Stabilize and Reinforce Hydrogen-Bonded Polymer Complex Elastic Fiber by Catechol Chemistry and Coordination

Ze-Xin Liu; De-Zhong Liu; Cai-Hong Zhang; Wei-Jie Wang; Hao Huang; Shu-Guang Yang

doi:10.1007/s10118-023-2992-5

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Stabilize and Reinforce Hydrogen-Bonded Polymer Complex Elastic Fiber by Catechol Chemistry and Coordination

RESEARCH ARTICLE | Updated：2023-11-27

- Stabilize and Reinforce Hydrogen-Bonded Polymer Complex Elastic Fiber by Catechol Chemistry and Coordination
- Chinese Journal of Polymer Science Vol. 41, Issue 12, Pages: 1846-1855(2023)
- Affiliations：
  
  State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
- Author bio：
  
  shgyang@dhu.edu.cn
- Funds：
- DOI：10.1007/s10118-023-2992-5
  CLC：
- Received：01 March 2023，
  
  Revised：2023-4-14，
  
  Accepted：17 April 2023，
  
  Online First：12 June 2023，
  
  Published：01 December 2023
- Accepted：
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Liu, Z. X.; Liu, D. Z.; Zhang, C. H.; Wang, W. J.; Huang, H.; Yang, S. G. Stabilize and reinforce hydrogen-bonded polymer complex elastic fiber by catechol chemistry and coordination. Chinese J. Polym. Sci. 2023, 41, 1846–1855

Ze-Xin Liu, De-Zhong Liu, Cai-Hong Zhang, et al. Stabilize and Reinforce Hydrogen-Bonded Polymer Complex Elastic Fiber by Catechol Chemistry and Coordination[J]. Chinese Journal of Polymer Science, 2023, 41(12): 1846-1855.
Liu, Z. X.; Liu, D. Z.; Zhang, C. H.; Wang, W. J.; Huang, H.; Yang, S. G. Stabilize and reinforce hydrogen-bonded polymer complex elastic fiber by catechol chemistry and coordination. Chinese J. Polym. Sci. 2023, 41, 1846–1855 DOI： 10.1007/s10118-023-2992-5.

Ze-Xin Liu, De-Zhong Liu, Cai-Hong Zhang, et al. Stabilize and Reinforce Hydrogen-Bonded Polymer Complex Elastic Fiber by Catechol Chemistry and Coordination[J]. Chinese Journal of Polymer Science, 2023, 41(12): 1846-1855. DOI： 10.1007/s10118-023-2992-5.

摘要

PEO/PAA-Dopa/Metal fibers were constructed by the synergy interactions of hydrogen bonds

coordinate bonds and covalent bonds. Compared with hydrogen-bonded PEO/PAA fibers

PEO/PAA-Dopa/Metal fibers show high stiffness

strength and toughness

and quick recovery.

Abstract

Hydrogen-bonded polymer complex fiber of poly(ethylene oxide) (PEO) and poly(acrylic acid) (PAA) shows rubber elasticity in ambient environment

but the fiber has relatively low strength and weak stability. We apply the catechol chemistry and metal coordination to stabilize and strengthen the PEO/PAA fiber. PAA is grafted with dopamine (Dopa)

and then combines with PEO to prepare fiber. PAA-Dopa in the fiber is cross-linked through oxidation induced dismutation and the metal ions are introduced through coordination. The cross-linking and coordination greatly improve the stability of the fiber against the erosion of alkaline water. Among four different metal coordination fibers

PEO/PAA-Dopa/Cu fiber keeps the excellent extensibility (~1000%) and presents much higher initial modulus (~7 MPa)

ultimate strength (~20 MPa)

and toughness (~60 MJ/m

) than its precursor PEO/PAA fiber. In addition

PEO/PAA-Dopa/Cu fiber shows quick recovery and large energy dissipation ratio compared with the PEO/PAA fiber. The distinct mechanical properties enhancement of the hydrogen-bonded complex fiber is attributed to the synergy of hydrogen bonds

coordination and covalent bond cross-linking.

关键词

Keywords

references

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