doi:10.1007/s10118-020-2349-2

Citation: Xu, H. G.; Qu, M. C.; Pan, Y. M.; Schubert, D. W. Conductivity of poly(methyl methacrylate)/polystyrene/carbon black and poly(ethyl methacrylate)/polystyrene/carbon black ternary composite films. Chinese J. Polym. Sci. 2020, 38, 288–297. doi: 10.1007/s10118-020-2349-2 shu

Conductivity of Poly(methyl methacrylate)/Polystyrene/Carbon Black and Poly(ethyl methacrylate)/Polystyrene/Carbon Black Ternary Composite Films

a.
Institute of Polymer Materials, Friedrich-Alexander-University Erlangen-Nuremberg, Martensstr. 7, 91058 Erlangen, Germany
b.
College of Materials Science and Engineering, The Key Laboratory of Material Processing and Mold of Ministry of Education, Zhengzhou University, Zhengzhou 450002, China
c.
Bavarian Polymer Institute, Dr. Mack-Strasse 77, 90762 Fürth, Germany

Corresponding author: Hua-Gen Xu, E-mail: huagen.xu@fau.de
Received Date: 2019-06-04
Available Online: 2019-11-07

Figures(8) / Tables(6)

Poly(methyl methacrylate) (PMMA)/polystyrene (PS)/carbon black (CB) and poly(ethyl methacrylate) (PEMA)/PS/CB ternary composite films were obtained using solution casting technique to investigate double percolation effect. In both PMMA/PS/CB and PEMA/PS/CB ternary composite films, the CB particles prefer to locate into PS phase based on the results of calculating wetting coefficient, which is also confirmed by SEM images. The conductivity of the films was investigated, and the percolation threshold (ϕ_c) of both ternary composite films with different polymer blend ratios was determined by fitting the McLachlan GEM equation. Conductivity of PMMA/PS/CB ternary composite films showed a typical double percolation effect. However, due to the double emulsion structure of PEMA/PS polymer blends, the PEMA/PS/CB ternary composite films (PEMA/PS = 50/50) showed a higher ϕ_c, even CB only located in PS phase, which conflicts with the double percolation effect. A schematic diagram combined with SEM images was proposed to explain this phenomenon.
- Double percolation effect,
- Conductivity,
- Ternary composite films,
- Compatibility
1. [1]
  Liu, X. H.; Li, C. H.; Pan, Y. M.; Schubert, D. W.; Liu, C. T. Shear-induced rheological and electrical properties of molten poly (methyl methacrylate)/carbon black nanocomposites. Compos. Part B Eng. 2019, 164, 37−44. doi: 10.1016/j.compositesb.2018.11.054
2. [2]
  Gulrez, S. K.; Ali Mohsin, M. E.; Shaikh, H.; Anis, A.; Pulose, A. M.; Yadav, M. K.; Qua, E. H.; Al-Zahrani, S. M. A review on electrically conductive polypropylene and polyethylene. Polym. Compos. 2014, 35, 900−914. doi: 10.1002/pc.22734
3. [3]
  Krause, B.; Boldt, R.; Häußler, L.; Pötschke, P. Ultralow percolation threshold in polyamide 6.6/MWCNT composites. Compos. Sci. Technol. 2015, 114, 119−125. doi: 10.1016/j.compscitech.2015.03.014
4. [4]
  Zhang, C.; Liu, X. H.; Liu, H.; Wang, Y. M.; Guo, Z. H.; Liu, C. T. Multi-walled carbon nanotube in a miscible PEO/PMMA blend: thermal and rheological behavior. Polym. Test. 2019, 75, 367−372. doi: 10.1016/j.polymertesting.2019.03.003
5. [5]
  Zhang, F. F; Liu, X. H.; Zheng, G. Q.; Guo, Z. H.; Liu, C. T.; Shen, C. Y. Facile route to improve the crystalline memory effect: electrospun composite fiber and annealing. Macromol. Chem. Phys. 2018, 219, 1800236. doi: 10.1002/macp.201800236
6. [6]
  Al-Saleh, M. H.; Sundararaj, U. An innovative method to reduce percolation threshold of carbon black filled immiscible polymer blends. Compos. Part A Appl. S. 2008, 39, 284−293. doi: 10.1016/j.compositesa.2007.10.010
7. [7]
