Recent Progress in Fabrication and Structural Design of Thermal Conductive Polymer Composites

Yuan-Kai Du; Zheng-Xue Shi; Shan Dong; Hui Jin; Xue Ke; Pei Zhao; Bing-Bing Jiang; Feng You

doi:10.1007/s10118-023-3057-5

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Recent Progress in Fabrication and Structural Design of Thermal Conductive Polymer Composites

REVIEW | Updated：2024-02-20

- Recent Progress in Fabrication and Structural Design of Thermal Conductive Polymer Composites
- Chinese Journal of Polymer Science Vol. 42, Issue 3, Pages: 277-291(2024)
- Affiliations：
  
  a.Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, School of Material Science and Engineering, Wuhan Institute of Technology, Wuhan 430205, China
  b.Key Laboratory of Green Preparation and Application of Functional Materials, Ministry of Education, Hubei University, Wuhan 430062, China
  c.Institute of Molecular Aggregation Science, Tianjin University, Tianjin 300072, China
- Author bio：
  
  youfeng.mse@wit.edu.cn
- Funds：
- DOI：10.1007/s10118-023-3057-5
  CLC：
- Received：08 August 2023，
  
  Revised：2023-9-19，
  
  Accepted：27 September 2023，
  
  Online First：10 November 2023，
  
  Published：01 March 2024
- Accepted：
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Du, Y. K.; Shi, Z. X.; Dong, S.; Jin, H.; Ke, X.; Zhao, P.; Jiang, B. B.; You, F. Recent progress in fabrication and structural design of thermal conductive polymer composites. Chinese J. Polym. Sci. 2024, 42, 277–291

Yuan-Kai Du, Zheng-Xue Shi, Shan Dong, et al. Recent Progress in Fabrication and Structural Design of Thermal Conductive Polymer Composites[J]. Chinese Journal of Polymer Science, 2024, 42(3): 277-291.
Du, Y. K.; Shi, Z. X.; Dong, S.; Jin, H.; Ke, X.; Zhao, P.; Jiang, B. B.; You, F. Recent progress in fabrication and structural design of thermal conductive polymer composites. Chinese J. Polym. Sci. 2024, 42, 277–291 DOI： 10.1007/s10118-023-3057-5.

Yuan-Kai Du, Zheng-Xue Shi, Shan Dong, et al. Recent Progress in Fabrication and Structural Design of Thermal Conductive Polymer Composites[J]. Chinese Journal of Polymer Science, 2024, 42(3): 277-291. DOI： 10.1007/s10118-023-3057-5.

摘要

The progress of design fabrication and performance of thermal conductive polymer composites was reviewed in three directions in this work

including the introduction of single filler

hybrid fillers and complex multiphase structures.

Abstract

In recent years

the demand direction for electronic equipment has expanded into embedded and miniaturized devices. The heat radiation problem has become one of the most significant factors for hindering the development of electronic devices. Since heat radiation material is one of the important components in electronic devices

the demand for enhancing thermal conductivity is also increasingly urgent. Research on thermal conductive polymer composites has become a major direction for developing functional composites. This work reviewed the recent progress in the fabrication of thermal conductive polymer composites. Five different structures are presented

including the using of single fillers

hybrid fillers

double threshold percolation structure

segregated structure and other complex multiphase structures. Specifically

the preparation of high-performance thermal conductive polymer composites was introduced through the combination of various thermal conductive fillers. Finally

the development direction of high thermal conductive polymer composites was briefly explored.

关键词

Keywords

references

Leung,S.N.Thermallyconductivepolymercompositesandnanocomposites:processing-structure-propertyrelationships. Compos. B Eng. 2018 , 150 ,78−92..

Xu,H.J.;Xing,Z.B.;Wang,F.Q.;Cheng,Z.M.Reviewonheatconduction,heatconvection,thermalradiationandphasechangeheattransferofnanofluidsinporousmedia:fundamentalsandapplications. Chem. Eng. Sci. 2019 , 195 ,462−483..

Qian,X.;Zhou,J.W.;Zhou,G.Phonon-engineeredextremethermalconductivitymaterials. Nat. Mater. 2021 , 9 ,1188−1202..

Mehra,N;Mu,L.W.Zhu,J.H.Developingheatconductionpathwaysthroughshortpolymerchainsinahydrogenbondedpolymersystem. Compos. Sci. Technol. 2017 , 148 ,97−105..

MehraN,Mu,L.W.;Ji,T.;Yang,X.T.;Kong,J.;Gu,J.W.;Zhu,J.H.Thermaltransportinpolymericmaterialsandacrosscompositeinterfaces. Appl. Mater. Today 2018 , 12 ,92−130..

