doi:10.1007/s10118-021-2528-9

Citation: Chueangchayaphan, W.; Luangchuang, P.; Chueangchayaphan, N.; Sulaiman, M. A.; Nakaramontri, Y. Barium titanate-reinforced acrylonitrile-butadiene rubber: synergy effect of carbon-based secondary filler. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-021-2528-9 doi: 10.1007/s10118-021-2528-9 shu

Barium Titanate-reinforced Acrylonitrile-Butadiene Rubber: Synergy Effect of Carbon-based Secondary Filler

a.
Faculty of Science and Industrial Technology, Prince of Songkla University, Surat Thani Campus, 84000 Surat Thani, Thailand
b.
Advanced Materials Research Cluster, Faculty Bioengineering and Technology, Universiti Malaysia Kelantan, 17600 Jeli, Kelantan, Malaysia
c.
Sustainable Polymer & Innovative Composite Materials Research Group, Department of Chemistry, Faculty of Science, King Mongkut’s University of Technology Thonburi, 10140 Bangkok, Thailand

Corresponding author: Yeampon Nakaramontri, E-mail: yeampon.nak@kmutt.ac.th
Received Date: 2020-07-12
Accepted Date: 2020-11-19
Available Online: 2021-01-05

Figures(11) / Tables(5)

Acrylonitrile rubber (NBR) composites filled with barium titanate (BT) were prepared using an internal mixer and a two-roll mill. Also, a secondary filler, namely carbon nanotubes (CNT), was added in order to find a potential synergistic blend ratio of BT and CNT. The cure characteristics, tensile and dielectric properties (dielectric constant and dielectric loss) of the composites were determined. It was found that NBR/BT composites with CNT secondary filler, at a proper BT:CNT ratio, exhibited shorter scorch time (t_s1) and cure time (t_c90) together with superior tensile properties and reinforcement efficiency, relative to the one with only the primary filler. In addition, the NBR/BT-CNT composite with 80 phr BT and 1−2 phr CNT had dielectric constant of 100−500, dielectric loss of 12−100 and electrical conductivity below 10⁻⁴ S/m together with high thermal stability. Thus, with a proper BT:CNT mix and filler loading, we can produce mechanically superior rubber composites that are easy to process and low-cost, for flexible dielectric materials application.
- Acrylonitrile-butadiene rubber,
- Barium titanate,
- Carbon nanotube,
- Dielectric properties,
- Mechanical properties
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沈阳化工大学材料科学与工程学院沈阳 110142