Effects of Conjugated Systems on UV-Visible Light-sensitive D-<italic style="font-style: italic">π</italic>-A Type Sulfonium Salt Photoacid Generators

Xing-yu Wu; Jin Ming; Jian-chao Xie; De-cheng Wan; Malval Jean Pierre

doi:10.1007/s10118-016-1863-8

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Effects of Conjugated Systems on UV-Visible Light-sensitive D-π-A Type Sulfonium Salt Photoacid Generators

Papers | Updated：2021-05-12

- Effects of Conjugated Systems on UV-Visible Light-sensitive D-π-A Type Sulfonium Salt Photoacid Generators
- Chinese Journal of Polymer Science Vol. 34, Issue 12, Pages: 1456-1468(2016)
- Affiliations：
  
  a.School of Materials Science and Engineering, Tongji University, Shanghai 201804, China
  b.Institut de Science des Matériaux de Mulhouse, UMR CNRS 7361, Université de Haute-Alsace, 15 rue Jean Starcky, 68057 Mulhouse, France
- Author bio：
  
  Ming Jin (金明), E-mail:mingjin@tongji.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1863-8
  CLC：
- Received：24 June 2016，
  
  Revised：2016-8-12，
  
  Accepted：12 August 2016，
  
  Published：2016-12
- Accepted：
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Xing-yu Wu, Jin Ming, Jian-chao Xie, et al. Effects of Conjugated Systems on UV-Visible Light-sensitive D-π-A Type Sulfonium Salt Photoacid Generators[J]. Chinese Journal of Polymer Science, 2016, 34(12): 1456-1468. DOI: 10.1007/s10118-016-1863-8.
DOI：

Xing-yu Wu, Jin Ming, Jian-chao Xie, et al. Effects of Conjugated Systems on UV-Visible Light-sensitive D-π-A Type Sulfonium Salt Photoacid Generators[J]. Chinese Journal of Polymer Science, 2016, 34(12): 1456-1468. DOI: 10.1007/s10118-016-1863-8. DOI：

摘要

Abstract

A series of D-

-A type sulfonium salt photoacid generators with different

-conjugated structures

such as triphenyl

phenylstilbene

styryl-biphenyl

and stilbene

were designed to determine the effect of molecular structures on the photochemical and photophysical properties. The mechanisms of photochemical generation of H

were studied by UV-Vis spectroscopy

theoretical calculations

and fluorescence spectroscopy. It is found that the frontier orbits determine the absorption

the molar extinction coefficients

and the quantum yields of photoacid generation. Triphenyl systems connected with sulfonium are beneficial to increase the quantum yields of acid generation. The photoreactivity of four sulfonium salts was further evaluated through the polymerizations of various epoxide monomers at different irradiation wavelengths (365-425 nm) by using the real-time infrared spectroscopy with light-emitting diodes. The high quantum yields for acid generation (

=~0.32 to 0.58) and the high molar extinction coefficients (

=~23500 L·mol

-1

·cm

-1

to 31000 L·mol

-1

·cm

-1

) of the sulfonium salts lead to high conversion rates (over 50%-80%). Hence

these photoinitiators exhibit potential for the photocuring applications.

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Effects of Conjugated Systems on UV-Visible Light-sensitive D-π-A Type Sulfonium Salt Photoacid Generators

DOI：10.1007/s10118-016-1863-8

摘要

Abstract

关键词

Keywords

references