Huang,X.Y.;Jiang,P.;Tanaka,T.Areviewofdielectricpolymercompositeswithhighthermalconductivity. IEEE Electr. Insul. M. 2011 , 27 ,8−16..

Li,M.;Liu,B.W.;Liu,ZJ.;Xiao,Y.M.;Guo,H.M.;An,Z.H.;Wang,L.D.;James,T.D.ReducingheatConductionenhancesthephotothermalefficiencyofupcycledadsorbents. Adv. Funct. Mater. 2023 , 33 ,2209987..

Chen,G.Non-Fourierphononheatconductionatthemicroscaleandnanoscale. Nat. Rev. Phys. 2021 , 3 ,555−569..

Guo,Y.Q.;Ruan,K.P.;Shi,X.T.;Yang,X.T.;Gu,J.M.Factorsaffectingthermalconductivitiesofthepolymersandpolymercomposites:areview. Compos. Sci. Technol. 2020 , 193 ,108134..

Kausar,A.Thermallyconductingpolymer/nanocarbonandpolymer/inorganicnanoparticlenanocomposite:areview. Polym. Plast. Techol. Mater. 2020 , 59 ,895..

Guo,Y.Q.;Ruan,K.P.;Wang,G.S.;Gu,J.W.Advancesandmechanismsinpolymercompositestowardthermalconductionandelectromagneticwaveabsorption. Sci. Bull. 2023 , 68 ,1195−1212..

Gu,J.;Ruan,K.P.Breakingthroughbottlenecksforthermallyconductivepolymercomposites:aperspectiveforintrinsicthermalconductivity,interfacialthermalresistanceandtheoretics. Nano-Micro Lett. 2021 , 13 ,110..

Swartz,E.T.;Pohl,R.O.Thermalboundaryresistance. Rev. Mod. Phys. 1989 , 61 ,605..

Chen,G.Thermalconductivityandballistic-phonontransportinthecross-planedirectionofsuperlattices. Phy. Rev. B 1998 , 57 ,14958..

Bi,D.M.;Chen,H.X.;Ye,T.Influencesoftemperatureandcontactpressureonthermalcontactresistanceatinterfacesatcryogenictemperatures. Cryogenics 2012 , 52 ,403−409..

Ruan,K.P.;Shi,X.T.;Guo,Y.Q.;Gu,J.M.Interfacialthermalresistanceinthermallyconductivepolymercomposites:areview. Compos. Commun. 2020 , 22 ,100518..

Tan,X.;Yuan,Q.L.Qiu,;M.T.;Yu,N.Jiang,C.T.Lin,J.H.;Dai,W.Rationaldesignofgraphene/polymercompositeswithexcellentelectromagneticinterferenceshieldingeffectivenessandhighthermalconductivity:aminireview. J. Mater. Sci. Technol. 2022 , 117 ,238−250..

Wang,Z.Y.;Sun,X.;Wang,Y.;Liu,J.D.;Zhang,C.;Zhao,Z.B.;Du,X.Y.Ahigh-performancethermallyconductiveandelectricallyinsulatingsilver@siloxane/graphene/epoxycompositesatlowfillercontent:Fabrication,mechanismstudyofinsulationandthermalconductivityenhancement. Ceram. Int. 2023 , 49 ,2871−2880..

Qi,W.;Liu,M.;Wu,J.L.;Xie,Q.;Chen,L.;Yang,X.;Shen,B.Y.;Bian,X.M.;Song,W.L.Promotingthethermaltransport via understandingtheintrinsicrelationbetweenthermalconductivityandinterfacialcontactprobabilityinthepolymericcompositeswithhybridfillers. Compos. Part. B-Eng. 2022 , 232 ,109613..

Xie.B.;Zhu,Y.W.;Marwat,M.A.;Zhang.S.J.;Zhang,L.;Zhang,H.B.Tailoringtheenergystorageperformanceofpolymernanocompositeswithaspectratiooptimized1Dnanofillers. J. Mater. Chem. A 2018 , 6 ,20356−20364..

Li,C.;Zeng,X.L.;Tan,L.Y.;Yao,Y.M.;Zhu,D.L.;Sun,R.;Xu,J.B.;Wong,C.P.Three-dimensionalinterconnectedgraphenemicrosphereasfillersforenhancingthermalconductivityofpolymer. Chem. Eng. J. 2019 , 368 ,79−87..

An,L.L.;Yu,Y.L.;Cai,Q.R.;Mateti,S.;Li,L.H.;Chen,Y.I.Hexagonalboronnitridenanosheets:preparation,heattransportpropertyandapplicationasthermallyconductivefillers. Prog. Mater. Sci. 2023 , 138 ,101154..