  Starý, Z.; Krückel, J.; Weck, C.; Schubert, D. W. Rheology and conductivity of carbon fibre composites with defined fibre lengths. Compos. Sci. Technol. 2013, 85, 58−64. doi: 10.1016/j.compscitech.2013.06.006
8. [8]
  Huang, J. C. Carbon black filled conducting polymers and polymer blends. Adv. Polym. Technol. 2002, 21, 299−313. doi: 10.1002/adv.10025
9. [9]
  Chen, J. W.; Cui, X. H.; Sui, K. Y.; Zhu, Y. T.; Jiang, W. Balance the electrical properties and mechanical properties of carbon black filled immiscible polymer blends with a double percolation structure. Compos. Sci. Technol. 2017, 140, 99−105. doi: 10.1016/j.compscitech.2016.12.029
10. [10]
  Pan, Y. M.; Liu, X. H.; Hao, X. Q.; Starý, Z.; Schubert, D. W. Enhancing the electrical conductivity of carbon black-filled immiscible polymer blends by tuning the morphology. Eur. Polym. J. 2016, 78, 106−115. doi: 10.1016/j.eurpolymj.2016.03.019
11. [11]
  Sumita, M.; Sakata, K.; Asai, S.; Miyasaka, K.; Nakagawa, H. Dispersion of fillers and the electrical conductivity of polymer blends filled with carbon black. Polym. Bull. 1991, 25, 265−271. doi: 10.1007/BF00310802
12. [12]
  Gubbels, F.; Jérôme, R.; Teyssie, P.; Vanlathem, E.; Deltour, R.; Calderone, A.; Parente, V. Brédas, J. L. Selective localization of carbon black in immiscible polymer blends: a useful tool to design electrical conductive composites. Macromolecules 1994, 27, 1972−1974. doi: 10.1021/ma00085a049
13. [13]
  Foulger, S. H. Reduced percolation thresholds of immiscible conductive blends of poly(ethylene-co-vinyl acetate) and high density polyethylene. Conference on electrical insulation and dielectric phenomena. IEEE Annual Report. 1998, Vol. 1, p. 282−287.
14. [14]
  Xu, Z. B.; Zhao, C.; Gu, A. J; Fang, Z. P.; Tong, L. F. Effect of morphology on the electric conductivity of binary polymer blends filled with carbon black. J. Appl. Polym. Sci. 2007, 106, 2008−2017. doi: 10.1002/app.26827
15. [15]
  Cheah, K.; Forsyth, M.; Simon, G. P. Processing and morphological development of carbon black filled conducting blends using a binary host of poly(styrene-co-acrylonitrile) and poly(styrene). J. Polym. Sci., Part B: Polym. Phys. 2000, 38, 3106−3119.
16. [16]
  Calberg, C.; Blacher, S.; Gubbels, F.; Brouers, F.; Deltour, R.; Jérôme, R. Electrical and dielectric properties of carbon black filled co-continuous two-phase polymer blends. J. Phys. D Appl. Phys. 1999, 32, 1517. doi: 10.1088/0022-3727/32/13/313
17. [17]
  Mamunya, Y.; Levchenko, V.; Boiteux, G.; Seytre, G.; Zanoaga, M.; Tanasa, F.; Lebedev, E. Controlling morphology, electrical, and mechanical properties of polymer blends by heterogeneous distribution of carbon nanotubes. Polym. Compos. 2016, 37, 2467−2477. doi: 10.1002/pc.23434
18. [18]
  Nasti, G.; Gentile, G.; Cerruti, P.; Carfagna, C.; Ambrogi, V. Double percolation of multiwalled carbon nanotubes in polystyrene/polylactic acid blends. Polymer 2016, 99, 193−203. doi: 10.1016/j.polymer.2016.06.058
19. [19]
  Chen, Y.; Yang, Q.; Huang, Y. J.; Liao, X.; Niu, Y. H. Influence of phase coarsening and filler agglomeration on electrical and rheological properties of MWNTs-filled PP/PMMA composites under annealing. Polymer 2015, 79, 159−170. doi: 10.1016/j.polymer.2015.10.027
20. [20]
  Dil, E. J.; Favis, B. D. Localization of micro and nano-silica particles in a high interfacial tension poly(lactic acid)/low density polyethylene system. Polymer 2015, 77, 156−166. doi: 10.1016/j.polymer.2015.08.063
21. [21]
  Harrats, C.; Groeninckx, G.; Thomas, S. Micro-and nanostructured multiphase polymer blend systems: phase morphology and interfaces. CRC press, 2015.
