). Polym. Test. 2015 , 48 , 125−132..

Kumagai, S.; Hayashi, S.; Katsuragi, A.; Imada, M.; Sato, K.; Abe, H.; Asakura, N. ; Takenaka, Y. One-pot synthesis of marine-biodegradable poly(ethylene succinate)-based Ester amide copolymers containing amino acid. ACS Appl. Polym. Mater. 2024 , 6 , 8339−8347..

Lu, Y.; Tu, Z.; Cheng, Y.; Liu, L. P.; Leng, X. F.; Wei, Z. Y.; Li, Y. Kilogram-scale production of biodegradable poly(butylene carbonate): molecular weight dependence of physical properties and enhanced crystallization by nucleating agent. J. Polym. Environ. 2022 , 31 , 1510−1524..

Tu, Z.; Lu, Y.; Liu, L. P.; Wang, L. Z.; Li, Y.; Wei, Z. Y. Modification of biodegradable poly(butylene carbonate) by biobased cis-2-butene-1,4-diol. Eur. Polym. J. 2023 , 198 , 112432..

Chung, S.; Park, S.; Hao, L.; Kim, H.; Park, S.; Jeon, H.; Hwang, D.; Oh, D.; Koo, J.; Park, J. Extended shelf-life of biodegradable poly(butylene succinate-co-carbonate)/chitin nanowhisker-based bags. Polym. Degrad. Stabil. 2025 , 233 , 111185..

Liu, L. P.; Tu, Z.; Lu, Y.; Wei, Z. Y. Scale synthesis of poly(butylene carbonate-co-terephthalate) and its depolymerization–repolymerization recycling process. Ind. Eng. Chem. Res. 2023 , 62 , 4260−4270..

Ma, X. J.; Wang, H. J.; Wang, Z. Q.; Lv, Y.; Wei, Z. Synthesis and properties of biodegradable thiophene-based aliphatic polycarbonate/polyester copolymer: potential substitutes for terephthalic acid-based polymer. Eur. Polym. J. 2024 , 210 , 112972..

Kim, H.; Jeon, H.; Shin, G.; Lee, M.; Jegal, J.; Hwang, S.; Oh, D.; Koo, J.; Eom, Y.; Park, J. Biodegradable nanocomposite of poly(ester-co-carbonate) and cellulose nanocrystals for tough tear-resistant disposable bags. Green Chem. 2021 , 23 , 2293−2299..

Wang, J.; Zheng, L. C.; Li, C. C.; Zhu, W. X.; Zhang, D.; Guan, G. H.; Xiao, Y. N. Synthesis and properties of biodegradable multiblock poly(ester-carbonate) comprising of poly(L-lactic acid) and poly(butylene carbonate) with hexamethylene diisocyanate as chain-extender. J. Appl. Polym. Sci. 2013 , 131 , 39158..

Cai, X. D.; Yang, X. G.; Li, J. G.; Wang, G. Y. Improvement of thermal stability, crystallinity and degradation of poly(butylene carbonate) by incorporation of bio-based poly(ethylene sebacate) segment. Polym. Adv. Technol. 2017 , 28 , 1902−1910..

Liu, L. P.; Wang, B.; Li, C.; Wei, C.; Wei, Z. Y. Development of high barrier biodegradable poly(butylene carbonate-co-terephthalate)-based blends with balanced mechanical properties by self-reactive compatibility and co-crystallization. Polymer 2023 , 281 , 126130..

Wang, Y.; Wen, L.; Liu, J. J.; Li, C. C.; Zhang, Z. J.; Xiao, Y. N.; Yin, T.; Wu, S. H.; Jiang, Z. K.; Zhang, B. Synthesis of biodegradable PGA-PBC-PGA triblock copolymers and closed-loop recycling via a thermal depolymerization strategy. Green Chem. 2023 , 25 , 9998−10009..