Liu,M.J.;Chiang,S.W.;Chu,X.D.;Li,J.;Gan,L.;He,Y.B.;Li,B.H.;Kang,F.Y.;Du,H.D.Polymercompositeswithenhancedthermalconductivityviaorientedboronnitrideandaluminahybridfillersassistedby3-Dprinting. Ceram. Int. 2020 , 46 ,20810−20818..

Maxwell,J.C. A treatise on electricity and magnetism ,ClarendonPress,Oxford, 1873 ,p.478..

Bruggemann,D.A.G.Dielectricconstantandconductivityofmixturesofisotropicmaterial. Ann. Phys. 1935 , 24 ,636−664..

Agari,Y.;Uno,T.Estimationonthermalconductivitiesoffilledpolymers. J. Appl. Polym. Sci. 1986 , 32 ,5705−5712..

Zhang,G.Q.;Xia,X.P.;Wang,H.;Tao,Y.;Tao,G.L.;Tu,S.T.;Wu,H.P.Apercolationmodelofthermalconductivityforfilledpolymercomposites. J. Compos. Mater. 2010 , 44 ,963−970..

Guo,Y.Q.;Ruan,K.P.;Gu,J.W.Controllablethermalconductivityincompositesbyconstructingthermalconductionnetworks. Mater. Today Phys. 2021 , 20 ,100449..

Li,A.;Zhang,C.;Zhang,Y.F.Thermalconductivityofgraphene-polymercomposites,mechanisms,properties,andapplications. Polymers 2017 , 9 ,437..

Shen,Z.M.;Feng,J.C.Highlythermallyconductivecompositefilmsbasedonnanofibrillatedcellulose in situ coatedwithasmallamountofsilvernanoparticle. ACS Appl. Mater. Interfaces 2018 , 10 ,24193−24200..

Krupa,I.;Cecen,V.;Boudenne,A.;Prokes,J.;Novak,I.Themechanicalandadhesivepropertiesofelectricallyandthermallyconductivepolymericcompositesbasedonhighdensitypolyethylenefilledwithnickelpowder. Mater. Des. 2013 , 51 ,620−628..

Wang,Y.;Chen,Q.M.;Liu,C.;Li,S.;Wu,W.HighlyenhancedthermalconductivityofTPUcompositeswithsegregatednetworkconstructedbythein-situreductionofcopper. J. Alloy. Compd. 2023 , 941 ,168801..

Chen,W.;Wang,Z.F.;Zhi,C.Y.;Zhang,W.J.Highthermalconductivityandtemperatureprobingofcoppernanowire/upconversionnanoparticles/epoxycomposite. Compos. Sci. Technol. 2016 , 130 ,63−69..

Ota,S.;Harada,M.Thermalconductivityenhancementofliquidcrystallineepoxy/MgOcompositesbyformationofhighlyorderednetworkstructure. J. Appl. Polym. Sci. 2020 , 138 ,50367..

Wondu,E.;Lule,Z.;Kim,J.Thermalconductivityandmechanicalpropertiesofthermoplasticpolyurethane-/silane-modifiedAl 2 O 3 compositefabricated via meltcompounding. Polymers 2019 , 11 ,1103..

Yeo,H.;Islam,A.M.;You,N.H.;Ahn,S.;Goh,M.;Hahn,J.R.;Jang,S.G.Characteristiccorrelationbetweenliquidcrystallineepoxyandaluminafilleronthermalconductingproperties. Compos. Sci. Technol. 2017 , 141 ,99−105..

Guo,L.C.;Zhang,Z.Y.;Kang,R.Y.;Chen,Y.P.;Hou,X.;Wu,Y.M.;Wang,M.J.;Wang,B.;Cui,J.F.;Jiang,N.;Lin,C.T.;Yu,J.H.Enhancedthermalconductivityofepoxycompositesfilledwithtetrapod-shapedZnO. RSC Adv. 2018 , 8 ,12337−12343..

Yuan,Y.;Li,Z.T.;Cao,L.;Tang,B.;Zhang,S.R.ModificationofSi 3 N 4 ceramicpowdersandfabricationofSi 3 N 4 /PTFEcompositesubstratewithhighthermalconductivity. Ceram. Int. 2019 , 45 ,16569−16576..

Lee,W.;Kim,J.Highlythermalconductiveandelectricalinsulatingepoxycompositeswithathree-dimensionalfillernetworkbysinteringsilvernanowiresonaluminumnitridesurface. Polymers 2021 , 13 ,694..

