Dynamic Crosslinked Phosphorescent Poly(vinyl alcohol)-Terpyridine Films with Enhanced Mechanical Properties and Tunable Shape Memory

Meng Wei; Wei-Hao Feng; Chen Yu; Zhen-Yi Jiang; Guang-Qiang Yin; Wei Lu; Tao Chen

doi:10.1007/s10118-024-3189-2

Your Location：

Home >

Browse articles >

Dynamic Crosslinked Phosphorescent Poly(vinyl alcohol)-Terpyridine Films with Enhanced Mechanical Properties and Tunable Shape Memory

RESEARCH ARTICLE | Updated：2024-09-23

- Dynamic Crosslinked Phosphorescent Poly(vinyl alcohol)-Terpyridine Films with Enhanced Mechanical Properties and Tunable Shape Memory
- Chinese Journal of Polymer Science Vol. 42, Issue 10, Pages: 1595-1601(2024)
- Affiliations：
  
  a.Key Laboratory of Advanced Marine Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
  b.School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
  c.School of Materials Science and Chemical Engineering. Ningbo University, Ningbo 315211, China
- Author bio：
  
  yinguangqiang@nimte.ac.cn (G.Q.Y.)
  luwei@nimte.ac.cn (W.L.)
  tao.chen@nimte.ac.cn (T.C.)
- Funds：
- DOI：10.1007/s10118-024-3189-2
  CLC：
- Published：01 October 2024，
  
  Published Online：27 August 2024，
  
  Received：22 May 2024，
  
  Revised：06 June 2024，
  
  Accepted：10 June 2024
- Accepted：
Scan QR Code
Wei, M.; Feng, W. H.; Yu, C.; Jiang, Z. Y.; Yin, G. Q.; Lu, W.; Chen, T. Dynamic crosslinked phosphorescent poly(vinyl alcohol)-terpyridine films with enhanced mechanical properties and tunable shape memory. Chinese J. Polym. Sci. 2024, 42, 1595–1601

Meng Wei, Wei-Hao Feng, Chen Yu, et al. Dynamic Crosslinked Phosphorescent Poly(vinyl alcohol)-Terpyridine Films with Enhanced Mechanical Properties and Tunable Shape Memory. [J]. Chinese Journal of Polymer Science 42(10):1595-1601(2024)
Wei, M.; Feng, W. H.; Yu, C.; Jiang, Z. Y.; Yin, G. Q.; Lu, W.; Chen, T. Dynamic crosslinked phosphorescent poly(vinyl alcohol)-terpyridine films with enhanced mechanical properties and tunable shape memory. Chinese J. Polym. Sci. 2024, 42, 1595–1601 DOI： 10.1007/s10118-024-3189-2.

Meng Wei, Wei-Hao Feng, Chen Yu, et al. Dynamic Crosslinked Phosphorescent Poly(vinyl alcohol)-Terpyridine Films with Enhanced Mechanical Properties and Tunable Shape Memory. [J]. Chinese Journal of Polymer Science 42(10):1595-1601(2024) DOI： 10.1007/s10118-024-3189-2.

摘要

By integrating dynamic lanthanide-Terpyridine coordination

borate ester bonds and hydrogen bondings in poly(vinyl alcohol) matrix

room temperature phosphorescence (RTP) films with multicolor fluorescence

afterglow

enhanced mechanical strength and programmable shape memory were constructed successfully.

Abstract

Achieving versatile room temperature phosphorescence (RTP) materials

especially with tunable mechanical properties and shape memory is attractive and essential but rarely reported. Here

a strategy was reported to realize multi-functional RTP films with multicolor fluorescence

ultralong afterglow

adjustable mechanical properties

and shape memory through the synergistic dynamic interaction of lanthanide (Ln

III

)-terpyridine coordination

borate ester bonds

and hydrogen bondings in a poly(vinyl alcohol) (PVA) matrix. By varying the amount of borax

the mechanical properties of the films could be finely controlled due to the change of crosslinking degree of dynamic borate ester bonds in PVA. The a

ssembly and disassembly of borate ester bonds upon the trigger of borax and acid were applied as reversible linkage to achieve programmable shape memory behavior. In addition

the films displayed both fascinating multicolor fluorescence and ultralong afterglow characteristics due to the presence of Ln

III

doping and confinement of terpyridine in PVA. This study provides a new avenue to impart modulable mechanical strength and shape memory to RTP materials.

关键词

Keywords

Room temperature phosphorescence materialsDynamic bondsMulticolor fluorescentTunable mechanical propertiesShape memory

references

Yin, G.; Zhou, J.; Lu, W.; Li, L.; Liu, D.; Qi, M.; Tang, B. Z.; Théato, P.; Chen, T. Targeting compact and ordered emitters by supramolecular dynamic interactions for high-performance organic ambient phosphorescence.Adv. Mater. 2024 , DOI: 10.1002/adma.202311347..