Zhang, K.; Jiang, Z.; Qiu, Z. B. Effect of different lengths of side groups on the thermal, crystallization and mechanical properties of novel biodegradable poly(ethylene succinate) copolymers. Polym. Degrad. Stabil. 2021 , 187 , 109542..

Zhang, F.; Jiang, Z. G.; Qiu, Z. B. Biobased Poly(ethylene succinate)-b-poly(triethylene terephthalate) multiblock copolyesters with high melting temperature and improved crystallization rate and mechanical property. Polymer 2022 , 254 , 125061..

Wang, J.; Zheng, L. C.; Li, C. C.; Zhu, W. X.; Zhang, D.; Guan, G. H.; Xiao, Y. N. Synthesis and properties of biodegradable poly(ester-co-carbonate) multiblock copolymers comprising of poly(butyl ene Succinate) and poly(butylene Carbonate) by chain extension. Ind. Eng. Chem. Res. 2012 , 51 , 10785−10792..

Xu, C. L.; Zeng, J. B.; Zhu, Q. Y.; Wang, Y. Z. Poly(ethylene succinate)-b-poly(butylene succinate) multiblock copolyesters: the effects of block length and composition on physical properties. Ind. Eng. Chem. Res. 2013 , 52 , 13669−13676..

He, H. F.; Li, H. F.; Qiu, Z. B. Synthesis and property of novel biodegradable poly(ethylene succinate) copolymers with methyl group introduced from diacid. Giant 2024 , 17 , 100241..

Yang, S. Z.; Wu, R.; Bai, W.; Wang, Q. Y.; Li, J. G.; Wang, G. Y. Preparation and properties of multiblock polyester synthesized by chain extension copolymerization of poly(l-lactic acid) and poly(butylene carbonate) prepolymer. J. Polym. Environ. 2025 , 33 , 2267−2279..

Zhang, K.; Qiu, Z. B. Effect of methyl as the simplest C–H side group on the significant variation of physical properties of biodegradable poly(ethylene succinate). Polym. Test. 2020 , 90 , 106755..

[Zhou, M. Y.; Zhang, K. J.; Jiang, Z. G.; Qiu, Z. B. Synthesis and characterization of novel poly(butylene succinate)-b-poly(diethylene glycol terephthalate) multiblock copolyesters with high melting point and significantly improved mechanical property. Polymer 2021 , 232 , 124151..

Cardoso, K.; Souza, P.; Alves, R.; Fechine, G. Poly(butylene adipate-co-terephthalate)/graphene oxide nanocomposite films for food packaging applications. ACS Appl. Polym. Mater. 2025 , 7 , 5229−5239..

Zhou, T. B.; Wang, B.; Wang, X. S.; Sun, H. R.; Liu, Y.; Zheng, L. C. Copolymers based on pbs and polydimethylsiloxane with improved properties and novel functions: effect of molecular weight of polydimethylsiloxane. ACS Sustain. Chem. Eng. 2023 , 11 , 15397−15409..

Wang, J.; Zheng, L. C.; Li, C. C.; Zhu, W. X.; Zhang, D.; Xiao, Y. N.; Guan, G. H. Fully biodegradable blends of poly(butylene succinate) and poly(butylene carbonate): miscibility, thermal properties, crystallization behavior and mechanical properties. Polym. Test. 2012 , 31 , 39−45..

Wu, W. H.; Zhai, H. J.; Wu, K. T.; Wang, X.; Rao, W. H.; Ding, J. D.; Yu, L. Cheap organocatalyst di phenyl phosphate for efficient chemical recycling of poly(lactic acid), other polyesters and polycarbonates. Chem. Eng. J. 2024 , 480 , 148131..

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⁰

Synthesis and Properties of Poly(ethylene succinate)-b-poly(butylene carbonate) Multiblock Copolymers

DOI：10.1007/s10118-025-3532-2

摘要

Abstract

关键词

Keywords

references