Zhang,Z.Y.;Wu,D.;Yang,H.;Qu,H.C.;Yao,C.;Liu,F.J.;Yu,P.;Yao,J.L.;You,F.;Jiang,X.L.Remarkableenhancementinthermalperformanceofpolypropylenecarbonatebyusingexfoliatedboronnitridenanosheets. Chem. Eng. J. 2022 , 450 ,138247..

Liu,B.C.;Li,Y.B.;Fei,T.;Han,S.;Xia,C.B.;Shan,Z.H.;Jiang,J.L.Highlythermallyconductivepolystyrene/polypropylene/boronnitridecompositeswith3Dsegregatedstructurepreparedbysolution-mixingandhot-pressingmethod. Chem. Eng. J. 2020 , 385 ,123829..

Zhang,X.W.;Zhang,B.;Sun,M.M.;Li,J.H.;Liu,C.Z.Preparationandthermalconductivitypropertiesofhigh-temperatureresistancepolyimidecompositefilmsbasedonsilvernanowires-decoratedmulti-walledcarbonnanotubes. J .Mater. Sci. Mater. Electron. 2022 , 33 ,1577−1588..

Lin,Y.;Lang,F.;Zeng,D.;You,Y.L.;Li,D.X.;Xiao,C.G.EffectsofmodifiedgrapheneonpropertyoptimizationinthermalconductivecompositesbasedonPPS/PA6blend. Soft Mater. 2021 , 19 ,457−467..

Wang,Y.Y.;Zhang,X.;Ding,X.;Li,Y.;Zhang,P.;Shu,M.T.;Zhang,Q.;Gong,Y.;Zheng,K.;Wu,B.;Tian,X.Y.Enhancedthermalconductivityofcarbonnitride-dopedgraphene/polyimidecompositefilm via a"deciduous-like"strategy. Compos. Sci. Technol. 2021 , 205 ,108693..

Ma,J.K.;Shang,T.Y.;Ren,L.L.;Yao,Y.M.;Zhang,T.;Xie,J.Q.;Zhang,B.T.;Zeng,X.L.;Sun,R.;Xu,J.B.;Wong,C.P.Through-planeassemblyofcarbonfibersinto3Dskeletonachievingenhancedthermalconductivityofathermalinterfacematerial. Chem. Eng. J. 2020 , 380 ,122550..

Zhan,C.;Cui,W.Z.;Li,L.J.;Quan,X.J.;Zhang,Y.Q.;Xiao,F.Dual-Alignedcarbonnanofiberscaffoldsasheatconductionpathtoenhancethermalconductivityofpolymercomposites. Compos. Sci. Technol. 2023 , 231 ,109823..

Wang,X.G.;Zhang,C.Y.;Wang,K.;Huang,Y.Q.;Chen,Z.F.Highlyefficientphotothermalconversioncapricacidphasechangemicrocapsule:Siliconcarbidemodifiedmelamineureaformaldehyde. J. Colloid Interface Sci. 2021 , 582 ,30−40..

Li,C.L.;Guo,H.L.;Tian,X.;Tian,X.G.Transientresponseforahalf-spacewithvariablethermalconductivityanddiffusivityunderthermalandchemicalshock. J. Therm. Stresses 2017 , 40 ,389−401..

Guo,Y.Q.;Yang,X.T.;Ruan,K.P.;Kong,J.;Dong,M.Y.;Zhang,J.X.;Gu,J.W.;Guo,Z.H.Reducedgrapheneoxideheterostructuredsilvernanoparticlessignificantlyenhancedthermalconductivitiesinhot-pressedelectrospunpolyimidenanocomposites. ACS Appl. Mater. Interfaces 2019 , 11 ,25465−25473..

Nayak,S.K.;Mohanty,S.;Nayak,S.K.Silver(Ag)nanoparticle-decoratedexpandedgraphite(EG)epoxycomposite:evaluatingthermalandelectricalproperties. J. Mater. Sci.-Mater. Electron. 2019 , 30 ,20574−20587..

Wang,Y.;Wu,W.;Drummer,D.;Liu,C.;Shen,W.T.;Tomiak,F.;Schneider,K.;Liu,X.R.;Chen,Q.M.Highlythermallyconductivepolybenzoxazinecompositesbasedonboronnitrideflakesdepositedwithcopperparticles. Mater. Des. 2020 , 191 ,108698..

Liu,C.;Wu,W.;Drummer,D.;Shen,W.T.;Wang,Y.;Schneider,K.;Tomiak,F.ZnOnanowire-decoratedAl 2 O 3 hybridsforimprovingthethermalconductivityofpolymercomposites. J. Mater. Chem. C 2020 , 8 ,5380−5388..