Yan, X.; Peng, H.; Xiang, Y.; Wang, J.; Yu, L.; Tao, Y.; Li, H.; Huang, W.; Chen, R. Recent advances on host-guest material systems toward organic room temperature phosphorescence.Small2022,18, 2104073..

Ma, X.-K.; Liu, Y. Supramolecular purely organic room-temperature phosphorescence.Acc. Chem. Res.2021,54, 3403−3414..

Liu, Y.; Zhan, G.; Liu, Z. W.; Bian, Z. Q.; Huang, C. H. Room-temperature phosphorescence from purely organic materials.Chinese Chem. Lett.2016,27, 1231−1240..

Gan, N.; Shi, H.; An, Z.; Huang, W. Recent advances in polymer-based metal-free room-temperature phosphorescent materials.Adv. Funct. Mater.2018,28, 1802657..

Li, L.; Zhou, J.; Han, J.; Liu, D.; Qi, M.; Xu, J.; Yin, G.; Chen, T. Finely manipulating room temperature phosphorescence by dynamic lanthanide coordination toward multi-level information security.Nat. Commun.2024,15, 3846..

Yin, G.; Huo, G.; Qi, M.; Liu, D.; Li, L.; Zhou, J.; Le, X.; Wang, Y.; Chen, T. Precisely coordination-modulated ultralong organic phosphorescence enables biomimetic fluorescence-afterglow dual-modal information encryption.Adv. Funct. Mater.2024,34, 2310043..

Wei, J. H.; Ou, W. T.; Luo, J. B.; Kuang, D. B. Zero-dimensional Zn-based halides with ultra-long room-temperature phosphorescence for time-resolved anti-counterfeiting.Angew. Chem. Int. Ed.2022,61, e202207985..

Liu, F.; Li, Z.; Li, Y.; Feng, Y.; Feng, W. Room-temperature phosphorescent fluorine-nitrogen co-doped carbon dots: information encryption and anti-counterfeiting.Carbon2021,181, 9−15..

Zhang, X. D.; Fu, X. H.; Dai, G. K.; Jin, H. W.; Zhang, X.; Bai, J. J.; Ma, J. X.; Ma, Z. Y. Ultralong organic room temperature phosphorescence polymer films based on-dibenzo[a,c]carbazole.Acta Polymerica Sinica(in Chinese)2023,54, 1624−1631..

Ju, H.; Zhang, H.; Hou, L. X.; Zuo, M.; Du, M.; Huang, F.; Zheng, Q.; Wu, Z. L. Polymerization-induced crystallization of dopant molecules: an efficient strategy for room-temperature phosphorescence of hydrogels.J. Am. Chem. Soc.2023,145, 3763−3773..

Zhou, W.-L.; Lin, W.; Chen, Y.; Liu, Y. Supramolecular assembly confined purely organic room temperature phosphorescence and its biological imaging.Chem. Sci.2022,13, 7976−7989..

Zhang, Y.; Li, H.; Yang, M.; Dai, W.; Shi, J.; Tong, B.; Cai, Z.; Wang, Z.; Dong, Y.; Yu, X. Organic room-temperature phosphorescence materials for bioimaging.Chem. Commun.2023,59, 5329−5342..

Hirata, S. Recent advances in materials with room-temperature phosphorescence: photophysics for triplet exciton stabilization.Adv. Opt. Mater.2017,5, 1700116..

Zhou, Y.; Qin, W.; Du, C. Gao, H.; Zhu, F.; Liang, G. Long-lived room-temperature phosphorescence for visual and quantitative detection of oxygen.Angew. Chem. Int. Ed.2019,131, 12230−12234..

Zhou, Y.; Ma, J.; Zhang, P.; Liu, Z., Chi; Z.; Liang, G. Deep-blue ultralong room-temperature phosphorescence from halogen-free organic materials through cage effect for various applications.Adv. Opt. Mater.2021,9, 2100959..

Ma, X.; Wang, J.; Tian, H. Assembling-induced emission: an efficient approach for amorphous metal-free organic emitting materials with room-temperature phosphorescence.Acc. Chem. Res.2019,52, 738−748..

Song, J.; Ma, L.; Sun, S.; Tian, H.; Ma, X. Reversible multilevel stimuli-responsiveness and multicolor room-temperature phosphorescence emission based on a single-component system.Angew. Chem. Int. Ed.2022,134, e202206157..

Shi, J.; Tao, W.; Zhou, Y.; Liang, G. Efficient room-temperature phosphorescence with tunable lifetime through light modulation from flexible polymer films.Chem. Eng. J.2023,475, 146178..

