The Anhydride-Amic Acid-Imide Forms of Maleinized Soybean Oil

Yun Zhou; Yan-Bin Huang; Wan-Tai Yang

doi:10.1007/s10118-023-2980-9

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The Anhydride-Amic Acid-Imide Forms of Maleinized Soybean Oil

RESEARCH ARTICLE | Updated：2023-11-27

- The Anhydride-Amic Acid-Imide Forms of Maleinized Soybean Oil
- Chinese Journal of Polymer Science Vol. 41, Issue 12, Pages: 1829-1835(2023)
- Affiliations：
  
  Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
- Author bio：
  
  yanbin@tsinghua.edu.cn (Y.B.H.)
  yangwantai@tsinghua.edu.cn (W.T.Y.)
- Funds：
- DOI：10.1007/s10118-023-2980-9
  CLC：
- Received：20 February 2023，
  
  Revised：2023-3-16，
  
  Accepted：17 March 2023，
  
  Online First：18 April 2023，
  
  Published：01 December 2023
- Accepted：
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Zhou, Y.; Huang, Y. B.; Yang, W. T. The anhydride-amic acid-imide forms of maleinized soybean oil. Chinese J. Polym. Sci. 2023, 41, 1829–1835

Yun Zhou, Yan-Bin Huang, Wan-Tai Yang. The Anhydride-Amic Acid-Imide Forms of Maleinized Soybean Oil[J]. Chinese Journal of Polymer Science, 2023, 41(12): 1829-1835.
Zhou, Y.; Huang, Y. B.; Yang, W. T. The anhydride-amic acid-imide forms of maleinized soybean oil. Chinese J. Polym. Sci. 2023, 41, 1829–1835 DOI： 10.1007/s10118-023-2980-9.

Yun Zhou, Yan-Bin Huang, Wan-Tai Yang. The Anhydride-Amic Acid-Imide Forms of Maleinized Soybean Oil[J]. Chinese Journal of Polymer Science, 2023, 41(12): 1829-1835. DOI： 10.1007/s10118-023-2980-9.

摘要

Utilizing the amination and imidization reactions of the anhydride groups

soybean oil was transformed into a water-soluble material

which could be applied in a green

water-based route but become water-resistant again after simple heat treatment.

Abstract

Vegetable oil is one of the most promising renewable feedstocks as an alternative to fossil resources

but there are few studies aiming to transform it into hydrophilic materials. We proposed a facile method to prepare water-soluble derivatives from soybean oil

which could become water resistant again after simple heat treatment. The model vegetable oil

soybean oil (SO)

was first reacted with maleic anhydride (MA) by the Alder ene reaction to obtain maleinized soybean oil (SOMA)

and SOMA was further reacted with gaseous ammonia to obtain the maleamic acid form (SOMA-Amic acid)

which was very soluble in water (solubility>100 mg/mL). The obtained water-soluble product was converted to the water-resistant maleimide form (SOMA-Imide) by a simple heat treatment. The potential application of these vegetable oil derived materials was demonstrated in paper sizing as an example. SOMA-Amic acid was demonstrated to be a novel green material

which can be used in an aqueous process and then heat-treated to become water-resistant in the final product.

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references

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