Lule,Z.;Kim,J.Thermallyconductiveandhighlyrigidpolylacticacid(PLA)hybridcompositefilledwithsurfacetreatedalumina/nano-sizedaluminumnitride. Compos. Part A: Appl. Sci. Manuf. 2019 , 124 ,105506..

Liu,Y.C.;Lu,M.P.;Wu,K.;Yao,S.;Du,X.X.;Chen,G.K.;Zhang,Q.;Liang,L.Y.;Lu,M.G.Anisotropicthermalconductivityandelectromagneticinterferenceshieldingofepoxynanocompositesbasedonmagneticdrivingreducedgrapheneoxide@Fe 3 O 4 . Compos. Sci. Technol. 2019 , 174 ,1−10..

Niu,H.Y.;Guo,H.C.;Ren,Y.J.;Ren,L.C.;Lv,R.C.;Kang,L.;Bashir,A.;Bai,S.L.SphericalaggregatedBN/AlNfilledsiliconecompositeswithenhancedthrough-planethermalconductivityassistedbyvortexflow. Chem. Eng. J. 2022 , 430 ,133155..

Yao,Y.M.;Sun,J.J.;Zeng,X.L.;Sun,R.;Xu,J.B.;Wong,C.P.Constructionof3Dskeletonforpolymercompositesachievingahighthermalconductivity. Small 2018 , 14 ,1704044..

Jiang,X.L.;Ma,P.F.;Zhou,C.;Zhu,W.W.;You,F.;Yao,C.;Liu,F.J.SimultaneouslyenhancingthethermalconductivityanddielectricconstantofBN/CFhybridfilledpolypropylene/polystyrenecomposites via in situ reactiveprocessing. Polym. Compos. 2019 , 41 ,1234−1241..

Xie,X.;Yang,D.Achievinghighthermalconductivityandsatisfactoryinsulatingpropertiesofelastomercompositesbyself-assemblingBN@GOhybrids. Polymers 2023 , 15 ,523..

Wu,H.C.;Zhou,W.Q.;Liu,Q.;Cai,X.;Qu,Z.H.;Li,P.;Hu,D.;Jia,X.L.Highpressurehomogenizationofgrapheneandcarbonnanotubeforthermalconductivepolyethylenecompositewithalowfillercontent. J. Appl. Polym. Sci. 2021 , 139 ,51838..

Jiang,Z.L.;Liu,X.;Xu,Q.F.;Zhou,C.Y.;Shang,Y.S.;Zhang,H.B.Thermalconductivesegregatedmulti-scalenetworkconstructedbyball-millingand in-situ polymerizationinPEEK/MWCNT/graphitecomposite. Compos. Commun. 2022 , 29 ,101035..

Song,J.N.;Zhang,Y.Verticallyalignedsiliconcarbidenanowires/reducedgrapheneoxidenetworksforenhancingthethermalconductivityofsiliconerubbercomposites. Compos. Pt. A Appl. Sci. Manuf. 2020 , 133 ,105873..

Ouyang,Y.G.;Bai,L.Y.;Tian,H.F.;Li,X.F.;Yuan,F.L.Recentprogressofthermalconductiveploymercomposites,Al 2 O 3 fillers,propertiesandapplications. Compos. Pt. A Appl. Sci. Manuf. 2022 , 152 ,106685..

Su,F.;Zhang,L.;Li,C.Z.High-thermal-conductionandlow-costcompositeoriginatedfromthetightpackingstructureofboronnitridesheetsandbinaryaluminaballs. Polym. Compos. 2021 , 42 ,3562−3571..

Kozlovskiy,A.L.;Zdorovets,M.V.;Uglov,V.V.Studyofchangesinopticalandheat-conductingpropertiesofAlNceramicsunderirradiationwithKr 15+ andXe 22+ heavyion. Nanomaterials 2020 , 10 ,2375..

Du,J.J.;Dai,W.J.;Kou,H.J.;Wu,P.F.;Xing,W.L.;Zhang,Y.Z.;Zhang,C.AlNcoatingswithhighthermalconductivityandexcellentelectricalpropertiesforthermalmanagementdevices. Ceram. Int. 2023 , 49 ,16740−16752..

Akkoyun,S.;Akkoyun,M.Improvementofthermalconductivityofrigidpolyurethanefoamswithaluminumnitridefiller. Cell. Polym. 2021 , 40 ,87..

Lee,S.;Park,D.;Kim,J.3D-printedsurface-modifiedaluminumnitridereinforcedthermallyconductivecompositeswithenhancedthermalconductivityandmechanicalstrength. Polym. Adv. Technol . 2022 , 33 ,1291−1297..

