Tough Hydrogen Bonding Crosslinked Poly(3-fluorothiophene) Network <italic style="font-style: italic">via</italic> Electrosynthesis for High-performance Electrochromic Supercapacitors

Chun-Hui Du; Yu-Hua Xu; Hui Li; Zhi-Xin Wu; Han-Jun Yang; Xi-Mei Liu; Bao-Yang Lu; Guang-Ming Nie; Ge Zhang

doi:10.1007/s10118-024-3175-8

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Tough Hydrogen Bonding Crosslinked Poly(3-fluorothiophene) Network via Electrosynthesis for High-performance Electrochromic Supercapacitors

RESEARCH ARTICLE | Updated：2024-11-04

- Tough Hydrogen Bonding Crosslinked Poly(3-fluorothiophene) Network via Electrosynthesis for High-performance Electrochromic Supercapacitors
- Chinese Journal of Polymer Science Vol. 42, Issue 11, Pages: 1749-1757(2024)
- Affiliations：
  
  a.Jiangxi Key Lab of Flexible Electronics, Flexible Electronics Innovation Institute, Jiangxi Science & Technology Normal University, Nanchang 330013, China
  b.Key Laboratory of Optic-Electric Sensing and Analytical Chemistry for Life Science, MOE, State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
- Author bio：
  
  luby@jxstnu.edu.cn (B.Y.L.)
  gnie@qust.edu.cn (G.M.N.)
  zhangge20082006@126.com (G.Z.)
- Funds：
- DOI：10.1007/s10118-024-3175-8
  CLC：
- Received：12 April 2024，
  
  Revised：2024-05-08，
  
  Accepted：23 May 2024，
  
  Online First：20 August 2024，
  
  Published：30 November 2024
- Accepted：
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Du, C. H.; Xu, Y. H.; Li, H.; Wu, Z. X.; Yang, H. J.; Liu, X. M.; Lu, B. Y.; Nie, G. M.; Zhang, G. Tough hydrogen bonding crosslinked poly(3-fluorothiophene) network via electrosynthesis for high-performance electrochromic supercapacitors. Chinese J. Polym. Sci. 2024, 42, 1749–1757

Chun-Hui Du, Yu-Hua Xu, Hui Li, et al. Tough Hydrogen Bonding Crosslinked Poly(3-fluorothiophene) Network via Electrosynthesis for High-performance Electrochromic Supercapacitors[J]. Chinese Journal of Polymer Science, 2024, 42(11): 1749-1757. DOI: 10.1007/s10118-024-3175-8.
Du, C. H.; Xu, Y. H.; Li, H.; Wu, Z. X.; Yang, H. J.; Liu, X. M.; Lu, B. Y.; Nie, G. M.; Zhang, G. Tough hydrogen bonding crosslinked poly(3-fluorothiophene) network via electrosynthesis for high-performance electrochromic supercapacitors. Chinese J. Polym. Sci. 2024, 42, 1749–1757 DOI： 10.1007/s10118-024-3175-8.

Chun-Hui Du, Yu-Hua Xu, Hui Li, et al. Tough Hydrogen Bonding Crosslinked Poly(3-fluorothiophene) Network via Electrosynthesis for High-performance Electrochromic Supercapacitors[J]. Chinese Journal of Polymer Science, 2024, 42(11): 1749-1757. DOI: 10.1007/s10118-024-3175-8. DOI：

摘要

A high-performance EC-SC material

PFT

with tough hydrogen bonding cross-linked intermolecular polymer network by one-step electrosynthesis is prepared.

PFT

-based FESDs can be used to visually monitor the energy storage state in real-time and maintain outstanding stability under mechanical distortion like bending.

Abstract

As a type of bi-functional device

electrochromic supercapacitors (EC-SCs) have attracted extensive attention in diverse applications such as flexible electronics. However

despite recent encouraging progress

rational design and development of high-performance EC-SC materials with desirable stability remain challenging for practical applications. Here

we propose a fluorination strategy to develop high-performance EC-SC materials w

ith tough hydrogen bonding cross-linked intermolecular polymer network by one-step electrosynthesis of 3-fluorothiophene. The electrosynthesized free-standing poly(3-fluorothiophene) (PFT

)

films simultaneously achieve high electrochromic performance (optical contrast 42% at 560 nm with reversible color changes between purple and blue)

and good capacitance property (290 F·g

−1

1 A·g

−1

)

as well as outstanding cyclic stability (

2% reduction after 20000 cycles). We further demonstrate the fabrication of PFT-based flexible electrochromic supercapacitor devices (FESDs)

and the resultant devices can be used to visually monitor the energy storage state in real-time and maintain outstanding stability under mechanical distortion like bending. Such a tough fluorination hydrogen bonding cross-linking strategy may provide a new design concept for high-performance EC-SC materials and reliable FESDs toward practical applications.

关键词

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references

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Tough Hydrogen Bonding Crosslinked Poly(3-fluorothiophene) Network via Electrosynthesis for High-performance Electrochromic Supercapacitors

DOI：10.1007/s10118-024-3175-8

摘要

Abstract

关键词

Keywords

references