22. [22]
  Utrachi, L. A. Polymer alloys and blends. 1990, Chapter 3.
23. [23]
  Paul, D. R.; Barlow, J. W. Polymer blends. J. Macromol. Sci. R. M. C. 1980, 18, 109−168. doi: 10.1080/00222358008080917
24. [24]
  Kim, J. H.; Park, D. S.; Kim, C. K. Characterization of the interaction energies for polystyrene blends with various methacrylate polymers. J. Polym. Sci., Part B: Polym. Phys. 2000, 38, 2666−2677. doi: 10.1002/1099-0488(20001015)38:20<2666::AID-POLB70>3.0.CO;2-P
25. [25]
  Schubert, D. W.; Stamm, M.; Müller, A. H. E. Neutron reflectometry studies on the interfacial width between polystyrene and various poly(alkylmethacrylates). Polym. Eng. Sci. 1999, 39, 1501−1507. doi: 10.1002/pen.11542
26. [26]
  Voulgaris, D.; Petridis, D. Emulsifying effect of dimethyldioctadecylammonium-hectorite in polystyrene/poly(ethyl methacrylate) blends. Polymer 2002, 43, 2213−2218. doi: 10.1016/S0032-3861(02)00039-3
27. [27]
  Taherian, R. Experimental and analytical model for the electrical conductivity of polymer-based nanocomposites. Compos. Sci. Technol. 2016, 123, 17−31. doi: 10.1016/j.compscitech.2015.11.029
28. [28]
  Radzuan, N. A. M.; Sulong, A. B.; Sahari, J. A review of electrical conductivity models for conductive polymer composite. Int. J Hydrogen Energ. 2017, 42, 9262−9273. doi: 10.1016/j.ijhydene.2016.03.045
29. [29]
  McLachlan, D. S.; Blaszkiewicz, M.; Newnham, R. E. Electrical resistivity of composites. J. Am. Ceram. Soc. 1990, 73, 2187−2203. doi: 10.1111/j.1151-2916.1990.tb07576.x
30. [30]
  Sahini, M.; Sahimi, M. Applications of percolation theory. CRC Press, 2014.
31. [31]
  Liu, X. H.; Krückel, J.; Zheng, G. Q.; Schubert, D. W. Mapping the electrical conductivity of poly (methyl methacrylate)/carbon black composites prior to and after shear. ACS Appl. Mater. Interfaces 2013, 5, 8857−8860. doi: 10.1021/am4031517
32. [32]
  Starý, Z. Thermodynamics and morphology and compatibilization of polymer blends. in Characterization of polymer blends. Eds. by Thomas, S.; Grohens, Y.; Jyotishkumar, P. Wiley-VCH Verlag GmbH & Co. KGaA, 2014, 93−132.
33. [33]
  Pajula, K.; Taskinen, M.; Lehto, V. P.; Ketolainen, J.; Korhonen, O. Predicting the formation and stability of amorphous small molecule binary mixtures from computationally determined Flory-Huggins interaction parameter and phase diagram. Mol. Pharmaceut. 2010, 7, 795−804. doi: 10.1021/mp900304p
34. [34]
  Gedde, U. W. Polymer physics. Springer Science & Business Media, 2013.
35. [35]
  Sammler, R. L.; Dion, R. P.; Carriere, C. J.; Cohen, A. Compatibility of high polymers probed by interfacial tension. Rheol. Acta 1992, 31, 554−564. doi: 10.1007/BF00367010
36. [36]
  Schubert, D. W.; Stamm, M. Influence of chain length on the interface width of an incompatible polymer blend. EPL 1996, 35, 419. doi: 10.1209/epl/i1996-00130-3
37. [37]
  Wu, S. Polymer interfaces and adhesion. Marcel Dekker, New York, 1982.