Hu,J.T.;Huang,Y.;Yao,Y.M.;Pan,G.R.;Sun,J.J.;Zeng,X.L.;Sun,R.;Xu,J.B.;Song,B.;Wong,C.P.Polymercompositewithimprovedthermalconductivitybyconstructingahierarchicallyorderedthree-dimensionalinterconnectednetworkofBN. ACS Appl. Mater. Interfaces 2017 , 9 ,13544−13553..

Jung,D.W.;Kim,J.M.;Yoon,H.W.;Nam,K.M.;Kwon,Y.E.;Jeong,S.;Baek,Y.H.;Choi,Y.S.;Chang,S.J.;Yi,G.R.;Cha,J.Y.;Lee,G.Solution-processablethermallyconductivepolymercompositeadhesivesofbenzyl-alcohol-modifiedboronnitridetwo-dimensionalnanoplates. Chem. Eng. J. 2019 , 361 ,783−791..

Su,X.;Wang,R.Y.;Li,X.F.;Araby,S.;Kuan,H.C.;Naeem,M.;Ma,J.Acomparativestudyofpolymernanocompositescontainingmulti-walledcarbonnanotubesandgraphenenanoplatelets. Nano Mater. Sci. 2022 , 4 ,185−204..

Burger,N.;Laachachi,A.;Ferriol,M.;Lutz,M.;Toniazzo,V.;Ruch,D.Reviewofthermalconductivityincomposites:mechanisms,parametersandtheory. Prog. Polym. Sci. 2016 , 61 ,1−28..

Che,J.W.;Cagin,T.;GoddardIII,W.A.Thermalconductivityofcarbonnanotubes. Nanotechnology 2000 , 11 ,65..

Han,Z.;Fina,A.Thermalconductivityofcarbonnanotubesandtheirpolymernanocomposites:areview. Prog. Polym. Sci. 2011 , 36 ,914−944..

Thostenson,E.T.;Chou,T.W.Processing-structure-multi-functionalpropertyrelationshipincarbonnanotube/epoxycomposites. Carbon 2006 , 44 ,3022−3029..

Yuan,S.Q.;Bai,J.M.;Chua,C.K.;Wei,J.;Zhou,K.HighlyenhancedthermalconductivityofthermoplasticnanocompositeswithalowmassfractionofMWCNTsbyafacilitatedlatexapproach. Compos. Part A: Appl. Sci. Manuf. 2016 , 90 ,699−710..

Wu,N.;Che,S.;Li,H.W.;Wang,C.N.;Tian,X.J.;Li,Y.F.Areviewofthree-dimensionalgraphenenetworksforuseinthermallyconductivepolymercomposites:constructionandapplications. New Carbon Mater. 2021 , 36 ,911−926..

Zhang,F.;Feng,Y.Y.;Feng,W.Three-dimensionalinterconnectednetworksforthermallyconductivepolymercomposites:design,preparation,properties,andmechanismsMater. Sci. Eng. R-Rep . 2020 , 142 ,100580..

Liu,P.F.;Li,X.F.;Min,P.;Chang,X.Y.;Shu,C.;Ding,Y.;Yu,Z.Z.3Dlamellar-structuredgrapheneaerogelsforthermalinterfacecompositeswithhighthrough-planethermalconductivityandfracturetoughness. Nano-Micro Lett . 2021 , 13 ,1..

Wang,F.Z.;Zhang,S.;Li,X.Q.;Wang,W.;Shi,M.X.;Huang,Z.X.;Li,C.S.Constructionoffunctionalizedgraphenenanoplatelets/SiCnanowireshybridskeletonforepoxycompositeswithenhancedthermalconductivityandthermomechanicalproperties. Mater. Res. Bull. 2023 , 162 ,112189..

Eksik,O.;Bartolucci,S.F.;Gupta,T.;Fard,H.;Tasciuc,T.B.;Koratkar,N.Anovelapproachtoenhancethethermalconductivityofepoxynanocompositesusinggraphenecore-shelladditives. Carbon. 2016 , 101 ,239−244..

Tao,J.R.;Luo,C.L.;Huang,M.L.;Weng,Y.X.;Wang,M.Constructionofuniqueconductivenetworksincarbonnanotubes/polymercompositesviapoly( ε -caprolactone)inducingpartialaggregationofcarbonnanotubesformicrowaveshieldingenhancement. Compos. Part A: Appl. Sci. Manuf. 2023 , 164 ,107304..

Luo,F.B.;Yang,S.G.;Yan,P.P.;Li,H.Z.;Huang,B.Q.;Qian,Q.R.;Chen,Q.H.Orientationbehaviorandthermalconductivityofliquidcrystalpolymercompositesbasedonthree-dimensionalprinting. Compos. Part A Appl. Sci. Manuf. 2022 , 160 ,107059..