Tao, W.; Zhou, Y.; Lin, F.; Gao, H.; Chi, Z.; Liang, G. Strain-responsive persistent room-temperature phosphorescence from halogen-free polymers for early damage reporting through phosphorescence lifetime and image analysis.Adv. Opt. Mater.2022,10, 2102449..

Zhou, Y.; Zhang, P.; Liu, Z.; Yan, W.; Gao, H.; Liang, G.; Qin, W. Sunlight-activated hour-long afterglow from transparent and flexible polymers.Adv. Mater. 2024 , 2312439..

Wojtecki, R. J.; Meador, M. A.; Rowan, S. J. Using the dynamic bond to access macroscopically responsive structurally dynamic polymers.Nat. Mater.2011,10, 14−27..

Wanasinghe, S. V.; Dodo, O. J.; Konkolewicz, D. Dynamic bonds: adaptable timescales for responsive materials.Angew. Chem. Int. Ed.2022,134, e202206938..

Maeda, T.; Otsuka, H.; Takahara, A. Dynamic covalent polymers: reorganizable polymers with dynamic covalent bonds.Prog. Poly. Sci.2009,34, 581−604..

Liu, K.; Kang, Y.; Wang, Z.; Zhang, X. 25thAnniversary article: Reversible and adaptive functional supramolecular materials: “Noncovalent interaction” matters.Adv. Mater.2013,25, 5530−5548..

Hu, X.-Y.; Xiao, T.; Lin, C.; Huang, F.; Wang, L. Dynamic supramolecular complexes constructed by orthogonal self-assembly.Acc. Chem. Res.2014,47, 2041−2051..

Ni, C. J.; X, T. Spatio-temporal programmable supramolecular shape memory polymer.Acta Polymerica Sinica(in Chinese)2022,53, 1161−1172..

Wang, X.; Li,Y.; S, J. Q. Mechanically robust and healable poly(vinyl alcohol)-based shape memory supramolecular plastics.Acta Polymerica Sinica(in Chinese)2021,52, 1043−1052..

Jian, Y. K.; Lu, W.; Zhang, J. W.; Chen, T. Research Progress in Supramolecular Shape Memory Hydrogels.Acta Polymerica Sinica(in Chinese)2018, 1385−1399..

Chakma, P.; Konkolewicz, D. Dynamic covalent bonds in polymeric materials.Angew. Chem. Int. Ed.2019,58, 9682−9695..

Marco-Dufort, B.; Tibbitt, M. W. Design of moldable hydrogels for biomedical applications using dynamic covalent boronic esters.Mater. Today Chem.2019,12, 16−33..

Huang, S.; Kong, X.; Xiong, Y.; Zhang, X.; Chen, H.; Jiang, W.; Niu, Y.; Xu, W.; Ren, C. An overview of dynamic covalent bonds in polymer material and their applications.Eur. Polym. J.2020,141, 110094..

Cho, S.; Hwang, S. Y.; Oh, D. X.; Park, J. Recent progress in self-healing polymers and hydrogels based on reversible dynamic B–O bonds: boronic/boronate esters, borax, and benzoxaborole.J. Mater. Chem. A2021,9, 14630−14655..

Aeridou, E.; Diaz Diaz, D.; Alemán, C.; Pérez-Madrigal, M. M. Advanced functional hydrogel biomaterials based on dynamic B–O bonds and polysaccharide building blocks.Biomacromolecules2020,21, 3984−3996..

Tang, J.; Ren, Y.; Feng, J. Fluorescence-color-changing biomimetic tough films with simultaneous shape-deformation triggered by pH.Chem. Eng. J.2022,440, 135932..

Le, X.; Lu, W.; Xiao, H.; Wang, L.; Ma, C.; Zhang, J.; Huang, Y.; Chen, T. Fe3+-, pH-, thermoresponsive supramolecular hydrogel with multishape memory effect.ACS Appl. Mater. Inter.2017,9, 9038−9044..

Zhang, Y.; Le, X.; Jian, Y.; Lu, W.; Zhang, J.; Chen, T. 3D fluorescent hydrogel origami for multistage data security protection.Adv. Funct. Mater.2019,29, 1905514..

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

A Composite Elastomer with Photo-responsive Shape Memory and Programmable Hygroscopic Actuation Functionalities

Design of Tough, yet Strong, Heat-resistant PLA/PBAT Blends with Reconfigurable Shape Memory Behavior by Engineering Exchangeable Covalent Crosslinks

Related Author

Guo Li

Xiang-Xi Cui

Li Shang

Zhong-Wen Liu

Zhao-Tie Liu

Jin-Qiang Jiang

Bi-Hua Xia

Xiao-Wen Zhou

Related Institution

Key Laboratory of Syngas Conversion of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University

The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University

Guangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and Devices, South China University of Technology

Suzhou Niumag Analytical Instrument Corporation

State Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University

⁰