FOLLOWUS
a.College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China
b.College of Physics and Electromechanical Engineering, Jishou University, Jishou 416000, China
jianhuawu@jsu.edu.cn (J.H.W.)
pnfxz@jsu.edu.cn (X.C.P.)
Received:28 March 2025,
Revised:13 May 2025,
Accepted:18 May 2025,
Published Online:10 October 2025,
Published:2025-06
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Ni, Q. G.; Mi, R.; Ou-Yang, B.; Wu, J. H.; Kong, P.; Li, Y. J.; Peng, X. C. Dual cross-linked eucommia ulmoides gum with reprocessibility, shape memory capability and broadband sound absorption at low frequency. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-025-3384-9
Qing-Gang Ni, Rui Mi, Biao Ou-Yang, et al. Dual Cross-linked Eucommia Ulmoides Gum with Reprocessibility, Shape Memory Capability and Broadband Sound Absorption at Low Frequency[J/OL]. Chinese journal of polymer science, 2025, 431-10.
Ni, Q. G.; Mi, R.; Ou-Yang, B.; Wu, J. H.; Kong, P.; Li, Y. J.; Peng, X. C. Dual cross-linked eucommia ulmoides gum with reprocessibility, shape memory capability and broadband sound absorption at low frequency. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-025-3384-9 DOI:
Qing-Gang Ni, Rui Mi, Biao Ou-Yang, et al. Dual Cross-linked Eucommia Ulmoides Gum with Reprocessibility, Shape Memory Capability and Broadband Sound Absorption at Low Frequency[J/OL]. Chinese journal of polymer science, 2025, 431-10. DOI: 10.1007/s10118-025-3384-9.
An inverse vulcanized polymer
SZIM
combining Zn
2+
-imidazole coordination bonds and polysulfide bonds was synthesized and incorporated in
to bio-based
Eucommia ulmoides gum
(EUG) to generate
EUG-SZIM-x
s. The residual crystallinity of the EUG matrix synergistically interacted with the dual cross-linking networks to establish reversible deformation domains
providing
EUG-SZIM-x
s with quick shape memory capability at moderate temperatures. The damping properties were also investigated
and
EUG-SZIM-x
s displayed high tan
δ
values (
>
0.3) when the
SZIM
dosage was higher than 5.5 phr
which showed a positive correlation with
SZIM
concentration. Such good damping performance endowed the
EUG-SZIM-x
s with broadband low-frequency sound absorption. In addition
the dual cross-linking networks endowed the materials with reprocessability under different catalytic systems
and the 1
8-diazobicyclic[5.4.0
]
undeca-7-ene (DBU)-catalyzed samples exhibited better mechanical properties than
EUG-SZIM-x
s.
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