Structure-Property Relationship Analysis of <sub>D</sub>-Penicillamine-Derived <italic style="font-style: italic">β</italic>-Polythioesters with Varied Alkyl Side Groups

Chun-Yan Lyu; Wei Xiong; Er-Qiang Chen; Hua Lu

doi:10.1007/s10118-023-3001-8

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Structure-Property Relationship Analysis of _D-Penicillamine-Derived β-Polythioesters with Varied Alkyl Side Groups

RESEARCH ARTICLE | Updated：2023-09-21

- Structure-Property Relationship Analysis of _D-Penicillamine-Derived β-Polythioesters with Varied Alkyl Side Groups
- Chinese Journal of Polymer Science Vol. 41, Issue 10, Pages: 1555-1562(2023)
- Affiliations：
  
  Beijing National Laboratory for Molecular Sciences, Center for Soft Matter Science and Engineering, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
- Author bio：
  
  eqchen@pku.edu.cn (E.Q.C.)
  chemhualu@pku.edu.cn (H.L.)
- Funds：
- DOI：10.1007/s10118-023-3001-8
  CLC：
- Received：07 April 2023，
  
  Revised：2023-5-4，
  
  Accepted：11 May 2023，
  
  Online First：14 June 2023，
  
  Published：01 October 2023
- Accepted：
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Lyu, C. Y.; Xiong, W.; Chen, E. Q.; Lu, H. Structure-property relationship analysis of _D-penicillamine-derived β-polythioesters with varied alkyl side groups. Chinese J. Polym. Sci. 2023, 41, 1555–1562 DOI: 10.1007/s10118-023-3001-8.

Chun-Yan Lyu, Wei Xiong, Er-Qiang Chen, et al. Structure-Property Relationship Analysis of _D-Penicillamine-Derived β-Polythioesters with Varied Alkyl Side Groups[J]. Chinese Journal of Polymer Science, 2023, 41(10): 1555-1562. DOI: 10.1007/s10118-023-3001-8.
Lyu, C. Y.; Xiong, W.; Chen, E. Q.; Lu, H. Structure-property relationship analysis of _D-penicillamine-derived β-polythioesters with varied alkyl side groups. Chinese J. Polym. Sci. 2023, 41, 1555–1562 DOI: 10.1007/s10118-023-3001-8. DOI：

Chun-Yan Lyu, Wei Xiong, Er-Qiang Chen, et al. Structure-Property Relationship Analysis of _D-Penicillamine-Derived β-Polythioesters with Varied Alkyl Side Groups[J]. Chinese Journal of Polymer Science, 2023, 41(10): 1555-1562. DOI: 10.1007/s10118-023-3001-8. DOI：

摘要

This work successfully synthesized a series of β-thiolactones with β-geminal dimethyl substitution and varied alkyl side groups. By virtue of Thorpe-Ingold effect

the ring-opening polymerization was highly controlled and the obtained polymers were completely depolymerizable. Moreover

a preliminary structure-property relationship between side chain structure and material thermal property was established.

Abstract

The ring-opening polymerization of heterocyclic monomers and the reversed ring-closing depolymerization of corresponding polymers with neutral thermodynamics are broadly explored to establish a circular economy of next-generation plastics. Polythioesters (PTEs)

analogues of polyesters

are emerging materials for this purpose due to their high refractive index

high crystallinity

dynamic property and responsiveness. In this work

we synthesize and polymerize a series of

-penicillamine-derived

-thiolactones (N

PenTL) with varied side chain alkyl groups

and study the structure-property relationship of the resulting polymers. The obtained PTEs exhibit tunable glass transition temperature in a wide range of 130−50 °C

and melting temperature of 90−105 °C. In addition

copolymerizations of monomers with different side chains are effective in modulating material properties. The obtained homo and copolymers can be fully depolymerized to recycle monomers. This work provides a robust molecular platform and detailed structure-property relationship of PTEs with potential of achieving sustainable plastics.

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Structure-Property Relationship Analysis of D-Penicillamine-Derived β-Polythioesters with Varied Alkyl Side Groups

DOI：10.1007/s10118-023-3001-8

摘要

Abstract

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Keywords

references

Structure-Property Relationship Analysis of _D-Penicillamine-Derived β-Polythioesters with Varied Alkyl Side Groups