Min,S.B.;Kim,M.;Hyun,K.;Ahn,C.W.;Kim,C.B.Thermallyconductive2Dfillerorientationcontrolinpolymerusingthermophoresis. Polym. Test. 2023 , 117 ,107838..

Yu,S.;Shen,X.;Kim,J.K.Beyondhomogeneousdispersion:orientedconductivefillersforhigh k nanocomposites. Mater. Horiz. 2021 , 8 ,3009−3042..

Han,J.K.;Du,G.L.;Gao,W.W.;Bai,H.Ananisotropicallyhighthermalconductiveboronnitride/epoxycompositebasedonnacre-mimetic3Dnetwork. Adv. Funct. Mater. 2019 , 29 ,1900412..

Jiao,D.J.;Song,N.;Ding,P.;Shi,L.Y.Enhancedthermalconductivityinorientedcellulosenanofibril/graphenecompositesviainterfacialengineering. Compos. Commun. 2022 , 31 ,101101..

Mao,L.;Han,J.B.;Zhao,D.;Song,N.;Shi,L.Y.;Wane,J.H.Particlepackingtheoryguidedthermalconductivepolymerpreparationandrelatedproperties. ACS Appl. Mater. Interfaces 2018 , 10 ,33556−33563..

Ma,M.;Chu,Q.D.;Lin,H.;Xu,L.;He,H.W.;Shi,Y.Q.;Chen,S.;Wang,X.Highlyanisotropicthermalconductivityandelectricalinsulationofnanofibrillatedcellulose/Al 2 O 3 @rGOcompositefilms:effectoftheparticlesize. Nanotechnology 2022 , 33 ,135711..

Li,R.;Yang,X.;Li,J.;Shen,Y.;Zhang,L.;Lu,R.;Wang,C.;Zheng,X.;Chen,H.;Zhang,T.Reviewonpolymercompositeswithhighthermalconductivityandlowdielectricpropertiesforelectronicpackaging. Mater. Today Phys. 2022 , 22 ,100594..

Hao,M.;Qian,X.;Zhang,Y.G.;Yang,J.M.;Li,C.J.;Gong,H.T.;Wang,X.F.;Wang,P.P.;Liu,L.;Huang,Y.D.Thermalconductivityenhancementofcarbonfiber/epoxycomposites via constructingthree-dimensionallyalignedhybridthermalconductivestructuresonfibersurfaces. Compos. Sci. Technol. 2023 , 231 ,109800..

Wu,W.F.;Ren,T.L.;Liu,X.Q.;Davis,R.;Huai,K.;Cui,X.;Wei,H.X.;Hu,J.J.;Xia,Y.M.;Huang,S.H.;Qiang,Z.;Fu,K.;Zhang,J.M.;Chen,Y.W.Creatingthermalconductivepathwaysinpolymermatrixbydirectionalassemblyofsynergisticfillersassistedbyelectricfields. Compos. Commun. 2022 , 35 ,101309..

Wen,Y.F.;Chen,C.;Ye,Y.S.;Xue,Z.G.;Liu,H.Y.;Zhou,X.P.;Zhang,Y.;Li,D.Q.;Xie,X.L.;Mai,Y.W.Advancesonthermallyconductiveepoxy-basedcompositesaselectronicpackagingunderfillmaterials—areview. Adv. Mater. 2022 , 34 ,2201023..

Hu,Z.F.;Zhao,T.T.;Dong,L.J.;Zhang,Y.Polyhedraloligosilsesquioxane-modifiedalumina/aluminumnitride/siliconerubbercompositestoenhancedielectricpropertiesandthermalconductivity. J. Electron. Mater. 2022 , 51 ,2308−2315..

Lule,Z.C.;Kim,J.Organic-inorganichybridfillerforimprovedthermalconductivityandanti-drippingperformanceofpolybutylenesuccinatecomposite. J. Clean Prod. 2022 , 340 ,130781..

Yu,A.P.;Ramesh,P.;Sun,X.B.;Bekyarova,E.;Itkis,M.E.;Haddon,R.C.Enhancedthermalconductivityinahybridgraphitenanoplatelet-carbonnanotubefillerforepoxycomposites. Adv. Mater. 2008 , 20 ,4740−4744..

Niu,N.T.;Zhang,Y.;Xiao,G.;He,X.H.;Yao,Y.G.Preparationofquasi-isotropicthermalconductivecompositesbyinterconnectingsphericalaluminaand2Dboronnitrideflakes. Rare Metals 2023 , 42 ,1283−1293..

Zhang,X.;Song,J.A.;Meng,J.J.;Zhang,K.AnisotropicPDMS/alumina/carbonfibercompositeswithahighthermalconductivityandanelectromagneticinterferenceshieldingperformance. Materials 2022 , 15 ,8078..

