Photocontrolled Solution [2+2] Polymerization of <italic style="font-style: italic">p</italic>-Phenylenediacrylate and Depolymerization

Miao-Yan Yi; Yu Jiang; Sai-Hu Liao

doi:10.1007/s10118-025-3431-6

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Photocontrolled Solution [2+2] Polymerization of p-Phenylenediacrylate and Depolymerization

RESEARCH ARTICLE | Updated：2025-10-30

- Photocontrolled Solution [2+2] Polymerization of p-Phenylenediacrylate and Depolymerization
- Chinese Journal of Polymer Science Vol. 43, Issue 11, Pages: 1973-1980(2025)
- Affiliations：
  
  State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Research Center of Chemicals for Electronics Manufacturing (Reconstruction), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
- Author bio：
  
  shliao@xmu.edu.cn
- Funds：
- DOI：10.1007/s10118-025-3431-6
  CLC：
- Received：22 May 2025，
  
  Accepted：08 August 2025，
  
  Online First：16 October 2025，
  
  Published：05 November 2025
- Accepted：
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Yi, M. Y.; Jiang, Y.; Liao, S. H. Photocontrolled solution [2+2] polymerization of p-phenylenediacrylate and depolymerization. Chinese J. Polym. Sci. 2025, 43, 1973–1980

Miao-Yan Yi, Yu Jiang, Sai-Hu Liao. Photocontrolled Solution [2+2] Polymerization of p-Phenylenediacrylate and Depolymerization[J]. Chinese Journal of Polymer Science, 2025, 43(11): 1973-1980. DOI: 10.1007/s10118-025-3431-6.
Yi, M. Y.; Jiang, Y.; Liao, S. H. Photocontrolled solution [2+2] polymerization of p-phenylenediacrylate and depolymerization. Chinese J. Polym. Sci. 2025, 43, 1973–1980 DOI： 10.1007/s10118-025-3431-6.

Miao-Yan Yi, Yu Jiang, Sai-Hu Liao. Photocontrolled Solution [2+2] Polymerization of p-Phenylenediacrylate and Depolymerization[J]. Chinese Journal of Polymer Science, 2025, 43(11): 1973-1980. DOI: 10.1007/s10118-025-3431-6. DOI：

摘要

We achieved visible-light-driven [2+2] solution polymerization of phenylenediacrylate monomers via energy transfer photocatalysis. This method yields cyclobutane-containing polymers with good thermal stability and processability

which are depolymerizable

showing potential for closed-loop recycling.

Abstract

The [2+2

]

photopolymerization of bisolefinic monomers is an important method for the synthesis of polymeric materials. However

these processes are usually carried out in solid states under the irradiation of high-energy UV light

while the corresponding [2+2

]

polymerization in solution has proved to be inefficient due to the lack of preassembly of the monomers. Herein

we demonstrate that the [2+2

]

polymerization of

-phenylenediacrylate monomers can be achieved in solution under visible light by employing energy transfer catalysis with 2

2’-methoxythioxanthone as a photocatalyst. Because no preassembly is required

this solution polymerization is applicable to

-phenylenediacrylate monomers with different ester groups

affording a series of cyclobutane-imbedded full-carbon chain polymers with high thermal stability

good solubility

and processibility. In addition

by virtue of the reversibility of the photo [2+2

]

cycloaddition

this [2+2

]

photopolymerization product can also undergo depolymerization to lower molecular weight polymers

suggesting the potential of this class of photopolymerization in the development of closed-loop chemical recyclable polymers.

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Keywords

references

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Photocontrolled Solution [2+2] Polymerization of p-Phenylenediacrylate and Depolymerization

DOI：10.1007/s10118-025-3431-6

摘要

Abstract

关键词

Keywords

references