38. [38]
  Deng, H.; Lin, L.; Ji, M. Z.; Zhang, S. M.; Yang, M. B.; Fu, Q. Progress on the morphological control of conductive network in conductive polymer composites and the use as electroactive multifunctional materials. Prog. Polym. Sci. 2014, 39, 627−655. doi: 10.1016/j.progpolymsci.2013.07.007
39. [39]
  Baudouin, A. C.; Devaux, J.; Bailly, C. Localization of carbon nanotubes at the interface in blends of polyamide and ethylene-acrylate copolymer. Polymer 2010, 51, 1341−1354. doi: 10.1016/j.polymer.2010.01.050
40. [40]
  www.surface-tension.desolid-surface-energy.htm
41. [41]
  Cao, Q.; Song, Y. H.; Tan, Y. Q.; Zheng, Q. Conductive and viscoelastic behaviors of carbon black filled polystyrene during annealing. Carbon 2010, 48, 4268−4275. doi: 10.1016/j.carbon.2010.07.036
42. [42]
  Pan, Y. M.; Liu, X. H.; Kaschta, J.; Liu, C. T.; Schubert, D. W. Reversal phenomena of molten immiscible polymer blends during creep-recovery in shear. J. Rheol. 2017, 61, 759−767. doi: 10.1122/1.4985005
43. [43]
  Liu, T.; Huang, K. Q.; Li, L. W.; Gu, Z. P.; Liu, X. H.; Peng, X. F.; Kuang, T. R. High performance high-density polyethylene/hydroxyapatite nanocomposites for load-bearing bone substitute: fabrication, in vitro and in vivo biocompatibility evaluation. Compos. Sci. Technol. 2019, 175, 100−110. doi: 10.1016/j.compscitech.2019.03.012
44. [44]
  Elias, L.; Fenouillot, F.; Majesté, J. C.; Alcouffe, P.; Cassagnau, P. Immiscible polymer blends stabilized with nano-silica particles: rheology and effective interfacial tension. Polymer 2008, 49, 4378−4385. doi: 10.1016/j.polymer.2008.07.018
45. [45]
  Fenouillot, F.; Cassagnau, P.; Majesté, J. C. Uneven distribution of nanoparticles in immiscible fluids: morphology development in polymer blends. Polymer 2009, 50, 1333−1350. doi: 10.1016/j.polymer.2008.12.029
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14. [14]
  DAI Yingkun , FENG Zhiliu . COMPATIBILITY AND PHASE BEHAVIOR OF PS/SBR BLEND Ⅰ. EFFECT OF MOLECULAR WEIGHT OF PS. Chinese J. Polym. Sci, 1990, 8(4): 321-329.
15. [15]
  LI Yongjun , WU Liuren , FANG Shibi , JIANG Yingyan . IONIC CONDUCTIVITY OF POLY(β-ALKOXYCARBONYLETHYLMETHYLSILOXANE)-LiClO4 CROSSLINKED FILMS. Chinese J. Polym. Sci, 1990, 8(2): 127-132.
16. [16]
  LI Yongjun , FU Yingwen , FANG Shibi , JIANG Yingyan . IONIC CONDUCTIVITY OF METHYLSILOXANE TERMINATED POLYETHYLENE OXIDE WITH LITHIUM PERCHLORATE NETWORK FILMS. Chinese J. Polym. Sci, 1988, 6(4): 332-336.
17. [17]
  WAN Meixiang , ZHOU Weixia , LI Yongfang . STUDIES ON THE ELECTRICAL CONDUCTIVITY OF FREE-STANDING FILMS OF POLYANILINE. Chinese J. Polym. Sci, 1991, 9(4): 307-313.
18. [18]
  ZHANG Chi , LU Fengcai . EFFECT OF WATER ON THE CONDUCTIVITY OF PPQ (ClO4-) COMPLEX. Chinese J. Polym. Sci, 1993, 11(1): 8-15.
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