Kashfipour,M.A.;Guo,M.L.;Mu,L.W.;Mehra,N.;Cheng,Z.H.;Olivio,J.;Zhu,S.S.;Maia,J.M.;Zhu,J.H.Carbonnanofiberreinforcedco-continuousHDPE/PMMAcomposites:exploringtheroleofviscosityratioonfillerdistributionandelectrical/thermalproperties. Compos. Sci. Technol. 2019 , 184 ,107859..

Huang,Y.;Ellingford,C.;Bowen,C.;McNally,T.;Wu,D.M.;Wan,C.Y.Tailoringtheelectricalandthermalconductivityofmulti-componentandmulti-phasepolymercomposites. Int. Mater. Rev. 2020 , 65 ,129−163..

Wu,W.J.;Liu,H.W.;Wang,Z.Y.;Lv,P.;Hu,E.T.;Zheng,J.J.;Yu,K.H.;Wei,W.Formationofthermalconductivenetworkinboronnitride/polyvinylalcoholbyice-templatedself-assembly. Ceram. Int. 2021 , 47 ,33926−33929..

Chen,X.L.;Lim,J.S.K.;Yan,W.L.;Guo,F.;Liang,Y.N.;Chen,H.;Lambourne,A.;Hu,X.SalttemplateassistedBNscaffoldfabricationtowardhighlythermallyconductiveepoxycomposites. ACS Appl. Mater. Interfaces 2020 , 12 ,16987−16996..

Yang,W.;Wang,Y.F.;Li,Y.;Gao,C.;Tian,X.J.;Wu,N.;Geng,Z.S.;Che,S.;Yang,F.;Li,Y.F.Three-dimensionalskeletonassembledbycarbonnanotubes/boronnitrideasfillerinepoxyforthermalmanagementmaterialswithhighthermalconductivityandelectricalinsulation. Compos. Part B Eng. 2021 , 224 ,109168..

Xu,X.W.;Hu,R.C.;Chen,M.Y.;Dong,J.F.;Xiao,B.;Wang,Q.;Wang,H.3Dboronnitridefoamfilledepoxycompositeswithsignificantlyenhancedthermalconductivitybyafacialandscalableapproach. Chem. Eng. J . 2020 , 397 ,125447..

Fu,H.B.;Huang,Y.;Liu,Y.;Li,F.;Gai,Z.P.;Jiang,Y.;Gao,X.L.;Zhuang,J.;Sun,J.Y.;Xu,H.;Wu.D.M.Enhancedthermalconductionofhybridfiller/polydimethylsiloxanecomposites via acontinuousspatialconfiningprocess. Compos. Sci. Technol. 2022 , 226 ,109536..

Sumita,M.;Sakata,K.;Asai,S.;Miyasaka,K.;Nakagawa,H.Dispersionoffillersandtheelectricalconductivityofpolymerblendsfilledwithcarbonblack. Polym. Bull. 1991 , 25 ,265−271..

Li,T.T.;Wang,Y.X.;Wang,Y.T.;Sun,F.;Xu,J.W.;Lou,C.W.;Lin,J.H.Preparationofflexible,highlyconductivepolymercompositefilmsbasedondoublepercolationstructuresandsynergisticdispersioneffect. Polym. Compos. 2021 , 42 ,5159−5167..

Cao,J.P.;Zhao,X.D.;You,F.;Yu,H.Z.;Hu,G.H.;Dang,Z.M.Highthermalconductivityandhighelectricalresistivityofpoly(vinylidenefluoride)/polystyreneblendsbycontrollingthelocalizationofhybridfillers. Compos. Sci. Technol. 2013 , 89 ,142−148..

Yang,L.;Zheng,Y.;Hou,M.;Chen,W.Y.;Wang,Z.Q.Constructingofhighlyordered3Dnetworkofcarbonnanotubeinsidepolymermatrixandtheimprovementsinpropertiesofthecomposites. Am. J. Polym. Sci. Technol. 2019 , 5 ,9−15..

Li,M.D.;Wang,Y.X.;Wang,Y.T.;Sun,F.;Xu,J.W.;Lou,C.W.;Lin,J.H.Thermalmanagementofchipsbyadeviceprototypeusingsynergisticeffectsof3-Dheat-conductivenetworkandelectrocaloricrefrigeration. Nat. Commun. 2022 , 13 ,5849..

Wang,J.Q.;Hu,L.;Li,W.H.;Ouyang,Y.G.;Bai,L.Y.Developmentandperspectivesofthermalconductivepolymercomposites. Nanomaterials 2022 , 12 ,3574..

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